Sustainable Stationery

Many inks used for printmaking contain harmful chemicals. Not only for us, but for the environment. Foliage has designed a system to reduce our carbon footprint. From start to finish, our products are designed by nature, for you. As an ink supplier, Foliage is designed to inspire print makers to produce their work in a more sustainable approach by addressing the selection and use of ink and paper. Our company follows these principles: Inspiration, Education, Safety, Sense of Community & to Love the World. This research distinction thesis explores the process and materials to make natural inks. It also evaluates the efficiency to convert to sustainable materials.No embargoAcademic Major: Visual Communication Desig

Lane reduction in driven 2d-colloidal systems through microchannels

The transport behavior of a system of gravitationally driven colloidal particles is investigated. The particle interactions are determined by the superparamagnetic behavior of the particles. They can thus be arranged in a crystalline order by application of an external magnetic field. Therefore the motion of the particles through a narrow channel occurs in well-defined lanes. The arrangement of the particles is perturbed by diffusion and the motion induced by gravity. Due to these combined influences a density gradient forms along the direction of motion of the particles. A reconfiguration of the crystal is observed leading to a reduction of the number of lanes. In the course of the lane reduction transition a local melting of the quasi-crystalline phase to a disordered phase and a subsequent crystallization along the motion of the particles is observed. This transition is characterized experimentally and using Brownian dynamics (BD) simulations.Comment: 4 pages, 4 figure

A nanomechanical resonator shuttling single electrons at radio frequencies

We observe transport of electrons through a metallic island on the tip of a nanomechanical pendulum. The resulting tunneling current shows distinct features corresponding to the discrete mechanical eigenfrequencies of the pendulum. We report on measurements covering the temperature range from 300 K down to 4.2 K. We explain the I-V curve, which differs from previous theoretical predictions, with model calculations based on a Master equation approach.Comment: 5 pages, 4 jpeg-figure

Influence of nano-mechanical properties on single electron tunneling: A vibrating Single-Electron Transistor

We describe single electron tunneling through molecular structures under the influence of nano-mechanical excitations. We develop a full quantum mechanical model, which includes charging effects and dissipation, and apply it to the vibrating C$_{60}$ single electron transistor experiment by Park {\em et al.} {[Nature {\bf 407}, 57 (2000)].} We find good agreement and argue vibrations to be essential to molecular electronic systems. We propose a mechanism to realize negative differential conductance using local bosonic excitations.Comment: 7 pages, 6 figure

Electromechanics of charge shuttling in dissipative nanostructures

We investigate the current-voltage (IV) characteristics of a model single-electron transistor where mechanical motion, subject to strong dissipation, of a small metallic grain is possible. The system is studied both by using Monte Carlo simulations and by using an analytical approach. We show that electromechanical coupling results in a highly nonlinear IV-curve. For voltages above the Coulomb blockade threshold, two distinct regimes of charge transfer occur: At low voltages the system behave as a static asymmetric double junction and tunneling is the dominating charge transfer mechanism. At higher voltages an abrupt transition to a new shuttle regime appears, where the grain performs an oscillatory motion back and forth between the leads. In this regime the current is mainly mediated by charges that are carried on the grain as it moves from one lead to the other.Comment: 8 pages, 10 figures, final version to be published in PR

Limiting Current Density of Oxygen Reduction under Ultrathin Electrolyte Layers: From the Micrometer Range to Monolayers

The oxygen reduction reaction (ORR) under ultrathin electrolyte layers is a key reaction in many processes, from atmospheric corrosion to energy conversion in fuel cells. However, the ORR current under ultrathin electrolyte layers is difficult to measure using conventional electrochemical methods. Hence, reliable data are scarce for the micrometer range and totally missing for the sub-micrometer range of the electrolyte layer thickness. Here, we report a novel hydrogen-permeation-based approach to measure the ORR current underneath thin and ultrathin electrolyte layers. By using a Kelvin-probe-based measurement of the potential, which results from dynamic equilibrium of oxygen reduction and hydrogen oxidation, and the corresponding hydrogen charging current density, the full current-potential relationship can be constructed. The results shed a new light on the nature of the limiting current density of ORR underneath ultrathin layers of electrolyte. © 2021 The Authors. ChemElectroChem published by Wiley-VCH Gmb

Bioactive Materials

Bioactive substantially silica-free glass material with a hydroxyapatite layer thereon is described, as well as methods for producing hydroxyapatite on a borate glass