2,014 research outputs found
Mechanism of tribo-chemical reactions of ionic liquids on titanium alloys
In this paper, the tribological, the tribo-chemical reaction mechanisms and desorption properties of three ionic liquids (ILs), [Bu3MeP][ Tf2N], [Bu3MeN][ Tf2N] and [Bu3MeP][ (MeO)2PO2], in contact with titanium and under vacuum conditions are studied with the CATRI © UHV Tribometer developed by IK4-TEKNIKER [1].
The two ILs containing the bis(trifluoromethanesulfonyl)amide anion presented lower coefficient of friction compared to that having the dimethyl phosphate anion. The tribodesorption study revealed that it is required an induction period to decrease the friction coefficient. The end of this period is accelerated in the case of trifluoromethane ionic liquids by the CF3+ release. Hence, the CF3+ reacts with the titanium surface generating a titanium fluoride tribolayer that could act like a catalyst to generate the tribodesorption of ionic liquid cation fragments (CH3+, C2H5+, C3H7+, C4H9+).
The XPS analysis confirmed the generation of a boundary film, comprising of sulfide and inorganic fluoride, and being possibly the responsible of decreasing the friction coefficient. The [Bu3MeP][MeO)2PO2] ionic liquid required a long induction period, it did not form any tribolayer and no reduction of friction coefficient, yielding instead a high abrasion and adhesion mechanism. Thus, it can be concluded that bis(trifluoromethanesulfonyl)amide anion is more effective than dimethylphosphate in generating a surface protective film on the titanium surface under the selected test conditions and the testing methodology seems to be useful to understand the tribodesorption mechanism.The partners would like to acknowledge the financing to the Austrian Government financing of COMET K2 Excellence
Centre of Tribology called X-Tribology to carry out this research collaborative activity. The authors also would like to
acknowledge the financing of the EMAITEK Programme by the Basque Country
Spin-1/2 Ising-Heisenberg model with the pair XYZ Heisenberg interaction and quartic Ising interactions as the exactly soluble zero-field eight-vertex model
The spin-1/2 Ising-Heisenberg model with the pair XYZ Heisenberg interaction
and quartic Ising interactions is exactly solved by establishing a precise
mapping relationship with the corresponding zero-field (symmetric) eight-vertex
model. It is shown that the Ising-Heisenberg model with the ferromagnetic
Heisenberg interaction exhibits a striking critical behavior, which manifests
itself through re-entrant phase transitions as well as continuously varying
critical exponents. The changes of critical exponents are in accordance with
the weak universality hypothesis in spite of a peculiar singular behavior to
emerge at a quantum critical point of the infinite order, which occurs at the
isotropic limit of the Heisenberg interaction. On the other hand, the
Ising-Heisenberg model with the antiferromagnetic Heisenberg interaction
surprisingly exhibits less significant changes of both critical temperatures as
well as critical exponents upon varying a strength of the exchange anisotropy
in the Heisenberg interaction.Comment: 11 pages, 9 figure
Wang-Landau study of the random bond square Ising model with nearest- and next-nearest-neighbor interactions
We report results of a Wang-Landau study of the random bond square Ising
model with nearest- () and next-nearest-neighbor ()
antiferromagnetic interactions. We consider the case for
which the competitive nature of interactions produces a sublattice ordering
known as superantiferromagnetism and the pure system undergoes a second-order
transition with a positive specific heat exponent . For a particular
disorder strength we study the effects of bond randomness and we find that,
while the critical exponents of the correlation length , magnetization
, and magnetic susceptibility increase when compared to the
pure model, the ratios and remain unchanged. Thus, the
disordered system obeys weak universality and hyperscaling similarly to other
two-dimensional disordered systems. However, the specific heat exhibits an
unusually strong saturating behavior which distinguishes the present case of
competing interactions from other two-dimensional random bond systems studied
previously.Comment: 9 pages, 3 figures, version as accepted for publicatio
Two dimensional Ising spin glasses with non-zero ordering temperatures
We demonstrate numerically that for Ising spins on square lattices with
ferromagnetic second neighbour interactions and random near neighbour
interactions, two dimensional Ising spin glass order with a non-zero freezing
temperature can occur. We compare some of the physical properties of these spin
glasses with those of standard spin glasses in higher dimensions.Comment: 9 page latex file and 9 ps figures. To appear in Phys. Rev. Let
Quenched bond randomness in marginal and non-marginal Ising spin models in 2D
We investigate and contrast, via entropic sampling based on the Wang-Landau
algorithm, the effects of quenched bond randomness on the critical behavior of
two Ising spin models in 2D. The random bond version of the
superantiferromagnetic (SAF) square model with nearest- and
next-nearest-neighbor competing interactions and the corresponding version of
the simple Ising model are studied and their general universality aspects are
inspected by a detailed finite-size scaling (FSS) analysis. We find that, the
random bond SAF model obeys weak universality, hyperscaling, and exhibits a
strong saturating behavior of the specific heat due to the competing nature of
interactions. On the other hand, for the random Ising model we encounter some
difficulties for a definite discrimination between the two well-known scenarios
of the logarithmic corrections versus the weak universality. Yet, a careful FSS
analysis of our data favors the field-theoretically predicted logarithmic
corrections.Comment: 19 pages, 5 figures, final versio
Quantum Diffusion and Eigenfunction Delocalization in a Random Band Matrix Model
We consider Hermitian and symmetric random band matrices in
dimensions. The matrix elements , indexed by , are independent, uniformly distributed random variables if \abs{x-y}
is less than the band width , and zero otherwise. We prove that the time
evolution of a quantum particle subject to the Hamiltonian is diffusive on
time scales . We also show that the localization length of an
arbitrarily large majority of the eigenvectors is larger than a factor
times the band width. All results are uniform in the size
\abs{\Lambda} of the matrix.Comment: Minor corrections, Sections 4 and 11 update
The development and characteristics of a hand-held high power diode laser-based industrial tile grout removal and single-stage sealing system
As the field of laser materials processing becomes ever more diverse, the high power diode laser (HPDL) is now being regarded by many as the most applicable tool. The commercialisation of an industrial epoxy grout removal and single-stage ceramic tile grout sealing process is examined through the development of a hand-held HPDL device in this work. Further, an appraisal of the potential hazards associated with the use of the HPDL in an industrial environment and the solutions implemented to ensure that the system complies with the relevant safety standards are given. The paper describes the characteristics and feasibility of the industrial epoxy grout removal process. A minimum power density of approximately 3 kW/cm2 was found to exist, whilst the minimum interaction time, below which there was no removal of epoxy tile grout, was found to be approximately 0.5 s. The maximum theoretical removal rate that may be achievable was calculated as being 65.98 mm2/s for a circular 2 mm diameter beam with a power density of 3 kW/cm2 and a traverse speed of 42 mm/s. In addition, the characteristics of the single-stage ceramic tile grout sealing are outlined. The single-stage ceramic tile grout sealing process yielded crack and porosity free seals which were produced in normal atmospheric conditions. Tiles were successfully sealed with power densities as low as 550 W/cm2 and at rates of up to 420 mm/min. In terms of mechanical, physical and chemical characteristics, the single-stage ceramic tile grout was found to be far superior to the conventional epoxy tile grout and, in many instances, matched and occasionally surpassed that of the ceramic tiles themselves
Kinetics of exciton photoluminescence in type-II semiconductor superlattices
The exciton decay rate at a rough interface in type-II semiconductor
superlattices is investigated. It is shown that the possibility of
recombination of indirect excitons at a plane interface essentially affects
kinetics of the exciton photoluminescence at a rough interface. This happens
because of strong correlation between the exciton recombination at the plane
interface and at the roughness. Expressions that relate the parameters of the
luminescence kinetics with statistical characteristics of the rough interface
are obtained. The mean height and length of roughnesses in GaAs/AlAs
superlattices are estimated from the experimental data.Comment: 3 PostScript figure
ALPGEN, a generator for hard multiparton processes in hadronic collisions
This paper presents a new event generator, ALPGEN, dedicated to the study of
multiparton hard processes in hadronic collisions. The code performs, at the
leading order in QCD and EW interactions, the calculation of the exact matrix
elements for a large set of parton-level processes of interest in the study of
the Tevatron and LHC data. The current version of the code describes the
following final states: (W -> ffbar') QQbar+ N jets (Q being a heavy quark, and
f=l,q), with N f fbar)+QQbar+Njets (f=l,nu), with N
ffbar') + charm + N jets (f=l,q), N f fbar') + N jets (f=l,q) and
(Z/gamma* -> f fbar)+ N jets (f=l,nu), with N<=6; nW+mZ+lH+N jets, with
n+m+l+N<=8 and N<=3 including all 2-fermion decay modes of W and Z bosons, with
spin correlations; Q Qbar+N jets (N b f fbar' decays and relative
spin correlations included if Q=t; Q Qbar Q' Qbar'+N jets, with Q and Q' heavy
quarks (possibly equal) and N b f fbar'
decays and relative spin correlations included if Q=t; N jets, with N<=6.
Parton-level events are generated, providing full information on their colour
and flavour structure, enabling the evolution of the partons into fully
hadronised final states.Comment: 1+38 pages, uses JHEP.cls. Documents code version 1.2: extended list
of processes, updated documentation and bibliograph
Cisplatin-induced emesis: systematic review and meta-analysis of the ferret model and the effects of 5-HT3 receptor antagonists
PURPOSE: The ferret cisplatin emesis model has been used for ~30 years and enabled identification of clinically used anti-emetics. We provide an objective assessment of this model including efficacy of 5-HT(3) receptor antagonists to assess its translational validity. METHODS: A systematic review identified available evidence and was used to perform meta-analyses. RESULTS: Of 182 potentially relevant publications, 115 reported cisplatin-induced emesis in ferrets and 68 were included in the analysis. The majority (n = 53) used a 10 mg kg(−1) dose to induce acute emesis, which peaked after 2 h. More recent studies (n = 11) also used 5 mg kg(−1), which induced a biphasic response peaking at 12 h and 48 h. Overall, 5-HT(3) receptor antagonists reduced cisplatin (5 mg kg(−1)) emesis by 68% (45–91%) during the acute phase (day 1) and by 67% (48–86%) and 53% (38–68%, all P < 0.001), during the delayed phase (days 2, 3). In an analysis focused on the acute phase, the efficacy of ondansetron was dependent on the dosage and observation period but not on the dose of cisplatin. CONCLUSION: Our analysis enabled novel findings to be extracted from the literature including factors which may impact on the applicability of preclinical results to humans. It reveals that the efficacy of ondansetron is similar against low and high doses of cisplatin. Additionally, we showed that 5-HT(3) receptor antagonists have a similar efficacy during acute and delayed emesis, which provides a novel insight into the pharmacology of delayed emesis in the ferret
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