Jupiter as an exoplanet: UV to NIR transmission spectrum reveals hazes, a Na layer and possibly stratospheric H2O-ice clouds

Currently, the analysis of transmission spectra is the most successful technique to probe the chemical composition of exoplanet atmospheres. But the accuracy of these measurements is constrained by observational limitations and the diversity of possible atmospheric compositions. Here we show the UV-VIS-IR transmission spectrum of Jupiter, as if it were a transiting exoplanet, obtained by observing one of its satellites, Ganymede, while passing through Jupiter's shadow i.e., during a solar eclipse from Ganymede. The spectrum shows strong extinction due to the presence of clouds (aerosols) and haze in the atmosphere, and strong absorption features from CH4. More interestingly, the comparison with radiative transfer models reveals a spectral signature, which we attribute here to a Jupiter stratospheric layer of crystalline H2O ice. The atomic transitions of Na are also present. These results are relevant for the modeling and interpretation of giant transiting exoplanets. They also open a new technique to explore the atmospheric composition of the upper layers of Jupiter's atmosphere.Comment: Accepted for publication in ApJ Letter

Genetic Variants and Phenotypic Characteristics ofSalmonellaTyphimurium-Resistant Mutants after Exposure to Carvacrol

The emergence of antimicrobial resistance has raised questions about the safety of essential oils and their individual constituents as food preservatives and as disinfection agents. Further research is required to understand how and under what conditions stable genotypic resistance might occur in food pathogens. Evolution experiments onSalmonellaTyphimurium cyclically exposed to sublethal and lethal doses of carvacrol permitted the isolation of SeSCar and SeLCar strains, respectively. Both evolved strains showed a significant increase in carvacrol resistance, assessed by minimum inhibitory and bactericidal concentrations, the study of growth kinetics in the presence of carvacrol, and the evaluation of survival under lethal conditions. Moreover, antibiotic susceptibility tests revealed a development of SeLCar resistance to a wide range of antibiotics. Whole genome sequencing allowed the identification of single nucleotide variations in transcriptional regulators of oxidative stress-response:yfhPin SeSCar andsoxRin SeLCar, which could be responsible for the increased resistance by improving the response to carvacrol and preventing its accumulation inside the cell. This study demonstrates the emergence of S. Typhimurium-resistant mutants against carvacrol, which might pose a risk to food safety and should therefore be considered in the design of food preservation strategies, or of cleaning and disinfection treatments

Thermoluminescent Characteristics of Li2B4O7 Doped with Mn2+ and Eu3+ Ions

Analysis of thermoluminescent properties were made for two samples; Li2B4O7, Li2B4O7:Mn2+:Eu3+. These samples were prepared by melt quenching method. The glow curves of the samples show two broad peaks at 160º C and 245 ºC, and a high peak at 130ºC for Li2B4O7 doped. The response of the materials were analyzed according to the doses (0.2-80 Gy), fading (0-72 hours) and reproducibility of the experiment (10 times). To determine how the glow curve is formed, thermal bleaching for a dose of 5 Gy were made from room temperature to 300º C. Besides, X-ray diffraction patterns were recorded to identify the structure and grain size of the samples

Funding models in palliative care: lessons from international experience

Background:Funding models influence provision and development of palliative care services. As palliative care integrates into mainstream health care provision, opportunities to develop funding mechanisms arise. However, little has been reported on what funding models exist or how we can learn from them.Aim:To assess national models and methods for financing and reimbursing palliative care.Design:Initial literature scoping yielded limited evidence on the subject as national policy documents are difficult to identify, access and interpret. We undertook expert consultations to appraise national models of palliative care financing in England, Germany, Hungary, Republic of Ireland, New Zealand, The Netherlands, Norway, Poland, Spain, Sweden, Switzerland, the United States and Wales. These represent different levels of service development and a variety of funding mechanisms.Results:Funding mechanisms reflect country-specific context and local variations in care provision. Patterns emerging include the following:Provider payment is rarely linked to population need and often perpetuates existing inequitable patterns in service provision.Funding is frequently characterised as a mixed system of charitable, public and private payers.The basis on which providers are paid for services rarely reflects individual care input or patient needs.Conclusion:Funding mechanisms need to be well understood and used with caution to ensure best practice and minimise perverse incentives. Before we can conduct cross-national comparisons of costs and impact of palliative care, we need to understand the funding and policy context for palliative care in each country of interest

Non stoichiometry effect and disorder in Cu2ZnSnS4 thin films obtained by flash evaporation Raman scattering investigation

The cation disorder in Cu2ZnSnS4 thin films grown by flash evaporation of ZnS, CuS and SnS binary compounds has been studied by Raman spectroscopy. Process parameters such as the substrate temperature during the evaporation and the Ar pressure in the post-thermal treatment determined the samples' composition and Raman spectra. As a measure of cation disorder, the half-width and relative intensity of the Raman band peaking at 331-332 cm-1 is analysed. Comparison of the spectra for different samples of known composition showed that the relative intensity of the 331 cm-1 defect peak correlates with the previously reported theoretical prediction about enhancement of antisite defect formation in Cu2ZnSnS4 under "Cu-poor, Zn-rich" conditions. For "Cu-rich, Zn-poor" films, further experimental confirmation was obtained of the previously detected effect of the enhancement of cation disorder under intense optical excitationThis research is supported by the People Programme (Marie Curie Actions) of the European Union’s Seventh Framework Program FP7/2007-2013/ under REA grant greement 269167 (PVICOKEST), the Spanish MINECO project (KEST- PV, ENE2010-21541-C03) and the OPTEC grant. RC acknowledges financial support from Spanish MINECO within the program Ramon y Cajal (RYC-2011-08521

Spectroscopic ellipsometry study of Cu2ZnSnS4 bulk poly-crystals

The linear optical properties of Cu2ZnSnS4 bulk poly-crystals have been investigated using spectroscopic ellipsometry in the range of 1.2-4.6 eV at room temperature. The characteristic features identified in the optical spectra are explained by using the Adachi analytical model for the interband transitions at the corresponding critical points in the Brillouin zone. The experimental data have been modeled over the entire spectral range taking into account the lowest E0 transition near the fundamental absorption edge and E1A and E1B higher energy interband transitions. In addition, the spectral dependences of the refractive index, extinction coefficient, absorption coefficient, and normal-incidence reflectivity values have been accurately determined and are provided since they are essential data for the design of Cu2ZnSnS4 based optoelectronic devicesThe research leading to the presented results was partially supported by the European Project INFINITE-CELL (Ref. H2020-MSCA-RISE-2017-777968, 2017–2021, www.infinitecell.eu) and the Spanish MINECO Projects “WINCOST” (ENE2016-80788-C5-2-R) and PHOTOMANA (TEC2015- 69916-C2-1-R). The authors from the Institute of Applied Physics appreciate the financial support from STCU 6224 and from the Institutional Project No. CSSDT 15.817.02.04

Study of secondary muons detected within the tunnels of the Cholula pyramid

The pyramid of Cholula was built at the beginning of 100 B.C. and during of period of 500 years it was finished, had several new constructions, based on the previous constructions. The primarily material of construction is the adobe. Early in 1931 archaeological excavations began with the intention of exploring the interior of the pyramid, excavations were stopped in 1971, and to date no further excavations have been carried out. This work shows the first measurements of muons, particles that are very penetrating, these are generated by primary cosmic rays that was incoming in the atmosphere and these generates a rain of secondary particles, among them the muons. To measure this kind of particles was implemented a detector system, it is formed by a scintillator plastic coupled to a tube photomultiplier; the signals were acquired by mean of an oscilloscope. The detector was collocated near of the center of the pyramid; the location belongs to the maxima concentration in mass over the detector. Graphs of the charge distribution, maximum amplitude and characteristic rise times of the generated pulses in a plastic scintillator are shown, this is scintillator was synthesized in the materials laboratory of the FCFM-BUAP. In addition the optical characterization of the same was realized

Band-gap engineering of Cu2ZnSn1-xGe xS4 single crystals and influence of the surface properties

Thin film solar cells based on Cu2ZnSn(S,Se)4 are very promising, because they contain earth-abundant elements and show high absorptivity. However, the performance of these solar cells needs to be improved in order to reach efficiencies as high as that reported for Cu(In,Ga)Se 2-based devices. This study investigates the potential of band-gap engineering of Cu2ZnSn1-xGexS 4 single crystals grown by chemical vapour transport as a function of the [Ge]/([Sn] + [Ge]) atomic ratio. The fundamental band gap E0 is found to change from 1.59 to 1.94 eV when the Ge content is increased from x = 0.1 to x = 0.5, as determined from spectroscopic ellipsometry measurements. This knowledge opens a route to enhancing the performance of kesterite-based photovoltaic devices by a Ge-graded absorber layer. Furthermore, the formation of GeO2 on the surface of the as-grown samples was detected by X-ray photoelectron spectroscopy, having an important impact on the effective optical response of the material. This should be also taken into account when designing photovoltaic solar cellsRC acknowledges financial support from Spanish MINECO within the program Ramón y Cajal (RYC-2011-08521). This work was supported by the Marie Curie-IRSES project (PVICOKEST, GA: 269167), MINECO projects (KEST-PV, ENE2010-21541-C03-01/-02/-03) and Marie Curie-ITN project (KESTCELL, GA: 316488