54 research outputs found
A topological method for the classification of entanglements in crystal networks
A rigorous method is proposed to describe and classify the topology of
entanglements between periodic networks if the links are of the Hopf type. The
catenation pattern is unambiguously identified by a net of barycentres of
catenating rings with edges corresponding to the Hopf links; this net is called the Hopf ring net. The Hopf ring net approach is compared with other methods of characterizing entanglements; a number of applications of this approach to various kinds of entanglement (interpenetration, polycatenation and self-catenation) both in modelled network arrays and in coordination networks are considered
How 2-periodic coordination networks are interweaved : entanglement isomerism and polymorphism
The entanglements of 1319 2-periodic coordination polymers are examined and fully classified using the
extended ring nets (ERNs) approach. The ERNs characterize the entanglement to the greatest detail ever
achieved: all possible classes/types/modes of entanglements observed and reported in the literature so far
result in 216 ERN topologically distinct modes of entanglements with 74% of all the structures falling into
only 21 of them. We also introduce the notion of entanglement isomerism to designate the coordination
polymers that have the same chemical composition, local and overall topology, but differ by their catenation
patterns as mapped into their ERNs
Microlensing effects and structure of gravitational lens systems
A study of gravitational microlensing of distant objects is presented. We performed simulations of light curves and trajectories of the image centroid of an extended source in the Chang–Refsdal lens with shear and continual dark matter. Various brightness distributions over the source (Gaussian, power-law, Shakura–Synyaev accretion disc) have been studied. We considered in detail approximate relations and corresponding algorithms used to fit observational data on high amplification events (HAE). The results are applied to interpretation of HAE observed by OGLE and GLITP groups. The source size and caustic crossing moment are estimated from these data, however, the determination of the brightness profile is statistically not reliable
Lattice dynamics effects on small polaron properties
This study details the conditions under which strong-coupling perturbation
theory can be applied to the molecular crystal model, a fundamental theoretical
tool for analysis of the polaron properties. I show that lattice dimensionality
and intermolecular forces play a key role in imposing constraints on the
applicability of the perturbative approach. The polaron effective mass has been
computed in different regimes ranging from the fully antiadiabatic to the fully
adiabatic. The polaron masses become essentially dimension independent for
sufficiently strong intermolecular coupling strengths and converge to much
lower values than those tradition-ally obtained in small-polaron theory. I find
evidence for a self-trapping transition in a moderately adiabatic regime at an
electron-phonon coupling value of .3. Our results point to a substantial
independence of the self-trapping event on dimensionality.Comment: 8 pages, 5 figure
Crossover from BCS to Composite Boson (Local Pair) Superconductivity in Quasi-2D systems
The crossover from cooperative Cooper pairing to independent bound state
(composite bosons) formation and condensation in quasi-2D systems is studied.
It is shown that at low carrier density the critical superconducting
temperature is equal to the temperature of Bose-condensation of ideal quasi-2D
Bose-gas with heavy dynamical mass, meanwhile at high densities the BCS result
remains valid. The evident nonmonotoneous behaviour of the critical temperature
as function of the coupling constant (the energy of the two particle bound
state) is a qualitative difference of quasi-2D crossover from 3D one.Comment: 9 pages, LaTeX, no figures. (The latest version which appeared in the
journal
The Holstein Polaron
We describe a variational method to solve the Holstein model for an electron
coupled to dynamical, quantum phonons on an infinite lattice. The variational
space can be systematically expanded to achieve high accuracy with modest
computational resources (12-digit accuracy for the 1d polaron energy at
intermediate coupling). We compute ground and low-lying excited state
properties of the model at continuous values of the wavevector in
essentially all parameter regimes. Our results for the polaron energy band,
effective mass and correlation functions compare favorably with those of other
numerical techniques including DMRG, Global Local and exact diagonalization. We
find a phase transition for the first excited state between a bound and unbound
system of a polaron and an additional phonon excitation. The phase transition
is also treated in strong coupling perturbation theory.Comment: 24 pages, 11 figures submitted to PR
Theory of bound polarons in oxide compounds
We present a multilateral theoretical study of bound polarons in oxide
compounds MgO and \alpha-Al_2O_3 (corundum). A continuum theory at arbitrary
electron-phonon coupling is used for calculation of the energies of thermal
dissociation, photoionization (optically induced release of an electron (hole)
from the ground self-consistent state), as well as optical absorption to the
non-relaxed excited states. Unlike the case of free strong-coupling polarons,
where the ratio \kappa of the photoionization energy to the thermal
dissociation energy was shown to be always equal to 3, here this ratio depends
on the Froehlich coupling constant \alpha and the screened Coulomb interaction
strength \beta. Reasonable variation of these two parameters has demonstrated
that the magnitude of \kappa remains usually in the narrow interval from 1 to
2.5. This is in agreement with atomistic calculations and experimental data for
hole O^- polarons bound to the cation vacancy in MgO. The thermal dissociation
energy for the ground self-consistent state and the energy of the optically
induced charge transfer process (hops of a hole between O^{2-} ions) have been
calculated using the quantum-chemical method INDO. Results obtained within the
two approaches for hole O polarons bound by the cation vacancies (V^-) in
MgO and by the Mg^{2+} impurity (V_{Mg}) in corundum are compared to
experimental data and to each other. We discuss a surprising closeness of the
results obtained on the basis of independent models and their agreement with
experiment.Comment: 13 pages, 2 figures, 2 tables, E-mail addresses:
[email protected], [email protected]
Mass Renormalization in the Su-Schrieffer-Heeger Model
This study of the one dimensional Su-Schrieffer-Heeger model in a weak
coupling perturbative regime points out the effective mass behavior as a
function of the adiabatic parameter , is the
zone boundary phonon energy and is the electron band hopping integral.
Computation of low order diagrams shows that two phonons scattering processes
become appreciable in the intermediate regime in which zone boundary phonons
energetically compete with band electrons. Consistently, in the intermediate
(and also moderately antiadiabatic) range the relevant mass renormalization
signals the onset of a polaronic crossover whereas the electrons are
essentially undressed in the fully adiabatic and antiadiabatic systems. The
effective mass is roughly twice as much the bare band value in the intermediate
regime while an abrupt increase (mainly related to the peculiar 1D dispersion
relations) is obtained at .Comment: To be published in Phys.Rev.B - 3 figure
Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest-Induced Elastic Expansion
Covalently linked single-crystalline porous organic materials are highly desired for structure-property analysis; however, periodically polymerizing organic entities into high dimensional networks is challenging. Here, we report a series of topologically divergent single-crystalline hydrogen-bonded cross-linked organic frameworks (HCOFs) with visible guest-induced elastic expansions, which mutually integrate high structural order and high flexibility into one framework. These HCOFs are synthesized by photo-cross-linking molecular crystals with alkyldithiols of different chain lengths. Their detailed structural information was revealed by single-crystal X-ray analysis and experimental investigations of HCOFs and their corresponding single-crystalline analogues. Upon guest adsorption, HCOF-2 crystals composed of a 3D self-entangled polymer network undergo anisotropic expansion to more than twice their original size, while the 2D-bilayer HCOF-3 crystals exhibit visible, layered sorption bands and form delaminated sheets along the plane of its 2D layers. The dynamic expansion of HCOF networks creates guest-induced porosity with over 473% greater volume than their permanent voids, as calculated from their record-breaking aqueous iodine adsorption capacities. Temperature-gated DMSO sorption investigations illustrated that the flexible nature of cross-linkers in HCOFs provides positive entropy from the coexistence of multiple conformations to allow for elastic expansion and contraction of the frameworks
Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers
As an alternative technology to energy intensive distillations, adsorptive separation by porous solids offers lower energy cost and higher efficiency. Herein we report a topology-directed design and synthesis of a series of Zr-based metal-organic frameworks with optimized pore structure for efficient separation of C6 alkane isomers, a critical step in the petroleum refining process to produce gasoline with high octane rating. Zr6O4(OH)4(bptc)3 adsorbs a large amount of n-hexane but excluding branched isomers. The n-hexane uptake is ~70% higher than that of a benchmark adsorbent, zeolite-5A. A derivative structure, Zr6O4(OH)8(H2O)4(abtc)2, is capable of discriminating all three C6 isomers and yielding a high separation factor for 3-methylpentane over 2,3-dimethylbutane. This property is critical for producing gasoline with further improved quality. Multicomponent breakthrough experiments provide a quantitative measure of the capability of these materials for separation of C6 alkane isomers. A detailed structural analysis reveals the unique topology, connectivity and relationship of these compounds
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