Reactivity difference between protolytic forms of some macrocyclic chromium(III) complexes in ligand substitution and electron transfer processes

The review provides insight into the mechanism of ligand substitution and electron transfer (from chromium( III) to iron(III)) by comparison of the reactivity of some tetraazamacrocyclic chromium(III) complexes in the conjugate acid-base forms. Use of two geometrical isomers made possible to estimate the influence of geometry and protolytic reactions in trans and cis position towards the leaving group on the rate enhancement. Studies on the reaction rates in different media demonstrated the role played by outer sphere interactions in a monodentate ligand substitution

FRW Universe Models in Conformally Flat Spacetime Coordinates. III: Universe models with positive spatial curvature

We deduce general expressions for the line element of universe models with positive spatial curvature described by conformally flat spacetime coordinates. Models with dust, radiation and vacuum energy are exhibited. Discussing the existence of particle horizons we show that there is continual annihilation of space, matter and energy in a dust and radiation dominated universe, and continual creation in a LIVE domined universe when conformal time is used in Friedmann-Robertson-Walker models with positive spatial curvature. A general procedure is given for finding coordinates to be used in Penrose diagrams. We also calculate the age and the redshift of some universe models using conformal time.Comment: 22 pages, 9 figure

FRW Universe Models in Conformally Flat Spacetime Coordinates. II: Universe models with negative and vanishing spatial curvature

We deduce general expressions for the line element of universe models with negative and vanishing spatial curvature described by conformally flat spacetime coordinates. The empty Milne universe model and models with dust, radiation and vacuum energy are exhibited. Discussing the existence of particle horizons we show that there is continual creation of space, matter and energy when conformal time is used in Friedmann-Robertson-Walker models with negative spatial curvature.Comment: 25 pages, 12 figure

Computation of local exchange coefficients in strongly interacting one-dimensional few-body systems: local density approximation and exact results

One-dimensional multi-component Fermi or Bose systems with strong zero-range interactions can be described in terms of local exchange coefficients and mapping the problem into a spin model is thus possible. For arbitrary external confining potentials the local exchanges are given by highly non-trivial geometric factors that depend solely on the geometry of the confinement through the single-particle eigenstates of the external potential. To obtain accurate effective Hamiltonians to describe such systems one needs to be able to compute these geometric factors with high precision which is difficult due to the computational complexity of the high-dimensional integrals involved. An approach using the local density approximation would therefore be a most welcome approximation due to its simplicity. Here we assess the accuracy of the local density approximation by going beyond the simple harmonic oscillator that has been the focus of previous studies and consider some double-wells of current experimental interest. We find that the local density approximation works quite well as long as the potentials resemble harmonic wells but break down for larger barriers. In order to explore the consequences of applying the local density approximation in a concrete setup we consider quantum state transfer in the effective spin models that one obtains. Here we find that even minute deviations in the local exchange coefficients between the exact and the local density approximation can induce large deviations in the fidelity of state transfer for four, five, and six particles.Comment: 12 pages, 7 figures, 1 table, final versio

The Gluonic Field of a Heavy Quark in Conformal Field Theories at Strong Coupling

We determine the gluonic field configuration sourced by a heavy quark undergoing arbitrary motion in N=4 super-Yang-Mills at strong coupling and large number of colors. More specifically, we compute the expectation value of the operator tr[F^2+...] in the presence of such a quark, by means of the AdS/CFT correspondence. Our results for this observable show that signals propagate without temporal broadening, just as was found for the expectation value of the energy density in recent work by Hatta et al. We attempt to shed some additional light on the origin of this feature, and propose a different interpretation for its physical significance. As an application of our general results, we examine when the quark undergoes oscillatory motion, uniform circular motion, and uniform acceleration. Via the AdS/CFT correspondence, all of our results are pertinent to any conformal field theory in 3+1 dimensions with a dual gravity formulation.Comment: 1+38 pages, 16 eps figures; v2: completed affiliation; v3: corrected typo, version to appear in JHE

The twin paradox and Mach's principle

The problem of absolute motion in the context of the twin paradox is discussed. It is shown that the various versions of the clock paradox feature some aspects which Mach might have been appreciated. However, the ultimate cause of the behavior of the clocks must be attributed to the autonomous status of spacetime, thereby proving the relational program advocated by Mach as impracticable.Comment: Latex2e, 11 pages, 6 figures, 33 references, no tables. Accepted for publication in The European Physical Journal PLUS (EPJ PLUS

Semiclassical limit for Dirac particles interacting with a gravitational field

The behavior of spin-1/2 particle in a weak static gravitational field is considered. The Dirac Hamiltonian is diagonalized by the Foldy-Wouthuysen transformation providing also the simple form for the momentum and spin polarization operators. The operator equations of momentum and spin motion are derived for a first time. Their semiclassical limit is analyzed. The dipole spin-gravity coupling in the previously found (another) Hamiltonian does not lead to any observable effects. The general agreement between the quantum and classical analysis is established, contrary to several recent claims. The expression for gravitational Stern-Gerlach force is derived. The helicity evolution in the gravitational field and corresponding accelerated frame coincides, being the manifestation of the equivalence principle.Comment: 8 pages, no figures; version to appear in Physical Review

Estimating oceanic primary production using vertical irradiance and chlorophyll profiles from ocean gliders in the North Atlantic

An autonomous underwater vehicle (Seaglider) has been used to estimate marine primary production (PP) using a combination of irradiance and fluorescence vertical profiles. This method provides estimates for depth-resolved and temporally evolving PP on fine spatial scales in the absence of ship-based calibrations. We describe techniques to correct for known issues associated with long autonomous deployments such as sensor calibration drift and fluorescence quenching. Comparisons were made between the Seaglider, stable isotope (13C), and satellite estimates of PP. The Seaglider-based PP estimates were comparable to both satellite estimates and stable isotope measurements