Nach dem Deutschstudium in Afrika wird man – was? Eine Überprüfung der Zielsetzungen der Deutschabteilung der Universität Lomé anhand einer Verbleibstudie

This paper reports on an investigation of the value of German Studies in eventual employment of students in this field. The objectives of German Studies in Africa have to include an indication of how inclusion in the curriculum is legitimized. Three approaches towards legitimization have developed since the establishment of German Departments at African Universities, namely (i) German Studies with a view to research and epistemological science, (ii) German in intercultural studies, and (iii)career-oriented German language learning. In this paper the implementation of these approaches will be examined on the basis of the objectives set out by the German Department at the University ofLomé. This will be done by discussing the results of a survey on the professional whereabouts of Togolese German Studies graduates to demonstrate the extent to which the objectives of the various approaches have been met. The paper concludes with a discussion of the implications of the findings for the programmes of the German Department at the University of Lomé.Keywords: legitimization debate, distribution survey, teaching German in Africa, German language and literature studies in AfricaSchlüsselbegriffe: Legitimierungsdebatte, Verbleibstudie, Deutschunterricht in Afrika, Germanistik in Afrik

Improved preparation of 9-octadecenes

Organic synthesis of cis-9 and trans-9 octadecenes from oleyl alcohol and elaidyl alcohol, respectively, by conversion to tosylates followed by lithium aluminum hydride reductio

Coherence properties of infrared thermal emission from heated metallic nanowires

Coherence properties of the infrared thermal radiation from individual heated nanowires are investigated as function of nanowire dimensions. Interfering the thermally induced radiation from a heated nanowire with its image in a nearby moveable mirror, well-defined fringes are observed. From the fringe visibility, the coherence length of the thermal emission radiation from the narrowest nanowires was estimated to be at least 20 um which is much larger than expected from a classical blackbody radiator. A significant increase in coherence and emission efficiency is observed for smaller nanowires.Comment: 4 pages,figures include

The Origins of a Rich Absorption Line Complex in a Quasar at Redshift 3.45

We discuss the nature and origin of a rich complex of narrow absorption lines in the quasar J102325.31+514251.0 at redshift 3.447. We measure nine C IV(\lambda1548,1551) absorption line systems with velocities from -1400 to -6200 km/s, and full widths at half minimum ranging from 16 to 350 km/s. We also detect other absorption lines in these systems, including H I, C III, N V, O VI, and Si IV. Lower ionisation lines are not present, indicating a generally high degree of ionisation in all nine systems. The total hydrogen column densities range from <=10^{17.2} to 10^{19.1}cm^{-2}. We examine several diagnostics to estimate more directly the location and origin of each absorber. Four of the systems can be attributed to a quasar-driven outflow based on line profiles that are smooth and broad compared to thermal line widths. Several systems also have other indicators of a quasar outflow origin, including partial covering. Altogether there is direct evidence for 6 of the 9 systems forming in a quasar outflow. Consistent with a near-quasar origin, eight of the systems have metallicity values or lower limits in the range Z >= 1-8 Z_{sun}. The lowest velocity system, which has an ambiguous location, also has the lowest metallicity, Z <= 0.3 Z_{sun}, and might form in a non-outflow environment farther from the quasar. Overall, however, this complex of narrow absorption lines can be identified with a highly structured, multi-component outflow from the quasar. The high metallicities are similar to those derived for other quasars at similar redshifts and luminosities, and are consistent with evolution scenarios wherein quasars appear after the main episodes of star formation and metal enrichment in the host galaxies.Comment: 16 pages, 12 figures, Accepted to MNRAS, July 201

Optimising Boltzmann codes for the Planck era

High precision measurements of the Cosmic Microwave Background (CMB) anisotropies, as can be expected from the Planck satellite, will require high-accuracy theoretical predictions as well. One possible source of theoretical uncertainty is the numerical error in the output of the Boltzmann codes used to calculate angular power spectra. In this work, we carry out an extensive study of the numerical accuracy of the public Boltzmann code CAMB, and identify a set of parameters which determine the error of its output. We show that at the current default settings, the cosmological parameters extracted from data of future experiments like Planck can be biased by several tenths of a standard deviation for the six parameters of the standard Lambda-CDM model, and potentially more seriously for extended models. We perform an optimisation procedure that leads the code to achieve sufficient precision while at the same time keeping the computation time within reasonable limits. Our conclusion is that the contribution of numerical errors to the theoretical uncertainty of model predictions is well under control -- the main challenges for more accurate calculations of CMB spectra will be of an astrophysical nature instead.Comment: 13 pages, 4 figure

Axions and saxions from the primordial supersymmetric plasma and extra radiation signatures

We calculate the rate for thermal production of axions and saxions via scattering of quarks, gluons, squarks, and gluinos in the primordial supersymmetric plasma. Systematic field theoretical methods such as hard thermal loop resummation are applied to obtain a finite result in a gauge-invariant way that is consistent to leading order in the strong gauge coupling. We calculate the thermally produced yield and the decoupling temperature for both axions and saxions. For the generic case in which saxion decays into axions are possible, the emitted axions can constitute extra radiation already prior to big bang nucleosynthesis and well thereafter. We update associated limits imposed by recent studies of the primordial helium-4 abundance and by precision cosmology of the cosmic microwave background and large scale structure. We show that the trend towards extra radiation seen in those studies can be explained by late decays of thermal saxions into axions and that upcoming Planck results will probe supersymmetric axion models with unprecedented sensitivity.Comment: 16 pages, 7 figures; v2: references added, minor clarifying additions, matches published versio

New One-Pot Methodologies for the Modification or Synthesis of Alkaloid Scaffolds

There are several avenues by which promising bioactive natural products can be produced in sufficient quantities to enable lead optimization and medicinal chemistry studies. The total synthesis of natural products is an important, but sometimes difficult, approach and requires the development of innovative synthetic methodologies to simplify the synthesis of complex molecules. Various classes of natural product alkaloids are both common and widely distributed in plants, bacteria, fungi, insects and marine organisms. This mini-review will discuss the scope, mechanistic insights and enantioselectivity aspects of selected examples of recently developed one-pot methods that have been published in 2009 for the synthesis of substituted piperidines, quinolizidines, pyrrolidines, hexahydropyrrolizines, octahydroindolizines and γ-lactams. In addition, progress on the synthesis of β-carboline (manzamine) alkaloids will also be discussed