767 research outputs found
Mutually unbiased bases in dimension six: The four most distant bases
We consider the average distance between four bases in dimension six. The
distance between two orthonormal bases vanishes when the bases are the same,
and the distance reaches its maximal value of unity when the bases are
unbiased. We perform a numerical search for the maximum average distance and
find it to be strictly smaller than unity. This is strong evidence that no four
mutually unbiased bases exist in dimension six. We also provide a two-parameter
family of three bases which, together with the canonical basis, reach the
numerically-found maximum of the average distance, and we conduct a detailed
study of the structure of the extremal set of bases.Comment: 10 pages, 2 figures, 1 tabl
Rotational cooling of trapped polyatomic molecules
Controlling the internal degrees of freedom is a key challenge for
applications of cold and ultracold molecules. Here, we demonstrate
rotational-state cooling of trapped methyl fluoride molecules (CH3F) by
optically pumping the population of 16 M-sublevels in the rotational states
J=3,4,5, and 6 into a single level. By combining rotational-state cooling with
motional cooling, we increase the relative number of molecules in the state
J=4, K=3, M=4 from a few percent to over 70%, thereby generating a
translationally cold (~30mK) and nearly pure state ensemble of about 10^6
molecules. Our scheme is extendable to larger sets of initial states, other
final states and a variety of molecule species, thus paving the way for
internal-state control of ever larger molecules
Анализ социальных медиа
The experimental electron-density distributions in crystals of five chain polymers [M(μ-X)2(py)2] (M = Zn, Cd; X = Cl, Br; py = 3,5-substituted pyridine) have been obtained from high-resolution X-ray diffraction data sets (sin θ/λ > 1.1 Å−1) at 100 K. Topological analyses following Bader's `Atoms in Molecules' approach not only confirmed the existence of (3, −1) critical points for the chemically reasonable and presumably strong covalent and coordinative bonds, but also for four different secondary interactions which are expected to play a role in stabilizing the polymeric structures which are unusual for Zn as the metal center. These weaker contacts comprise intra- and inter-strand C—H⋯X—M hydrogen bonds on the one hand and C—X⋯X—C interhalogen contacts on the other hand. According to the experimental electron-density studies, the non-classical hydrogen bonds are associated with higher electron density in the (3, −1) critical points than the halogen bonds and hence are the dominant interactions both with respect to intra- and inter-chain contacts
Phase-dependent which-way information
We introduce a new observable for reading out a which-way detector in a
Young-type interferometer whose eigenstates either contain full which-way
information or none at all. We calculate the which-way knowledge K that can be
retrieved from this observable and find that K depends on the phase difference
\delta that the interfering object accumulates on its way from either slit to
the detector. In particular, it turns out that K(\delta) has an upper bound of
1, almost independent of the visibility V of the interference pattern generated
by the interfering object on a screen, which is in marked contrast to the
well-known inequality K^2 + V^2 <= 1 (cf. B.-G. Englert, Phys. Rev. Lett. 77,
2154 (1996)).Comment: 7 pages, 4 figure
ЯКІВ ДМИТРОВИЧ ГРАХОВ – ДІЯЧ КУЛЬТУРИ ТА ОСВІТИ В КАТЕРИНОСЛАВСЬКІЙ ГУБЕРНІЇ
Розглянуто життєвий шлях, освітянську, наукову та музеєзнавчу діяльність директора Катеринославської гімназії та училищ краю Якова Дмитровича Грахова в середині ХІХ ст.The article covers life, scientific and museum activities of Yakiv Dmitrovych Grakhov, a director of Katerinoslav schools in the middle of the 19th centuary
Silver Complexation by Metallacryptates
We report the first complete characterization of metallycryptates encapsulating Ag(i) cations: carboxylato ligands derived from l-proline and l-alanine chelate and bridge six Cu(ii) centres arranged in a slightly distorted octahedral fashion
Tomographic Quantum Cryptography: Equivalence of Quantum and Classical Key Distillation
The security of a cryptographic key that is generated by communication
through a noisy quantum channel relies on the ability to distill a shorter
secure key sequence from a longer insecure one. For an important class of
protocols, which exploit tomographically complete measurements on entangled
pairs of any dimension, we show that the noise threshold for classical
advantage distillation is identical with the threshold for quantum entanglement
distillation. As a consequence, the two distillation procedures are equivalent:
neither offers a security advantage over the other.Comment: 4 pages, 1 figur
Lattice thermal expansion and anisotropic displacements in {\alpha}-sulfur from diffraction experiments and first-principles theory
Thermal properties of solid-state materials are a fundamental topic of study
with important practical implications. For example, anisotropic displacement
parameters (ADPs) are routinely used in physics, chemistry, and crystallography
to quantify the thermal motion of atoms in crystals. ADPs are commonly derived
from diffraction experiments, but recent developments have also enabled their
first-principles prediction using periodic density functional theory (DFT).
Here, we combine experiments and dispersion-corrected DFT to quantify lattice
thermal expansion and ADPs in crystalline {\alpha}-sulfur (S8), a prototypical
elemental solid that is controlled by the interplay of covalent and van der
Waals interactions. We first report on single-crystal and powder X-ray
diffraction (XRD) measurements that provide new and improved reference data
from 10 K up to room temperature. We then use several popular
dispersion-corrected DFT methods to predict vibrational and thermal properties
of {\alpha}-sulfur, including the anisotropic lattice thermal expansion.
Hereafter, ADPs are derived in the commonly used harmonic approximation (in the
computed zero-Kelvin structure) and also in the quasi-harmonic approximation
(QHA) which takes the predicted lattice thermal expansion into account. At the
PBE+D3(BJ) level, the latter leads to excellent agreement with experiments.
Finally, more general implications of this study for realistic materials
modeling at finite temperature are discussed
Complementarity, quantum erasure and delayed choice with modified Mach-Zehnder interferometers
Often cited dictums in Quantum Mechanics include "observation disturbance
causes loss of interference" and "ignorance is interference". In this paper we
propose and describe a series of experiments with modified Mach-Zehnder
interferometers showing that one has to be careful when applying such dictums.
We are able to show that without interacting in any way with the light quantum
(or quanta) expected to behave "wave-like", interference fringes can be lost by
simply gaining (or having the potential to gain) the which-path knowledge.
Erasing this information may revive the interference fringes. Delayed choice
can be added, arriving to an experiment in line with Wheeler's original
proposal. We also show that ignorance is not always synonym with having the
interference fringes. The often-invoked "collapse of the wavefunction" is found
to be a non-necessary ingredient to describe our experiments.Comment: 8 pages, 3 figures; to appear in EPJ
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