3 research outputs found
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Electroplating lithium transition metal oxides.
Materials synthesis often provides opportunities for innovation. We demonstrate a general low-temperature (260°C) molten salt electrodeposition approach to directly electroplate the important lithium-ion (Li-ion) battery cathode materials LiCoO2, LiMn2O4, and Al-doped LiCoO2. The crystallinities and electrochemical capacities of the electroplated oxides are comparable to those of the powders synthesized at much higher temperatures (700° to 1000°C). This new growth method significantly broadens the scope of battery form factors and functionalities, enabling a variety of highly desirable battery properties, including high energy, high power, and unprecedented electrode flexibility
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Carbon fiber reinforced structural lithium-ion battery composite: Multifunctional power integration for CubeSats
Here we demonstrate a multifunctional battery platform where lithium-ion battery active materials are combined with carbon fiber weave materials to form energy storage composites using traditional layup methods. This design utilizes epoxy resin as a packaging medium for the battery and the carbon fibers as both a conductive current collector and structurally reinforcing layer. These composites exhibit energy density surpassing 35 Wh/kg relative to combined active and inactive composite materials, stable full-cell cycling, and mechanical properties including tensile strength of 213 MPa and Young’s modulus of ~1.8 MPa/(Δl/l). Structural battery panels developed from this approach are demonstrated as an integrated power delivery platform for a 1U CubeSat frame to augment or replace interior external battery packs. Overall, this approach shows a new path for battery integration into systems where the inactive materials for energy storage are the active composite structural materials.
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