Thermal Regime of a Cold Air Trap in Central Pennsylvania, USA: the Trough Creek Ice Mine

Air temperatures internal and external to a talus cave (‘ice mine’) in central Pennsylvania were measured hourly for three years. Despite its location near the base of a talus slope, the cave demonstrated the thermal characteristics of an apparently static cave, with limited connections to the external environment other than through the cave entrance. Congelation ice that lasted until late spring formed as drip or flowstone and ponded ice from the limited influx of infiltrating water during late winter/early spring. A closed period of thermal stratification and slow warming of cave air was followed by an open period in winter months during which the cave was cooled by the influx of cold dry air. Unlike the occasionally strong and localised cooling induced by the flow of cold air from vents at the base of talus slopes, static cold traps retain their cold air and have little apparent effect on surrounding biota, instead providing potential refugia for organisms that prefer colder temperatures. Published 2012. This article is a U.S. Government work and is in the public domain in the USA

Hydrogel Tracer Beads: The Development, Modification, and Testing of an Innovative Tracer for Better Understanding LNAPL Transport in Karst Aquifers

The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport

Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (εSr SW = +13.8 to +41.6, where εSr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters

Isotopic evidence of enhanced carbonate dissolution at a coal mine drainage site in Allegheny County, Pennsylvania, USA

18 O SO4 isotopic signatures of the mine drainage and the presence of presumptive SO 4 -reducing bacteria suggest that SO 4 reduction activity also contributes C depleted in 13 C isotope to the total DIC pool. With distance downstream from the mine portal, C isotope signatures in the drainage increased , accompanied by decreased total DIC concentrations and increased pH. These data are consistent with H 2 SO 4 dissolution of carbonate rocks, enhanced by cation exchange, and C release to the atmosphere via CO 2 outgassing

Isotopic evidence of enhanced carbonate dissolution at a coal mine drainage site in Allegheny County, Pennsylvania, USA

18 O SO4 isotopic signatures of the mine drainage and the presence of presumptive SO 4 -reducing bacteria suggest that SO 4 reduction activity also contributes C depleted in 13 C isotope to the total DIC pool. With distance downstream from the mine portal, C isotope signatures in the drainage increased , accompanied by decreased total DIC concentrations and increased pH. These data are consistent with H 2 SO 4 dissolution of carbonate rocks, enhanced by cation exchange, and C release to the atmosphere via CO 2 outgassing

Determination of free CO2 in emergent groundwaters using a commercial beverage carbonation meter

Dissolved CO{sub 2} in groundwater is frequently supersaturated relative to its equilibrium with atmospheric partial pressure and will degas when it is conveyed to the surface. Estimates of dissolved CO{sub 2} concentrations can vary widely between different hydrochemical facies because they have different sources of error (e.g., rapid degassing, low alkalinity, non-carbonate alkalinity). We sampled 60 natural spring and mine waters using a beverage industry carbonation meter, which measures dissolved CO{sub 2} based on temperature and pressure changes as the sample volume is expanded. Using a modified field protocol, the meter was found to be highly accurate in the range 0.2–35 mMCO{sub 2}. The meter provided rapid, accurate and precise measurements of dissolved CO{sub 2} in natural waters for a range of hydrochemical facies. Dissolved CO{sub 2} concentrations measured in the field with the carbonation meter were similar to CO{sub 2} determined using the pH-alkalinity approach, but provided immediate results and avoided errors from alkalinity and pH determination. The portability and ease of use of the carbonation meter in the field made it well-suited to sampling in difficult terrain. The carbonation meter has proven useful in the study of aquatic systems where CO{sub 2} degassing drives geochemical changes that result in surficial mineral precipitation and deposition, such as tufa, travertine and mine drainage deposits

Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (εSr SW = +13.8 to +41.6, where εSr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters

Determination of free CO2 in emergent groundwaters using a commercial beverage carbonation meter

Dissolved CO{sub 2} in groundwater is frequently supersaturated relative to its equilibrium with atmospheric partial pressure and will degas when it is conveyed to the surface. Estimates of dissolved CO{sub 2} concentrations can vary widely between different hydrochemical facies because they have different sources of error (e.g., rapid degassing, low alkalinity, non-carbonate alkalinity). We sampled 60 natural spring and mine waters using a beverage industry carbonation meter, which measures dissolved CO{sub 2} based on temperature and pressure changes as the sample volume is expanded. Using a modified field protocol, the meter was found to be highly accurate in the range 0.2–35 mMCO{sub 2}. The meter provided rapid, accurate and precise measurements of dissolved CO{sub 2} in natural waters for a range of hydrochemical facies. Dissolved CO{sub 2} concentrations measured in the field with the carbonation meter were similar to CO{sub 2} determined using the pH-alkalinity approach, but provided immediate results and avoided errors from alkalinity and pH determination. The portability and ease of use of the carbonation meter in the field made it well-suited to sampling in difficult terrain. The carbonation meter has proven useful in the study of aquatic systems where CO{sub 2} degassing drives geochemical changes that result in surficial mineral precipitation and deposition, such as tufa, travertine and mine drainage deposits

Thermal Regime of a Cold Air Trap in Central Pennsylvania, USA: the Trough Creek Ice Mine

Air temperatures internal and external to a talus cave (‘ice mine’) in central Pennsylvania were measured hourly for three years. Despite its location near the base of a talus slope, the cave demonstrated the thermal characteristics of an apparently static cave, with limited connections to the external environment other than through the cave entrance. Congelation ice that lasted until late spring formed as drip or flowstone and ponded ice from the limited influx of infiltrating water during late winter/early spring. A closed period of thermal stratification and slow warming of cave air was followed by an open period in winter months during which the cave was cooled by the influx of cold dry air. Unlike the occasionally strong and localised cooling induced by the flow of cold air from vents at the base of talus slopes, static cold traps retain their cold air and have little apparent effect on surrounding biota, instead providing potential refugia for organisms that prefer colder temperatures. Published 2012. This article is a U.S. Government work and is in the public domain in the USA

Amendment of a hardwood biochar with compost tea: effects on plant growth, insect damage and the functional diversity of soil microbial communities

<p>Biochar is an organic soil amendment that has been shown to improve plant growth and increase resistance to plant diseases and insect damage in certain soils. Organic growers have been known to use compost teas to amend biochar, claiming that this practice adds nutrients and beneficial microorganisms that can improve plant growth and resistance to pathogens and insect pests. However, few data exist to support this hypothesis. This study investigated the effects of a hardwood biochar amended with different types of compost teas and microbial enrichments (prepared from vermicompost) on eggplant (<i>Solanum melongena</i> var. Rosa Bianca) growth, flea beetle (<i>Epitrix fuscula</i>) damage, and soil microbial activity and functional diversity in two temperate soils. No positive short-term effects were observed on eggplant growth or flea beetle damage when biochar amended with compost teas prepared from horse manure, mushroom compost or vermicompost were added to a temperate agricultural soil. However, a second experiment suggested that biochar amended with microbial enrichments from vermicompost tea may improve eggplant growth if matched with the physical and chemical properties of a given soils. Results from Community Level Physiological Profiling (CLPP) revealed that biochar amended with compost teas altered soil microbial activity and functional diversity differently to that of biochar alone, and that these changes corresponded with plant growth and insect damage.</p