Silicon oxycarbide glass for the immobilisation of irradiated graphite waste

© 2015 Elsevier B.V. Silicon oxycarbide glass has been investigated as a potential immobilisation medium for irradiated graphite waste from nuclear power generation. The glass was synthesised via sol-gel techniques using alkoxysilane precursors. Attempts to produce a wasteform via conventional sintering were unsuccessful, but dense wasteforms were achieved by spark plasma sintering (SPS). Microstructural investigations showed that the addition of graphite to the glass did not alter the structure of the matrix; no reaction between the graphite and the glass matrix was observed. Silicon oxycarbide glass is a viable candidate for encapsulation of graphite waste prior to disposal

Assessing the economics of large Energy Storage Plants with an optimisation methodology

Power plants, such as wind farms, that harvest renewable energy are increasing their share of the energy portfolio in several countries, including the United Kingdom. Their inability to match demand power profiles is stimulating an increasing need for large ESP (Energy Storage Plants), capable of balancing their instability and shifting power produced during low demand to peak periods. This paper presents and applies an innovative methodology to assess the economics of ESP utilising UK electricity price data, resulting in three key findings. Firstly the paper provides a methodology to assess the trade-off “reserve capacity vs. profitability” and the possibility of establishing the “optimum size capacity”. The optimal reserve size capacity maximizing the NPV (Net Present Value) is smaller than the optimum size capacity minimizing the subsidies. This is not an optimal result since it complicates the incentive scheme to align investors and policy makers' interests. Secondly, without subsidies, none of the existing ESP technologies are economically sustainable. However, subsidies are a relatively small percentage of the average price of electricity in UK. Thirdly, the possibility of operating ESP as both as a reserve and do price arbitrage was identified as a mean of decreasing subsidies for the ESP technologies