6,309 research outputs found
Effect of Local Electron-Electron Correlation in Hydrogen-like Impurities in Ge
We have studied the electronic and local magnetic structure of the hydrogen
interstitial impurity at the tetrahedral site in diamond-structure Ge, using an
empirical tight binding + dynamical mean field theory approach because within
the local density approximation (LDA) Ge has no gap. We first establish that
within LDA the 1s spectral density bifurcates due to entanglement with the four
neighboring sp3 antibonding orbitals, providing an unanticipated richness of
behavior in determining under what conditions a local moment hyperdeep donor or
Anderson impurity will result, or on the other hand a gap state might appear.
Using a supercell approach, we show that the spectrum, the occupation, and the
local moment of the impurity state displays a strong dependence on the strength
of the local on-site Coulomb interaction U, the H-Ge hopping amplitude, the
depth of the bare 1s energy level epsilon_H, and we address to some extent the
impurity concentration dependence. In the isolated impurity, strong interaction
regime a local moment emerges over most of the parameter ranges indicating
magnetic activity, and spectral density structure very near (or in) the gap
suggests possible electrical activity in this regime.Comment: 9 pages, 5 figure
Effects of 3-d and 4-d-transition metal substitutional impurities on the electronic properties of CrO2
We present first-principles based density functional theory calculations of
the electronic and magnetic structure of CrO2 with 3d (Ti through Cu) and 4d
(Zr through Ag) substitutional impurities. We find that the half-metallicity of
CrO2 remains intact for all of the calculated substitutions. We also observe
two periodic trends as a function of the number of valence electrons: if the
substituted atom has six or fewer valence electrons (Ti-Cr or Zr-Mo), the
number of down spin electrons associated with the impurity ion is zero,
resulting in ferromagnetic (FM) alignment of the impurity magnetic moment with
the magnetization of the CrO2 host. For substituent atoms with eight to ten
(Fe-Ni or Ru-Pd with the exception of Ni), the number of down spin electrons
contributed by the impurity ion remains fixed at three as the number
contributed to the majority increases from one to three resulting in
antiferromagnetic (AFM) alignment between impurity moment and host
magnetization. The origin of this variation is the grouping of the impurity
states into 3 states with approximate "t2g" symmetry and 2 states with
approximate "eg" symmetry. Ni is an exception to the rule because a
Jahn-Teller-like distortion causes a splitting of the Ni eg states. For Mn and
Tc, which have 8 valence electrons, the zero down spin and 3 down spin
configurations are very close in energy. For Cu and Ag atoms, which have 11
valence electrons, the energy is minimized when the substituent ion contributes
5 Abstract down-spin electrons. We find that the interatomic exchange
interactions are reduced for all substitutions except for the case of Fe for
which a modest enhancement is calculated for interactions along certain
crystallographic directions.Comment: 26 pages, 10 figures, 2 table
Femtosecond probing of bimolecular reactions: The collision complex
Progress has been made in probing the femtosecond
dynamics of transition states of chemical reactions.(1) The
"half-collision" case of unimolecular reactions has been
experimentally investigated for a number of systems and
much theoretical work has already been developed.(2) For
bimolecular reactions, the case of full collision, the zero of
time is a problem which makes the femtosecond temporal
resolution of the dynamics a difficult task
Femtosecond real-time probing of reactions. VIII. The bimolecular reaction Br+I2
In this paper, we discuss the experimental technique for real-time measurement of the lifetimes of the collision complex of bimolecular reactions. An application to the atom–molecule Br+I_2 reaction at two collision energies is made. Building on our earlier Communication [J. Chem. Phys. 95, 7763 (1991)], we report on the observed transients and lifetimes for the collision complex, the nature of the transition state, and the dynamics near threshold. Classical trajectory calculations provide a framework for deriving the global nature of the reactive potential energy surface, and for discussing the real-time, scattering, and asymptotic (product-state distribution) aspects of the dynamics. These experimental and theoretical results are compared with the extensive array of kinetic, crossed beam, and theoretical studies found in the literature for halogen radical–halogen molecule exchange reactions
Theoretical investigation into the possibility of very large moments in Fe16N2
We examine the mystery of the disputed high-magnetization \alpha"-Fe16N2
phase, employing the Heyd-Scuseria-Ernzerhof screened hybrid functional method,
perturbative many-body corrections through the GW approximation, and onsite
Coulomb correlations through the GGA+U method. We present a first-principles
computation of the effective on-site Coulomb interaction (Hubbard U) between
localized 3d electrons employing the constrained random-phase approximation
(cRPA), finding only somewhat stronger on-site correlations than in bcc Fe. We
find that the hybrid functional method, the GW approximation, and the GGA+U
method (using parameters computed from cRPA) yield an average spin moment of
2.9, 2.6 - 2.7, and 2.7 \mu_B per Fe, respectively.Comment: 8 pages, 3 figure
Propagation of Correlations in Quantum Lattice Systems
We provide a simple proof of the Lieb-Robinson bound and use it to prove the
existence of the dynamics for interactions with polynomial decay. We then use
our results to demonstrate that there is an upper bound on the rate at which
correlations between observables with separated support can accumulate as a
consequence of the dynamics.Comment: 10 page
Biaxial fatigue loading of notched composites
Thin walled, 2.54-cm (1-in.) diameter tubular specimens of T300/934 graphite/epoxy were fabricated and fatigue cycled in combinations of axial, torsional, and internal pressure loading. Two different four-ply layup configurations were tested: (0/90)S and (+ or - 45)S; all tubes contained a 0.48-cm (3/16-in.) diameter circular hole penetrating one wall midway along the tube length. S-N curves were developed to characterize fatigue behavior under pure axial, torsional, or internal pressure loading, as well as combined loading fatigue. A theory was developed based on the Hill plane stress model which enabled the S-N curve for combined stress states to be predicted from the S-N data for the uniaxial loading modes. Correlation of the theory with the experimental data proved to be remarkably good
Development of N/P AlGaAs free-standing top solar cells for tandem applications
The combination of a free standing AlGaAs top solar cell and an existing bottom solar cell is the highest performance, lowest risk approach to implementing the tandem cell concept. The solar cell consists of an AlGaAs substrate layer, an AlGaAs base layer, an AlGaAs emitter, and an ultra-thin AlGaAs window layer. The window layer is compositionally graded which minimizes reflection at the window layer/emitter interface and creates a built-in electric field to improve quantum response in the blue region of the spectrum. Liquid phase epitaxy (LPE) is the only viable method to produce this free standing top solar cell. Small (0.125 sq cm), transparent p/n AlGaAs top solar cells were demonstrated with optimum bandgap for combination with a silicon bottom solar cell. The efficiency of an AlGaAs/Si stack using the free standing AlGaAs device upon an existing silicon bottom solar cell is 24 pct. (1X, Air Mass Zero (AM0). The n/p AlGaAs top solar cell is being developed in order to facilitate the wiring configuration. The two terminal tandem stack will retain fit, form, and function of existing silicon solar cells. Progress in the development of large area (8 and 16 sq cm), free standing AlGaAs top solar cells is discussed
Mars rover sample return: An exobiology science scenario
A mission designed to collect and return samples from Mars will provide information regarding its composition, history, and evolution. At the same time, a sample return mission generates a technical challenge. Sophisticated, semi-autonomous, robotic spacecraft systems must be developed in order to carry out complex operations at the surface of a very distant planet. An interdisciplinary effort was conducted to consider how much a Mars mission can be realistically structured to maximize the planetary science return. The focus was to concentrate on a particular set of scientific objectives (exobiology), to determine the instrumentation and analyses required to search for biological signatures, and to evaluate what analyses and decision making can be effectively performed by the rover in order to minimize the overhead of constant communication between Mars and the Earth. Investigations were also begun in the area of machine vision to determine whether layered sedimentary structures can be recognized autonomously, and preliminary results are encouraging
Mars Rover Sample Return: A sample collection and analysis strategy for exobiology
For reasons defined elsewhere it is reasonable to search for biological signatures, both chemical and morphological, of extinct life on Mars. Life on Earth requries the presence of liquid water, therefore, it is important to explore sites on Mars where standing bodies of water may have once existed. Outcrops of layered deposits within the Valles Marineris appear to be ancient lake beds. Because the outcrops are well exposed, relatively shallow core samples would be very informative. The most important biological signature to detect would be organics, microfossils, or larger stromato-like structures, although the presence of cherts, carbonates, clays, and shales would be significant. In spite of the limitations of current robotics and pattern recognition, and the limitations of rover power, computation, Earth communication bandwidth, and time delays, a partial scenario was developed to implement such a scientific investigation. The rover instrumentation and the procedures and decisions and IR spectrometer are described in detail. Preliminary results from a collaborative effort are described, which indicate the rover will be able to autonomously detect stratification, and hence will ease the interpretation burden and lead to greater scientific productivity during the rover's lifetime
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