Sorption Studies of Cs+ and Ba2+ Cations on Magnesite

Cataloged from PDF version of article.The adsorption behavior of Cs+ and Ba2+ cations on magnesite has been studied as a function of time, cation concentration and temperature, utilizing both the radiotracer method and X-ray photoelectron spectroscopy (XPS). Saturation was approached in about I day for both cations. The sorption data were found to follow Freundlich type isotherms. Sorption of both Cs+ and Ba2+ cations were found to be exothermic in nature with ΔH0 (kJ/mol) of -37, -13 and ΔS0 (kJ/mol·K) of -0.09, -0.009, respectively. Negative ΔG0 values were obtained for both cations, indicating the spontaneity of their sorption on magnesite. The magnitude of ΔG0 suggest that ion exchange is the dominating sorption mechanism. The adsorption behavior of Cs+ and Ba2+ cations on magnesite has been studied as a function of time, cation concentration and temperature, utilizing both the radiotracer method and X-ray photoelectron spectroscopy (XPS). Saturation was approached in about 1 day for both cations. The sorption data were found to follow Freundlich type isotherms. Sorption of both Cs+ and Ba2+ cations were found to be exothermic in nature with ΔH0 (kJ/mol) of -37, -13 and ΔS0 (kJ/mol·K) of -0.09, -0.009, respectively. Negative ΔG0 values were obtained for both cations, indicating the spontaneity of their sorption on magnesite. The magnitude of ΔG0 suggest that ion exchange is the dominating sorption mechanism

The Sorption Behavior of Cs+ ion On Clay Minerals and Zeolite in Radioactive Waste Managemen: Sorption Kinetics and Themodynamics

Cataloged from PDF version of article.In this work, Cs+ ion sorption on some clays and zeolite were investigated. Cs-137 was used as a tracer. Activities were measured with a NaI crystal gamma counter. The particle size distribution was determined by a laser sizer. Surface area of the particles were determined by BET (Brunauer, Emmett and Teller method). Structure analysis was made by using X-ray diffraction. The chemical compositions of the solid samples were determined using a ICAP-OE spectrometer. Kinetic and thermodynamic parameters were determined. Due to very high uptake results; clay and zeolite can be proposed as a good sorbents in waste management considerations

A Radiotracer study of the adsorption behaviour of aqueous Ba2+ ions on nonoparticles of zero-valent iron

Cataloged from PDF version of article.Recently, iron nanoparticles are increasingly being tested as adsorbents for various types of organic and inorganic pollutants. In this study, nanoparticles of zero-valent iron (NZVI) synthesized under atmospheric conditions were employed for the removal of Ba2+ ions in a concentration range 10-3 to 10-6 M. Throughout the study, 133Ba was used as a tracer to study the effects of time, concentration, and temperature. The obtained data was analyzed using various kinetic models and adsorption isotherms. Pseudo-second-order kinetics and Dubinin-Radushkevich isotherm model provided the best correlation with the obtained data. Observed thermodynamic parameters showed that the process is exothermic and hence enthalpy-driven. © 2007 Elsevier B.V. All rights reserved

A radiotracer study of the adsorption behavior of aqueous Ba2+ ions on nanoparticles of zero-valent iron

Recently, iron nanoparticles are increasingly being tested as adsorbents for various types of organic and inorganic pollutants. In this study, nanoparticles of zero-valent iron (NZVI) synthesized under atmospheric conditions were employed for the removal of Ba2+ ions in a concentration range 10-3 to 10-6 M. Throughout the study, 133Ba was used as a tracer to study the effects of time, concentration, and temperature. The obtained data was analyzed using various kinetic models and adsorption isotherms. Pseudo-second-order kinetics and Dubinin-Radushkevich isotherm model provided the best correlation with the obtained data. Observed thermodynamic parameters showed that the process is exothermic and hence enthalpy-driven.2006 İYTE 1

ToF-SIMS depth profiling analysis of the uptake of Ba2+ and Co2+ ions by natural kaolinite clay

The sorption behavior of Ba2+ and Co2+ ions on a natural clay sample rich in kaolinite was studied using time-of-flight secondary ion mass spectrometry (ToF-SIMS). Depth profiling at 10-Å steps was performed up to a 70-Å matrix depth of the clay prior to and following sorption. The results showed that Co2+ is sorbed in slightly larger quantities than Ba2+, with significant numbers of ions fixed on the outermost surface of the clay. Depletion of the ions K+, Mg 2+, and Ca2+ from the clay lattice was observed to accompany enrichment with Co2+ and Ba2+ ions. The data obtained using X-ray powder diffraction (XRPD) and scanning electron microscopy (SEM) indicated insignificant structural and morphological changes in the lattice of the clay upon sorption of both Ba2+ and Co2+ ions. Analysis using energy dispersive X-ray spectroscopy (EDS) showed that the average atomic percentage (±S.D.) of Ba and Co on kaolinite surface were 0.49±0.11 and 0.61±0.19, respectively, indicating a limited uptake capacity of natural kaolinite for both ions

Topological quantum many-body scars in quantum dimer models on the kagome lattice

We present a class of quantum dimer models on the kagome lattice with full translational invariance that feature a quantum many-body scar state of analytically known entanglement properties within their spectra. Using exact diagonalization on lattices of up to 60 sites, we show that nonscar states conform to the eigenstate thermalization hypothesis. Specifically, we show that energies are distributed according to the Gaussian ensemble expected of their respective symmetry sector, illustrate the existence of the scar from bipartite entanglement properties, and demonstrate revival phenomena in studies of fidelity dynamics

Morphing Planar Graph Drawings Optimally

We provide an algorithm for computing a planar morph between any two planar straight-line drawings of any $n$-vertex plane graph in $O(n)$ morphing steps, thus improving upon the previously best known $O(n^2)$ upper bound. Further, we prove that our algorithm is optimal, that is, we show that there exist two planar straight-line drawings $\Gamma_s$ and $\Gamma_t$ of an $n$-vertex plane graph $G$ such that any planar morph between $\Gamma_s$ and $\Gamma_t$ requires $\Omega(n)$ morphing steps

Synthesis and spectral studies of 5-[3-(1,2,4-triazolyl-azo]-2,4-dihydroxybenzaldehyde(TA)and its Schiff bases with 1,3-diaminopropane(TAAP)and 1,6-diaminohexane(TAAH).Their analytical application for spectrophotometric microdetermination of cobalt(II).

Cataloged from PDF version of article.The new azo compound 5-[3-(1,2,4-triazolyl-azo]-2,4-dihydroxy-benzaldehyde (TA) and its Schiff bases with 1,3-diaminopropane (TAAP) and 1,6-diaminohexane (TAAH) have been synthesized. The bands of diagnostic importance in the IR and the main signals in 1 H NMR spectra are assigned. The electronic absorption spectra in pure organic solvents of different polarity and in buffer solutions of varying pH are investigated. The quantitative description of the solvent effect on the electronic absorption spectra is studied and their acid ionization constants are determined. Also, a new simple and sensitive method for the spectrophotometric microdetermination of Co(II) using these compounds (TA, TAAP and TAAH) as new chromogenic reagents is established. The developed method is successfully used for the determination of trace amounts of cobalt in authentic samples and calculation of the distribution ratio of cobalt adsorbed on bentonite and kaolinite clay minerals. 2004 Elsevier Ltd. All rights reserved

Capital account liberalization in China: the need for a balanced approach

This repository item contains a single issue of the Pardee Center Task Force Reports, a publication series that began publishing in 2009 by the Boston University Frederick S. Pardee Center for the Study of the Longer-Range Future.This is the third report stemming from the Pardee Center Task Force on Regulating Capital Flows for Long-Run Development, a project of the Global Economic Governance Initiative (GEGI) at Boston University. This report is the collective work of experts examining the benefits and risks of accelerated capital account liberalization in China. The contributing authors – all leading scholars and practitioners from around the world (listed below) – met at Boston University in February 2014 to discuss the experiences of other emerging market countries that liberalized the capital account to glean lessons for China as it considers this delicate task. This volume is an outcome from that meeting, presenting the authors’ perspectives on important aspects of capital account liberalization that China should pay special attention to, not only for its own sake, but also in consideration of the potential impacts that China’s actions may have on other emerging markets and the global economy overall