Erosion/corrosion of turbine airfoil materials in the high-velocity effluent of a pressurized fluidized coal combustor

Four candidate turbine airfoil superalloys were exposed to the effluent of a pressurized fluidized bed with a solids loading of 2 to 4 g/scm for up to 100 hours at two gas velocities, 150 and 270 m/sec, and two temperatures, 730 deg and 795 C. Under these conditions, both erosion and corrosion occurred. The damaged specimens were examined by cross-section measurements, scanning electron and light microscopy, and X-ray analysis to evaluate the effects of temperature, velocity, particle loading, and alloy material. Results indicate that for a given solids loading the extent of erosion is primarily dependent on gas velocity. Corrosion occurred only at the higher temperature. There was little difference in the erosion/corrosion damage to the four alloys tested under these severe conditions

The erosion/corrosion of small superalloy turbine rotors operating in the effluent of a PFB coal combustor

Superalloy turbine rotors in a single stage turbine with 6 percent partial admittance were operated in the effluent of a pressurized fluidized bed coal combustor for up to 164 hours. Total mass flow was 300 kg/hr and average particulate loadings ranged from 600 to 2800 ppm for several coal/sorbent combinations. A 5.5 atm turbine inlet gas pressure and inlet gas temperatures from 700 to 800 C yielded absolute gas velocities at the stator exit of about 500 m/s. The angular rotation speed (40,000 rpm) of the six inch diameter rotors was equivalent to a tip speed of about 300 m/s, and average gas velocities relative to the rotating surface ranged from 260 to 330 m/s at mean radius. The rotor erosion pattern reflects heavy particle separation with severe (5 to 500 cm/yr) erosion at the leading edge, pressure side center, and suction side trailing edge at the tip. The erosion distribution pattern provides a spectrum of erosion/oxidation/deposition as a function of blade position. This spectrum includes enhanced oxidation (10 to 100 x air), mixed oxides in exposed depletion zones, sulfur rich oxides in deposition zones, and rugged areas of erosive oxide removal

An exactly solvable model of a superconducting to rotational phase transition

We consider a many-fermion model which exhibits a transition from a superconducting to a rotational phase with variation of a parameter in its Hamiltonian. The model has analytical solutions in its two limits due to the presence of dynamical symmetries. However, the symmetries are basically incompatible with one another; no simple solution exists in intermediate situations. Exact (numerical) solutions are possible and enable one to study the behavior of competing but incompatible symmetries and the phase transitions that result in a semirealistic situation. The results are remarkably simple and shed light on the nature of phase transitions.Comment: 11 pages including 1 figur

An algebraic approach to problems with polynomial Hamiltonians on Euclidean spaces

Explicit expressions are given for the actions and radial matrix elements of basic radial observables on multi-dimensional spaces in a continuous sequence of orthonormal bases for unitary SU(1,1) irreps. Explicit expressions are also given for SO(N)-reduced matrix elements of basic orbital observables. These developments make it possible to determine the matrix elements of polynomial and a other Hamiltonians analytically, to within SO(N) Clebsch-Gordan coefficients, and to select an optimal basis for a particular problem such that the expansion of eigenfunctions is most rapidly convergent.Comment: 19 pages, 8 figure

Reversable heat flow through the carbon nanotube junctions

Microscopic mechanisms of externally controlled reversable heat flow through the carbon nanotube junctions (NJ) are studied theoretically. Our model suggests that the heat is transfered along the tube section ${\cal T}$ by electrons ($e$) and holes ($h$) moving ballistically in either in parallel or in opposite directions and accelerated by the bias source-drain voltage $V_{\rm SD}$ (Peltier effect). We compute the Seebeck coefficient $\alpha$, electric $\sigma$ and thermal $\kappa$ conductivities and find that their magnitudes strongly depend on $V_{\rm SD}$ and $V_{\rm G}$. The sign reversal of $\alpha$ versus the sign of $V_{\rm G}$ formerly observed experimentally is interpreted in this work in terms of so-called chiral tunneling phenomena (Klein paradox)

Richardson-Gaudin integrability in the contraction limit of the quasispin

Background: The reduced, level-independent, Bardeen-Cooper-Schrieffer Hamiltonian is exactly diagonalizable by means of a Bethe Ansatz wavefunction, provided the free variables in the Ansatz are the solutions of the set of Richardson-Gaudin equations. On the one side, the Bethe Ansatz is a simple product state of generalised pair operators. On the other hand, the Richardson-Gaudin equations are strongly coupled in a non-linear way, making them prone to singularities. Unfortunately, it is non-trivial to give a clear physical interpretation to the Richardson-Gaudin variables because no physical operator is directly related to the individual variables. Purpose: The purpose of this paper is to shed more light on the critical behavior of the Richardson-Gaudin equations, and how this is related to the product wave structure of the Bethe Ansatz. Method: A pseudo-deformation of the quasi-spin algebra is introduced, leading towards a Heisenberg-Weyl algebra in the contraction limit of the deformation parameter. This enables an adiabatic connection of the exact Bethe Ansatz eigenstates with pure bosonic multiphonon states. The physical interpretation of this approach is an adiabatic suppression of the Pauli exclusion principle. Results: The method is applied to a so-called "picket-fence" model for the BCS Hamiltonian, displaying a typical critical behavior in the Richardson-Gaudin variables. It was observed that the associated bosonic multiphonon states change collective nature at the critical interaction strengths of the Richardson-Gaudin equations. Conclusions: The Pauli exclusion principle is the main responsible for the critical behavior of the Richardson-Gaudin equations, which can be suppressed by means of a pseudo deformation of the quasispin algebra.Comment: PACS 02.30.Ik, 21.10.Re, 21.60.Ce, 74.20.F

Vector coherent state representations, induced representations, and geometric quantization: II. Vector coherent state representations

It is shown here and in the preceeding paper (quant-ph/0201129) that vector coherent state theory, the theory of induced representations, and geometric quantization provide alternative but equivalent quantizations of an algebraic model. The relationships are useful because some constructions are simpler and more natural from one perspective than another. More importantly, each approach suggests ways of generalizing its counterparts. In this paper, we focus on the construction of quantum models for algebraic systems with intrinsic degrees of freedom. Semi-classical partial quantizations, for which only the intrinsic degrees of freedom are quantized, arise naturally out of this construction. The quantization of the SU(3) and rigid rotor models are considered as examples.Comment: 31 pages, part 2 of two papers, published versio

Vector coherent state representations, induced representations, and geometric quantization: I. Scalar coherent state representations

Coherent state theory is shown to reproduce three categories of representations of the spectrum generating algebra for an algebraic model: (i) classical realizations which are the starting point for geometric quantization; (ii) induced unitary representations corresponding to prequantization; and (iii) irreducible unitary representations obtained in geometric quantization by choice of a polarization. These representations establish an intimate relation between coherent state theory and geometric quantization in the context of induced representations.Comment: 29 pages, part 1 of two papers, published versio

Liver transplantation for arteriohepatic dysplasia (Alagille's syndrome)

Thirteen out of 268 children (<18 years old) underwent hepatic transplantation (OLT) for end-stage liver disease (ESLD) associated with arteriohepatic dysplasia (AHD). Seven children are alive and well with normal liver function. Six children died, four within 11 days of the operation and the other two at 4 and 10 months after the OLT. Vascular complications with associated septicemia were responsible for the deaths of three children. Two died of heart failure and circulatory collapse, secondary to pulmonary hypertension and congenital heart disease. The remaining patient died of overwhelming sepsis not associated with technical complications. Seven patients had a portoenterostomy or portocholecystostomy early in life; five of these died after the OLT. Severe cardiovascular abnormalities in some of our patients suggest that complete hemodynamic monitoring with invasive studies should be performed in all patients with AHD, especially in cases of documented hypertrophy of the right ventricle. The improved quality of life in our surviving patients confirms the validity of OLT as a treatment of choice in cases of ESLD due to AHD. © 1992 Springer-Verlag

The Skyrme energy functional and low lying 2+ states in Sn, Cd and Te isotopes

We study the predictive power of Skyrme forces with respect to low lying quadrupole spectra along the chains of Sn, Cd, and Te isotopes. Excitation energies and B(E2) values for the lowest quadrupole states are computed from a collective Schroedinger equation which as deduced through collective path generated by constraint Skyrme-Hartree-Fock (SHF) plus self-consistent cranking for the dynamical response. We compare the results from four different Skyrme forces, all treated with two different pairing forces (volume versus density-dependent pairing). The region around the neutron shell closure N=82 is very sensitive to changes in the Skyrme while the mid-shell isotopes in the region N<82 depend mainly on the adjustment of pairing. The neutron rich isotopes are most sensitive and depend on both aspects