975 research outputs found

    Urban heat stress vulnerability in the U.S. Southwest: The role of sociotechnical systems

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    Heat vulnerability of urban populations is becoming a major issue of concern with climate change, particularly in the cities of the Southwest United States. In this article we discuss the importance of understanding coupled social and technical systems, how they constitute one another, and how they form the conditions and circumstances in which people experience heat. We discuss the particular situation of Los Angeles and Maricopa Counties, their urban form and the electric grid. We show how vulnerable populations are created by virtue of the age and construction of buildings, the morphology of roads and distribution of buildings on the landscape. Further, the regulatory infrastructure of electricity generation and distribution also contributes to creating differential vulnerability. We contribute to a better understanding of the importance of sociotechnical systems. Social infrastructure includes codes, conventions, rules and regulations; technical systems are the hard systems of pipes, wires, buildings, roads, and power plants. These interact to create lock-in that is an obstacle to addressing issues such as urban heat stress in a novel and equitable manner

    Building thermal performance, extreme heat, and climate change

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    The leading source of weather-related deaths in the United States is heat, and future projections show that the frequency, duration, and intensity of heat events will increase in the Southwest. Presently, there is a dearth of knowledge about how infrastructure may perform during heat waves or could contribute to social vulnerability. To understand how buildings perform in heat and potentially stress people, indoor air temperature changes when air conditioning is inaccessible are modeled for building archetypes in Los Angeles, California, and Phoenix, Arizona, when air conditioning is inaccessible is estimated. An energy simulation model is used to estimate how quickly indoor air temperature changes when building archetypes are exposed to extreme heat. Building age and geometry (which together determine the building envelope material composition) are found to be the strongest indicators of thermal envelope performance. Older neighborhoods in Los Angeles and Phoenix (often more centrally located in the metropolitan areas) are found to contain the buildings whose interiors warm the fastest, raising particular concern because these regions are also forecast to experience temperature increases. To combat infrastructure vulnerability and provide heat refuge for residents, incentives should be adopted to strategically retrofit buildings where both socially vulnerable populations reside and increasing temperatures are forecast

    An interacting spin flip model for one-dimensional proton conduction

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    A discrete asymmetric exclusion process (ASEP) is developed to model proton conduction along one-dimensional water wires. Each lattice site represents a water molecule that can be in only one of three states; protonated, left-pointing, and right-pointing. Only a right(left)-pointing water can accept a proton from its left(right). Results of asymptotic mean field analysis and Monte-Carlo simulations for the three-species, open boundary exclusion model are presented and compared. The mean field results for the steady-state proton current suggest a number of regimes analogous to the low and maximal current phases found in the single species ASEP [B. Derrida, Physics Reports, {\bf 301}, 65-83, (1998)]. We find that the mean field results are accurate (compared with lattice Monte-Carlo simulations) only in the certain regimes. Refinements and extensions including more elaborate forces and pore defects are also discussed.Comment: 13pp, 6 fig

    Holomorphic mappings from the ball and polydisc

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    Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/46216/1/208_2005_Article_BF01351851.pd

    Modeling Fungal Melanin Buildup: Biomimetic Polymerization of 1,8-Dihydroxynaphthalene Mapped by Mass Spectrometry

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    Due to the emerging biomedical relevance and technological potential of fungal melanins, and prompted by the virtual lack of information about their structural arrangement, an optimized synthetic protocol has been devised for a potential structural model of Ascomyces allomelanin through enzyme-catalyzed oxidative polymerization of 1,8-dihydroxynaphthalene (1,8-DHN). Electrospray ionization mass spectrometry (ESI-MS) measurements of freshly synthesized DHN-polymer recorded in the negative ion mode allowed detection of oligomers up to m/z 4000, separated by 158 Da, corresponding to the in-chain DHN-unit. The dominant peaks were assigned to singly-charged distribution, up to 23 repeating units, whereas a doubly charged polymer distribution was also detectable. Chemical derivatization, ultra-performance liquid chromatography (UPLC)-ESI MS, and MS/MS data confirmed that oxidative polymerization of 1,8-DHN proceeds through C−C coupling of the naphthalene rings. The new insights reported here into synthetic 1,8-DHN oligomers/polymers as a mimic of fungal melanins may guide novel interesting advances and applications in the field of biomimetic functional material

    Infrared temperature sounding - S-043 Final report, 1 Jul. 1967 - 31 Aug. 1969

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    Balloon-borne multidetector infrared grating spectrometer to measure earths radiance for atmospheric temperature profile determination
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