Determination of atmospheric mercury during the North Sea experiment

Total gaseous mercury (TGM) and rainwater were collected on board of two research vessels (F. S. ALKOR and R.V. BELGICA) positioned 200 km apart in the center of the North Sea during the North Sea Experiment, September 1991. On the F. S. ALKOR (up-wind ship) TGM concentrations ranged from 0.7 to 2.6 ng.m(-3) with an average of 1.5 ng.m(-3) and on the R. V. BELGICA (down-wind ship) TGM ranged from 0.7 to 1.9 ng.m(-3) with an average of 1.2 ng.m(-3). An average 20% decrease is observed from the up-wind to the downwind ship. which may largely be affected by entrainment into the free troposphere. An overall removal (entrainment) velocity of 0.95 cm.s(-1) was calculated for the whole experiment. The average removal velocity was 0.5 cm.s(-1) for dry periods and varied between 1 to 5 cm.s(-1) during rain events. Rainwater concentrations varied between 5 and 25 ng.l(-1). Based on these data an annual wet deposition flux of 1.08 ng Hg cm(-2) yr(1-) was estimated for the North Sea

Atmospheric mercury speciation and mercury in snow over time at Alert, Canada

Ten years of atmospheric mercury speciation data and 14 years of mercury in snow data from Alert, Nunavut, Canada, are examined. The speciation data, collected from 2002 to 2011, includes gaseous elemental mercury (GEM), particulate mercury (PHg) and reactive gaseous mercury (RGM). During the winter-spring period of atmospheric mercury depletion events (AMDEs), when GEM is close to being completely depleted from the air, the concentration of both PHg and RGM rise significantly. During this period, the median concentrations for PHg is 28.2 pgm⁻³ and RGM is 23.9 pgm⁻³, from March to June, in comparison to the annual median concentrations of 11.3 and 3.2 pgm⁻³ for PHg and RGM, respectively. In each of the ten years of sampling, the concentration of PHg increases steadily from January through March and is higher than the concentration of RGM. This pattern begins to change in April when the levels of PHg peak and RGM begin to increase. In May, the high PHg and low RGM concentration regime observed in the early spring undergoes a transition to a regime with higher RGM and much lower PHg concentrations. The higher RGM concentration continues into June. The transition is driven by the atmospheric conditions of air temperature and particle availability. Firstly, a high ratio of the concentrations of PHg to RGM is reported at low temperatures which suggests that oxidized gaseous mercury partitions to available particles to form PHg. Prior to the transition, the median air temperature is −24.8 °C and after the transition the median air temperature is −5.8 °C. Secondly, the high PHg concentrations occur in the spring when high particle concentrations are present. The high particle concentrations are principally due to Arctic haze and sea salts. In the snow, the concentrations of mercury peak in May for all years. Springtime deposition of total mercury to the snow at Alert peaks in May when atmospheric conditions favour higher levels of RGM. Therefore, the conditions in the atmosphere directly impact when the highest amount of mercury will be deposited to the snow during the Arctic spring

Gaseous elemental mercury depletion events observed at Cape Point during 2007–2008

Gaseous mercury in the marine boundary layer has been measured with a 15 min temporal resolution at the Global Atmosphere Watch station Cape Point since March 2007. The most prominent features of the data until July 2008 are the frequent occurrences of pollution (PEs) and depletion events (DEs). Both types of events originate mostly within a short transport distance (up to about 100 km), which are embedded in air masses ranging from marine background to continental. The Hg/CO emission ratios observed during the PEs are within the range reported for biomass burning and industrial/urban emissions. The depletion of gaseous mercury during the DEs is in many cases almost complete and suggests an atmospheric residence time of elemental mercury as short as a few dozens of hours, which is in contrast to the commonly used estimate of approximately 1 year. The DEs observed at Cape Point are not accompanied by simultaneous depletion of ozone which distinguishes them from the halogen driven atmospheric mercury depletion events (AMDEs) observed in Polar Regions. Nonetheless, DEs similar to those observed at Cape Point have also been observed at other places in the marine boundary layer. Additional measurements of mercury speciation and of possible mercury oxidants are hence called for to reveal the chemical mechanism of the newly observed DEs and to assess its importance on larger scales

222Rn calibrated mercury fluxes from terrestrial surfaces of southern Africa derived from observations at Cape Point, South Africa

Gaseous elemental mercury (GEM) and 222Rn, a radioactive gas of primarily terrestrial origin with a half-life of 3.8 days, have been measured simultaneously at Cape Point, South Africa, since March 2007. Between March 2007 and December 2009 altogether 59 events with high 222Rn concentrations were identified. GEM correlated with 222Rn in 41 of the events and was constant during the remaining events without significant correlation. The average GEM/222Rn emission ratio of all events was -0.0047 ± 0.0054 pg mBq-1, with ± 0.0054 being the standard error of the average. With an emission rate of 1.1 222Rn atoms cm-2 s-1 and a correction for the transport duration, this emission ratio corresponds to a radon calibrated flux of about -0.53 ± 0.62 ng m-2 h-1 which is statistically not distinguishable from zero. With wet deposition, which is not included in this estimate, the terrestrial surface of southern Africa appears to be a net mercury sink. © Owned by the authors, published by EDP Sciences, 201

222Rn-calibrated mercury fluxes from terrestrial surface of southern Africa

Gaseous elemental mercury (GEM) and 222Rn, a radioactive gas of primarily terrestrial origin with a half-life of 3.8 days, have been measured simultaneously at Cape Point, South Africa, since March 2007. Between March 2007 and December 2011, altogether 191 events with high 222Rn concentrations were identified. GEM correlated with 222Rn in 94 of the events and was constant during almost all the remaining events without significant correlation. The average GEM / 222Rn flux ratio of all events including the non-significant ones was −0.0001 with a standard error of ±0.0030 pg mBq−1. Weighted with the event duration, the average GEM / 222Rn flux ratio was −0.0048 ± 0.0011 pg mBq−1. With an emission rate of 1.1 222Rn atoms cm−2 s−1 and a correction for the transport time, this flux ratio corresponds to a radon-calibrated flux of about −0.54 ng GEM m−2 h−1 with a standard error of ±0.13 ng GEM m−2 h−1 (n = 191). With wet deposition, which is not included in this estimate, the terrestrial surface of southern Africa seems to be a net mercury sink of about −1.55 ng m−2 h−1. The additional contribution of an unknown but presumably significant deposition of reactive gaseous mercury would further increase this sink.© 2013, European Geosciences Unio

Sustainable risk management of emerging contaminants in municipal wastewaters

This article is available open access through the publisher’s website at the link below. Copyright @ 2009 The Royal Society.The presence of emerging contaminants in municipal wastewaters, particularly endocrine-disrupting compounds such as oestrogenic substances, has been the focus of much public concern and scientific attention in recent years. Due to the scientific uncertainty still surrounding their effects, the Precautionary Principle could be invoked for the interim management of potential risks. Therefore, precautionary prevention risk-management measures could be employed to reduce human exposure to the compounds of concern. Steroid oestrogens are generally recognized as the most significant oestrogenically active substances in domestic sewage effluent. As a result, the UK Environment Agency has championed a ‘Demonstration Programme’ to investigate the potential for removal of steroid oestrogens and alkylphenol ethoxylates during sewage treatment. Ecological and human health risks are interdependent, and ecological injuries may result in increased human exposures to contaminants or other stressors. In this context of limiting exposure to potential contaminants, examining the relative contribution of various compounds and pathways should be taken into account when identifying effective risk-management measures. In addition, the explicit use of ecological objectives within the scope of the implementation of the EU Water Framework Directive poses new challenges and necessitates the development of ecosystem-based decision tools. This paper addresses some of these issues and proposes a species sensitivity distribution approach to support the decision-making process related to the need and implications of sewage treatment work upgrade as risk-management measures to the presence of oestrogenic compounds in sewage effluent

Odds and ends of atmospheric mercury in Europe and over the North Atlantic Ocean: temporal trends of 25 years of measurements

The global monitoring plan of the Minamata Convention on Mercury was established to generate long-term data necessary for evaluating the effectiveness of regulatory measures at a global scale. After 25 years of monitoring (since 1995), Mace Head is one of the atmospheric monitoring stations with the longest mercury record and has produced sufficient data for the analysis of temporal trends of total gaseous mercury (TGM) in Europe and the North Atlantic. Using concentration-weighted trajectories for atmospheric mercury measured at Mace Head as well as another five locations in Europe, Amderma, Andoya, Villum, Waldhof and Zeppelin, we identify the regional probabilistic source contribution factor and its changes for the period of 1996 to 2019. Temporal trends indicate that concentrations of mercury in the atmosphere in Europe and the North Atlantic have declined significantly over the past 25 years at a non-monotonic rate averaging 0.03 ng m(-3) yr(-1). Concentrations of TGM at remote marine sites were shown to be affected by continental long-range transport, and evaluation of reanalysis back trajectories displays a significant decrease in TGM in continental air masses from Europe in the last 2 decades. In addition, using the relationship between mercury and other atmospheric trace gases that could serve as a source signature, we perform factorization regression analysis, based on positive rotatable factorization to solve probabilistic mass functions. We reconstructed atmospheric mercury concentration and assessed the contribution of the major natural and anthropogenic sources. The results reveal that the observed downward trend in the atmospheric mercury is mainly associated with a factor with a high load of long-lived anthropogenic species

ATMOSPHERIC MERCURY MEASUREMENTS AT CAPE POINT, SOUTH AFRICA

Over the 1995-2009 period the gaseous elemental mercury (GEM) concentrations have decreased by about 0.04 ng m-3 yr-1 -at Cape Point (CPT). A reduction of the same magnitude is indicated by measurements during intermittent ship cruises, implying a homogeneous distribution of GEM concentrations in the Southern Hemisphere (SH) and a 30% reduction of its atmospheric burden. Almost all GEM measurements in the Northern Hemisphere (NH) point to a substantial decrease but the trends are inhomogeneous, most likely due to a variable source distribution. However, measurements in the NH during ship cruises suggest a trend of similar magnitude. A decrease in the total atmospheric GEM burden by about 30% is inconsistent with the current mercury budgets. The most probable explanation for this is subsiding re-emissions from the legacy of large past emissions. High-resolution data since 2007 revealed depletion (DES) as well as pollution events (PEs). Both types are embedded in air masses ranging from marine background to continental. The DES observed at Cape Point are a local phenomenon (<100 km) and are the first mercury depletion events reported outside the Polar Regions. In contrast to polar DES, the DES at CPT are not accompanied by concurrent O3 depletion. They mostly appear at wind speeds < 10 m s-1 and their predominating occurrence between 11 and 18 hours suggests a photochemical destruction mechanism which could not be explained yet. GEM correlates with CO, C02, and CH4 during most PES at CPT (GEM levels > 1.3 ng m-3) and with 222Rn during about half the events. Most of the observed GEM/CO emission ratios are within the range bracketed by values reported for biomass burning and industrial/urban emissions, thus suggesting a mixture of both. No significant differences of GEM/CO and GEM/C02 could be found between different source regions defined by backward trajectories. This implies that exceptionally high emissions ascribed to the Gauteng region in global mercury inventories are overestimated