The water resource in tropical Africa and its exploitation

Deals with water resource & its exploitation in tropical Africa from an engineering point of view, giving an insight into the wide range of problems in water development & providing general guidelines for future planning. Considers such issues as the mechanics of the hydrological cycle, the origins of wide variations in rainfall, the potential for water resources development in pastoral areas & low cost methods of exploiting these resources, & problems of water quality. Includes some recommendations on key areas which play an important role in the successful implementation & continued operation of schemes for water supply

Patient-reported outcomes following flexible sigmoidoscopy screening for colorectal cancer in a demonstration screening programme in the UK

<p>OBJECTIVES: Flexible sigmoidoscopy (FS) screening for colorectal cancer will be introduced into the National Cancer Screening Programmes in England in 2013. Patient-reported outcome measures (PROMs) from trial participants indicate high acceptability and no adverse physical or psychological consequences, but this may not generalize to routine screening in the community. This study examined PROMs in a community-based FS screening programme.</p> <p>METHODS: Eligible adults aged 58-59 (n = 2016) registered at 34 London general practices were mailed a National Health Service-endorsed invitation to attend FS screening. Pain and side-effects were assessed in a 'morning-after' questionnaire, and satisfaction was assessed in a three-month follow-up questionnaire. Anxiety, self-rated health and colorectal symptoms were assessed at prescreening and follow-up.</p> <p>RESULTS: In total, 1020 people attended screening and were included in the current analyses, of whom 913 (90%) returned the morning-after questionnaire, and 674 (66%) the follow-up questionnaire. The prescreening questionnaire had been completed by 751 (74%) of those who attended. The majority (87%) of respondents reported no pain or mild pain, and the most frequent side-effect (wind) was only experienced more than mildly by 16%. Satisfaction was extremely high, with 98% glad they had the test; 97% would encourage a friend to have it. From prescreening to follow-up there were no changes in anxiety or self-rated health, and the number of colorectal symptoms declined. Satisfaction and changes in wellbeing were not moderated by gender, deprivation, ethnicity or screening outcome.</p> <p>CONCLUSIONS: PROMs indicate high acceptability of FS screening in 58-59 year olds, with no adverse effects on colorectal symptoms, health status or psychological wellbeing.</p&gt

Perceptions of Time, Cost and Quality Management on Building Projects

This paper examines the relative intrinsic importance of the effective management of projecttime, cost and quality in the attainment of client objectives. The findings from a questionnairesurvey are presented. The survey explored the perceptions of South Africanclients concerning their objectives and the project time, cost and quality management associatedwith building procurement systems in South Africa. The findings indicate thatmis-perceptions exist between clients, contractors and building professionals regardingthe time, cost and quality management associated with building projects, and the contributionthis makes to the attainment of client objectives

Impact of pre-harvest rainfall on the distribution of fusarium mycotoxins in wheat mill fractions

Legislative limits for Fusarium mycotoxins decrease from unprocessed wheat to processed products. A previous observational study identified a seasonal difference in the distribution of deoxynivalenol (DON) but not zearalenone (ZON) within mill fractions. Rainfall is known to influence the production of these mycotoxins in wheat, but the effects of rainfall on their distribution within mill fractions is not known. Laboratory and field experiments were conducted to determine the impact of different watering regimes on the distribution of DON and ZON in wheat mill fractions. Results indicated that repeated wetting and drying could cause movement of DON towards equilibrium across the mill fractions. Whereas, high levels of rainfall could cause a large reduction of DON in the grain, predominantly from the bran fraction, resulting in a proportional increase within white flour. ZON was detectable in fewer samples but results indicated it is less mobile within the grain. It is important for processors to be aware of the variation of mycotoxin distribution within mill fractions and the drivers of this variation to ensure limits set for grain intake result in mill products within mycotoxin legislative limits

Comparison of mechanical debridement and radiofrequency energy for chondroplasty in an in vivo equine model of partial thickness cartilage injury

SummaryObjectiveThe purpose of this study was to develop a long-term model of cartilage injury that could be used to compare the effects of radiofrequency energy (RFE) and mechanical debridement as a treatment.MethodsPartial thickness fibrillation of patellar cartilage was created in 16 mature ponies. Three months after the initial surgery all injured patellae were randomly selected to receive one of the four treatments (n=8/treatment): (1) control, (2) mechanical debridement with a motorized shaver, (3) TAC-CII RFE probe, and (4) CoVac 50 RFE probe. The ponies were euthanized 22 months after treatment. Macroscopic appearance of the cartilage surface was scored, vital cell staining was used to determine chondrocyte viability and light microscopy was used to grade the morphometric changes within the cartilage. Mechanical properties (aggregate modulus, Poisson's ratio and permeability) also were determined and compared to normal uninjured cartilage.ResultsThere were no differences in the cartilage surface scores among the treatment groups and control samples (P>0.05). The maximum depth of cell death and the percentage of dead area in control and mechanical debridement groups were significantly less than those in both RFE groups. There were no significant differences in maximum depth and the percentage of dead area between the two RFE treatment groups. Histologic scores demonstrated better cartilage morphology for the control and mechanical debridement groups than those of RFE groups. However, even with full thickness chondrocyte death, the matrix in the RFE treated sections was still retained and the mechanical properties of the treated cartilage did not differ from the mechanical debridement group.ConclusionRFE caused greater chondrocyte death and more severe morphological changes compared to untreated degenerative cartilage and mechanical debridement in this model

An assessment of mortgage loan default propensity in Ghana

Purpose Credit market development requires appropriate credit assessment and default policies. This paper aims to examine the impact of household characteristics on mortgage default, using survey data collected from Ghanaian financial institutions. Design/methodology/approach Data were gathered using semi-structured questionnaires from customers of five universal banks in Ghana. A logistic regression was used to model the determinants of credit default propensity. Findings Contrary to established knowledge, the study shows that females are more likely to default on credit than their male counterparts. This is even more likely if the female is older, unmarried, divorced and financially illiterate and has lower educational attainments. These factors are associated with lower earning capacity, which increases default tendencies. The findings confirm that price instability (typified by excessive movements in inflation and exchange rates in addition to low national savings rate) are adversely linked to credit defaults. Borrower’s perception of constraints to credit access (such as collateral requirements, interest rate and loan size) influence credit default. Banks should be encouraged to invest in the financial literacy skills development of their customers to mitigate credit default tendencies. Social implications The study is of practical value to credit officers and the development of the credit market in Ghana. A novel model is presented for assessing credit applications and developing credit default policies. Originality/value The research findings have not only expanded the frontiers of literature but also empirically examined the determinants of credit default propensity, which provides a basis for developing and improving credit default policy in the credit market

Quenching 2D Quantum Gravity

We simulate the Ising model on a set of fixed random $\phi^3$ graphs, which corresponds to a {\it quenched} coupling to 2D gravity rather than the annealed coupling that is usually considered. We investigate the critical exponents in such a quenched ensemble and compare them with measurements on dynamical $\phi^3$ graphs, flat lattices and a single fixed $\phi^3$ graph.Comment: 8 page

Synthesis, characterization and thermochemistry of synthetic Pb–As, Pb–Cu and Pb–Zn jarosites

The enthalpy of formation from the elements of well characterized Pb-As, Pb-Cu, and Pb-Zn synthetic jarosites, corresponding to chemical formulas (H3O)0.68±0.03Pb0.32±0.002Fe2.86±0.14(SO4)1.69±0.08(AsO4)0.31±0.02(OH)5.59±0.28(H2O)0.41±0.02, (H3O)0.67±0.03Pb0.33±0.02Fe2.71±0.14Cu0.25±0.01(SO4)2±0.00(OH)5.96±0.30(H2O)0.04±0.002 and (H3O)0.57±0.03Pb0.43±0.02Fe2.70±0.14Zn0.21±0.01(SO4)2±0.00(OH)5.95±0.30(H2O)0.05±0.002, was measured by high temperature oxide melt solution calorimetry and gave ΔH°f = -3691.2 ± 8.6 kJ/mol, ΔH°f = -3653.6 ± 8.2 kJ/mol, and ΔH°f = -3669.4 ± 8.4 kJ/mol, respectively. Using estimated entropies, the standard Gibbs free energy of formation from elements at 298 K ΔG°f of the three compounds were calculated to be -3164.8 ± 9.1 kJ/mol, -3131.4 ± 8.7 kJ/mol, and -3153.6 ± 8.9 kJ/mol, respectively. Based on these free energies, their logKsp values are -13.94 ± 1.89, -4.38 ± 1.81 and -3.75 ± 1.80, respectively. For this compounds, a log10{Pb2+} - pH diagram is presented. The diagram shows that the formation of Pb-As jarosite may decrease aqueous arsenic and lead concentrations to meet drinking water standards. The new thermodynamic data confirm that transformation of Pb-As jarosite to plumbojarosite is thermodynamically possible

Depinning with dynamic stress overshoots: A hybrid of critical and pseudohysteretic behavior

A model of an elastic manifold driven through a random medium by an applied force F is studied focussing on the effects of inertia and elastic waves, in particular {\it stress overshoots} in which motion of one segment of the manifold causes a temporary stress on its neighboring segments in addition to the static stress. Such stress overshoots decrease the critical force for depinning and make the depinning transition hysteretic. We find that the steady state velocity of the moving phase is nevertheless history independent and the critical behavior as the force is decreased is in the same universality class as in the absence of stress overshoots: the dissipative limit which has been studied analytically. To reach this conclusion, finite-size scaling analyses of a variety of quantities have been supplemented by heuristic arguments. If the force is increased slowly from zero, the spectrum of avalanche sizes that occurs appears to be quite different from the dissipative limit. After stopping from the moving phase, the restarting involves both fractal and bubble-like nucleation. Hysteresis loops can be understood in terms of a depletion layer caused by the stress overshoots, but surprisingly, in the limit of very large samples the hysteresis loops vanish. We argue that, although there can be striking differences over a wide range of length scales, the universality class governing this pseudohysteresis is again that of the dissipative limit. Consequences of this picture for the statistics and dynamics of earthquakes on geological faults are briefly discussed.Comment: 43 pages, 57 figures (yes, that's a five followed by a seven), revte

Ginzburg-Landau functional for nearly antiferromagnetic perfect and disordered Kondo lattices

Interplay between Kondo effect and trends to antiferromagnetic and spin glass ordering in perfect and disordered bipartite Kondo lattices is considered. Ginzburg-Landau equation is derived from the microscopic effective action written in three mode representation (Kondo screening, antiferromagnetic correlations and spin liquid correlations). The problem of local constraint is resolved by means of Popov-Fedotov representation for localized spin operators. It is shown that the Kondo screening enhances the trend to a spin liquid crossover and suppresses antiferromagnetic ordering in perfect Kondo lattices and spin glass ordering in doped Kondo lattices. The modified Doniach's diagram is constructed, and possibilities of going beyond the mean field approximation are discussed.Comment: 18 pages, RevTeX, 7 EPS figures include