A comparison of different parameter correlation models and the validation of an MEA-based absorber model

AbstractConsiderable effort on research in CO2 capture technologies has been directed towards steady state systems while less seems to have been done for the same systems in transient state. This work presents a dynamic model for CO2 absorption using aqueous mono-ethanolamine (MEA). Validation against experimental results both obtained at steady state and dynamic conditions is included. A parametric sensitivity study of the underlying model equations is carried out based alternative parameter correlations for the reaction rate constant. It is concluded that validated results for one specific pilot plant don’t necessarily apply to other plants of different sizes under other operational conditions. Furthermore, a parametric sensitivity study for the other parameters as well as for the rest of the CO2 capture process is also warranted

Demonstration of a novel instrument for online monitoring of absorber emissions to air

A novel concept for online monitoring of nitrosamines, solvent amines and their degradation products in amine absorber emissions to air was demonstrated at the Tiller CO2-lab pilot facility. The monitoring concept is based on SINTEF patent No. PCT/EP2011/073557. The measurement method applies gas sampling by capture of analytes in a condensate stream from a single stage condensate collector unit. An improved design for the SINTEF prototype for online gas and liquid measurements has been established as part of the CCUS-ALIGN project. The new design has low complexity and improved robustness, making it applicable as integrated part of industrial monitoring systems. The established prototype was successfully tested for monitoring of trace gas emission from a CO2 capture pilot plant, demonstrating measurements of nitrosamines at levels far below the lower detection limits of commercial industrial online analyzers. Results from testing of a condensate collector prototype indicate high capture efficiency for analytes of interest, including analytes present in aerosols during operation conditions where the absorber emit mist to the atmosphere. The measurement concept has potential for significantly reducing the costs related to manual gas measurements for critical trace gas components in plant operation. Application of the concept can enable continuous measurements of nitrosamines and other critical trace gas analytes in the emissions to air not currently available in absorption-based CO2 capture processes.publishedVersio

Characterisation of Chitin and a Study of its Acid-Catalysed Hydrolysis

PhD i bioteknologiPhD in Biotechnolog

Multi-component analysis of monethanolamine solvent samples by FTIR

Partial least square regression (PLS-R) methodology have been applied on dataset containing FTIR spectra and densities for a large set of MEA solvent samples. The prediction capabilities for the major compounds were tested on different set of realistic degraded solvent samples ranging from bench scale experiments to pilot plant campaigns. Generally, the methods showed good results with exception of samples with high amount of heat stabile salts (HSS). For the real samples, sample residuals (i.e. part of data not fitted by the model) were also studied, and a clear correlation between the residuals and HSS level in samples were observed. Online techniques based on PLS-R and FTIR should be an attractive alternative for monitoring the major solvent compounds in CO2 capture plants using amine solvents, as this will reduce cost of chemical analysis and could be an important tool for implementation of control strategies for energy saving in the process.publishedVersio

Energy assessments of onboard CO2 capture from ship engines by MEA-based post combustion capture system with flue gas heat integration

An early phase feasibility study was carried out for offshore CO2 capture from ship engines of a CO2 transport ship. A flexible in-house process simulator was applied in the assessments. Parametric studies of the overall onboard process were enabled by a fast data-driven capture plant model derived from supervised machine learning by PLS regression of a large dataset of rigorous simulations. The results show, based on the given models and assumptions, that the thermal energy coming from the ship engine exhaust gas is not sufficient alone to cover the thermal energy demand of an absorption-based CO2 capture unit operating above 50% capture rate using 30 wt% MEA (mono-ethanolamine) as solvent. The thermal energy demand can be met using a fuel afterburner as heat source. The added fuel consumption is estimated to increase the fuel consumption by 6–9% when operating with liquefied natural gas (LNG) as fuel source, while an increase of 8–12% is expected with diesel as fuel source. The effect of absorber height on energy consumption at a given CO2 capture rate is limited, especially for lower capture rates, and may be an important degree of freedom for optimizing the CAPEX/OPEX trade-offs. Use of state-of-the art solvents with lower specific energy consumptions will shift the results towards higher capture rates before a fuel afterburner is required to meet the thermal energy demands.publishedVersio

Multi-component analysis of monethanolamine solvent samples by FTIR

Partial least square regression (PLS-R) methodology have been applied on dataset containing FTIR spectra and densities for a large set of MEA solvent samples. The prediction capabilities for the major compounds were tested on different set of realistic degraded solvent samples ranging from bench scale experiments to pilot plant campaigns. Generally, the methods showed good results with exception of samples with high amount of heat stabile salts (HSS). For the real samples, sample residuals (i.e. part of data not fitted by the model) were also studied, and a clear correlation between the residuals and HSS level in samples were observed. Online techniques based on PLS-R and FTIR should be an attractive alternative for monitoring the major solvent compounds in CO2 capture plants using amine solvents, as this will reduce cost of chemical analysis and could be an important tool for implementation of control strategies for energy saving in the process

Demonstration of a novel instrument for online monitoring of absorber emissions to air

A novel concept for online monitoring of nitrosamines, solvent amines and their degradation products in amine absorber emissions to air was demonstrated at the Tiller CO2-lab pilot facility. The monitoring concept is based on SINTEF patent No. PCT/EP2011/073557. The measurement method applies gas sampling by capture of analytes in a condensate stream from a single stage condensate collector unit. An improved design for the SINTEF prototype for online gas and liquid measurements has been established as part of the CCUS-ALIGN project. The new design has low complexity and improved robustness, making it applicable as integrated part of industrial monitoring systems. The established prototype was successfully tested for monitoring of trace gas emission from a CO2 capture pilot plant, demonstrating measurements of nitrosamines at levels far below the lower detection limits of commercial industrial online analyzers. Results from testing of a condensate collector prototype indicate high capture efficiency for analytes of interest, including analytes present in aerosols during operation conditions where the absorber emit mist to the atmosphere. The measurement concept has potential for significantly reducing the costs related to manual gas measurements for critical trace gas components in plant operation. Application of the concept can enable continuous measurements of nitrosamines and other critical trace gas analytes in the emissions to air not currently available in absorption-based CO2 capture processes

Comparison of different solvents from the solvent degradation rig With real samples

publishedVersio