159 research outputs found
Structure and dielectric response in the high ferroelectric Bi(Zn,Ti)O-PbTiO solid solutions
Theoretical {\em ab initio} and experimental methods were used to investigate
the Bi(Zn,Ti)O-(1-)PbTiO (BZT-PT) solid solution. We find that
hybridization between Zn 4 and O 2 orbitals allows the formation of
short, covalent Zn-O bonds, enabling favorable coupling between A-site and
B-site displacements. This leads to large polarization, strong tetragonality
and an elevated ferroelectric to paraelectric phase transition temperature.
nhomogeneities in local structure near the 90 domain boundaries can be
deduced from the asymetric peak broadening in the neutron and x-ray diffraction
spectra. These extrinsic effects make the ferroelectric to paraelectric phase
transition diffuse in BZT-PT solid solutions
Synchronous population fluctuations of forest and field voles: implications for population management
Tkadlec, E., Suchomel, J., Purchart, L., Heroldová, M., Čepelka, L., Homolka, M
Structure and Polarization in the High T\u3csub\u3ec\u3c/sub\u3e Ferroelectric Bi(Zn,Ti)O\u3csub\u3e3\u3c/sub\u3e-PbTiO\u3csub\u3e3\u3c/sub\u3e Solid Solutions
Theoretical ab initio and experimental methods are used to investigate the [Bi(Zn1/2Ti1/2)O3]x [PbTiO3]1-x solid solution. We find that hybridization between Zn 4s and 4p and O 2p orbitals allows the formation of short, covalent Zn-O bonds, enabling favorable coupling between A-site and B-site displacements. This leads to unusually large polarization, strong tetragonality, and an elevated ferroelectric to paraelectric phase transition temperature
Vole impact on tree regeneration: insights into forest management
Heroldová, M., Homolka, M., Tkadlec, E., Kamler, J., Suchomel, J., Purchart, L., Krojerová, J., Barančeková, M., Turek, K., Baňař, M
Charge disproportionation and the pressure-induced insulator?metal transition in cubic perovskite PbCrO3
The perovskite PbCrO3 is an antiferromagnetic insulator. However, the fundamental interactions leading to the insulating state in this single-valent perovskite are unclear. Moreover, the origin of the unprecedented volume drop observed at a modest pressure of P = 1.6 GPa remains an outstanding problem. We report a variety of in situ pressure measurements including electron transport properties, X-ray absorption spectrum, and crystal structure study by X-ray and neutron diffraction. These studies reveal key information leading to the elucidation of the physics behind the insulating state and the pressure-induced transition. We argue that a charge disproportionation 3Cr4+ → 2Cr3+ + Cr6+ in association with the 6s-p hybridization on the Pb2+ is responsible for the insulating ground state of PbCrO3 at ambient pressure and the charge disproportionation phase is suppressed under pressure to give rise to a metallic phase at high pressure. The model is well supported by density function theory plus the correlation energy U (DFT+U) calculations.Fil: Cheng, Jinguang. University Of Texas At Austin; Estados Unidos. Chinese Academy Of Sciences; República de China. University of Tokyo. Institute for Solid State Physics; JapónFil: Kweon, K. E.. University Of Texas At Austin; Estados UnidosFil: Larregola, Sebastian Alberto. University Of Texas At Austin; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Ding, Yang. Argonne National Laboratory; Estados UnidosFil: Shirako, Y.. University Of Texas At Austin; Estados UnidosFil: Marshall, L. G.. University Of Texas At Austin; Estados Unidos. Northeastern University; Estados UnidosFil: Li, Z. Y.. University Of Texas At Austin; Estados UnidosFil: Li, X.. University Of Texas At Austin; Estados UnidosFil: Dos Santos, António M.. Oak Ridge National Laboratory. Quantum Condensed Matter Division; Estados UnidosFil: Suchomel, M. R.. Argonne National Laboratory; Estados UnidosFil: Matsubayashi, K.. University of Tokyo. Institute for Solid State Physics; JapónFil: Uwatoko, Y.. University of Tokyo. Institute for Solid State Physics; JapónFil: Hwang, G. S.. University Of Texas At Austin; Estados UnidosFil: Goodenough, John B.. University Of Texas At Austin; Estados UnidosFil: Zhou, J. S.. University Of Texas At Austin; Estados Unido
Photon-number-resolved measurement of an exciton-polariton condensate
We measure the full photon-number distribution emitted from a Bose condensate of microcavity exciton polaritons confined in a micropillar cavity. The statistics are acquired by means of a photon-number-resolving transition edge sensor. We directly observe that the photon-number distribution evolves with the nonresonant optical excitation power from geometric to quasi-Poissonian statistics, which is canonical for a transition from a thermal to a coherent state. Moreover, the photon-number distribution allows one to evaluate the higher-order photon correlations, shedding further light on the coherence formation and phase transition of the polariton condensate. The experimental data are analyzed in terms of thermal-coherent states, which gives direct access to the thermal and coherent fraction from the measured distributions. These results pave the way for a full understanding of the contribution of interactions in light-matter condensates in the coherence buildup at threshold.Ministry of Science and Education of the Russian Federation (Grant No. RFMEFI61617X0085
Magnetic and structural properties of the iron silicide superconductor LaFeSiH
The magnetic and structural properties of the recently discovered
pnictogen/chalcogen-free superconductor LaFeSiH (~K) have been
investigated by Fe synchrotron M{\"o}ssbauer source (SMS) spectroscopy,
x-ray and neutron powder diffraction and Si nuclear magnetic resonance
spectroscopy (NMR). No sign of long range magnetic order or local moments has
been detected in any of the measurements and LaFeSiH remains tetragonal down to
2 K. The activated temperature dependence of both the NMR Knight shift and the
relaxation rate is analogous to that observed in strongly overdoped
Fe-based superconductors. These results, together with the
temperature-independent NMR linewidth, show that LaFeSiH is an homogeneous
metal, far from any magnetic or nematic instability, and with similar Fermi
surface properties as strongly overdoped iron pnictides. This raises the
prospect of enhancing the of LaFeSiH by reducing its carrier
concentration through appropriate chemical substitutions. Additional SMS
spectroscopy measurements under hydrostatic pressure up to 18.8~GPa found no
measurable hyperfine field
Counter-directional polariton coupler
The Wurzburg group acknowledges the financial support by the state of Bavaria and the DFG within the project Schn1376-3.1. J.B. and S.K. acknowledge funding from DFG grant KL3124/2-1. The Madrid team acknowledges financial support by the Spanish MINECO Grants MAT2014-53119-C2-1-R and MAT2017-83722-R.We report on an on-chip routing device for propagating condensates of exciton-polaritons. This counter-directional coupler implements signal control by a photonic microdisk potential, which couples two lithographically defined waveguides and reverses the condensate's propagation direction. By varying the structural sizes, we utilize the conjunction of the different dimensionalities to additionally evidence the functionality of a polaritonic resonant tunnel diode. Furthermore, we show the ultra fast time dynamics of the device via ps-resolved streak camera measurements. This scalable, all-directional coupler element is a central building block for compact non-linear on-chip photonic architectures.PostprintPeer reviewe
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