Dimensionality-driven spin-flop transition in quasi-one-dimensional PrBa2Cu4O8

In the quasi-one-dimensional cuprate PrBa$_2$Cu$_4$O$_8$, the Pr cations order antiferromagnetically at 17 K in zero field. Through a combination of magnetic susceptibility, torque magnetometry, specific heat and interchain transport measurements, the anisotropic temperature-magnetic field phase diagram associated with this ordering has been mapped out. A low-temperature spin-flop transition in the Pr sub-lattice is found to occur at the same magnetic field strength and orientation as a dimensional crossover in the ground state of the metallic CuO chains. This coincidence suggests that the spin reorientation is driven by a change in the anisotropic Rudermann-Kittel-Kasuya-Yosida (RKKY) interaction induced by a corresponding change in effective dimensionality of the conduction electrons.Comment: 8 pages, 8 figure

Irradiation-induced confinement in a quasi-one-dimensional metal

The anisotropic resistivity of PrBa$_2$Cu$_4$O$_8$ has been measured as a function of electron irradiation fluence. Localization effects are observed for extremely small amounts of disorder corresponding to electron mean-free-paths of order 100 unit cells. Estimates of the localization corrections suggest that this anomalous localization threshold heralds a crossover to a ground state with pronounced one-dimensional character in which conduction electrons become confined to a small cluster of chains.Comment: 4 pages, 4 figure

Possible co-existence of local itinerancy and global localization in a quasi-one-dimensional conductor

In the chain compound PrBa$_2$Cu$_4$O$_8$ localization appears simultaneously with a dimensional crossover in the electronic ground state when the scattering rate in the chains exceeds the hopping rate between the chains. Here we report the discovery of a large, transverse magnetoresistance in PrBa$_2$Cu$_4$O$_8$ in the localized regime. This result suggests a novel form of localization whereby electrons retain their metallic (quasi-one-dimensional) character over a microscopic length scale despite the fact that macroscopically, they exhibit localized (one-dimensional) behavior.Comment: 4 pages, 4 Figure

Anomalous behaviors of the charge and spin degrees of freedom in the CuO double chains of PrBa2_2Cu4_4O8_8

The density-matrix renormalization-group method is used to study the electronic states of a two-chain Hubbard model for CuO double chains of PrBa$_2$Cu$_4$O$_8$. We show that the model at quarter filling has the charge ordered phases with stripe-type and in-line--type patterns in the parameter space, and in-between, there appears a wide region of vanishing charge gap; the latter phase is characteristic of either Tomonaga-Luttinger liquid or a metallic state with a spin gap. We argue that the low-energy electronic state of the CuO double chains of PrBa$_2$Cu$_4$O$_8$ should be in the metallic state with a possibly small spin gap.Comment: REVTEX 4, 10 pages, 9 figures; submitted to PR

Fragile three-dimensionality in the quasi-one-dimensional cuprate PrBa_2Cu_4O_8

In this article we report on the experimental realization of dimensional crossover phenomena in the chain compound PrBa$_2$Cu$_4$O$_8$ using temperature, high magnetic fields and disorder as independent tuning parameters. In purer crystals of PrBa$_2$Cu$_4$O$_8$, a highly anisotropic three-dimensional Fermi-liquid state develops at low temperatures. This metallic state is extremely susceptible to disorder however and localization rapidly sets in. We show, through quantitative comparison of the relevant energy scales, that this metal/insulator crossover occurs precisely when the scattering rate within the chain exceeds the interchain hopping rate(s), i.e. once carriers become confined to a single conducting element.Comment: 12 pages, 5 figures, published at http://www.iop.org/EJ/article/1367-2630/8/9/172/njp6_9_172.htm

Spin dynamics and antiferromagnetic order in PrBa2Cu4O8 studied by Cu nuclear respnance

Results of the nuclear resonance experiments for the planar Cu sites in PrBa2Cu4O8 are presented. The NMR spectrum at 1.5 K in zero magnetic field revealed an internal field of 6.1 T, providing evidence for an antiferromagnetic order of the planar Cu spins. This confirms that the CuO2 planes are insulating, therefore, the metallic conduction in this material is entirely due to the one-dimensional zigzag Cu2O2 chains. The results of the spin-lattice relaxation rates measured by zero field NQR above 245 K in the paramagnetic state are explained by the theory for a Heisenberg model on a square lattice.Comment: 4 pages, 2 figure

Angle-resolved photoemission study of insulating and metallic Cu-O chains in PrBa2_2Cu3_3O7_7 and PrBa2_2Cu4_4O8_8

We compare the angle-resolved photoemission spectra of the hole-doped Cu-O chains in PrBa$_2$Cu$_3$O$_7$ (Pr123) and in PrBa$_2$Cu$_4$O$_8$ (Pr124). While, in Pr123, a dispersive feature from the chain takes a band maximum at $k_b$ (momentum along the chain) $\sim$ $\pi/4$ and loses its spectral weight around the Fermi level, it reaches the Fermi level at $k_b$ $\sim$ $\pi/4$ in Pr124. Although the chains in Pr123 and Pr124 are approximately 1/4-filled, they show contrasting behaviors: While the chains in Pr123 have an instability to charge ordering, those in Pr124 avoid it and show an interesting spectral feature of a metallic coupled-chain system.Comment: 4 pages, 5 figures, to be published in PR

Accuracy and reliability of China's energy statistics

Many observers have raised doubts about the accuracy and reliability of China's energy statistics, which show an unprecedented decline in recent years, while reported economic growth has remained strong. This paper explores the internal consistency of China's energy statistics from 1990 to 2000, coverage and reporting issues, and the state of the statistical reporting system. Available information suggests that, while energy statistics were probably relatively good in the early 1990s, their quality has declined since the mid-1990s. China's energy statistics should be treated as a starting point for analysis, and explicit judgments regarding ranges of uncertainty should accompany any conclusions

Charge Fluctuations in Geometrically Frustrated Charge Ordering System

Effects of geometrical frustration in low-dimensional charge ordering systems are theoretically studied, mainly focusing on dynamical properties. We treat extended Hubbard models at quarter-filling, where the frustration arises from competing charge ordered patterns favored by different intersite Coulomb interactions, which are effective models for various charge transfer-type molecular conductors and transition metal oxides. Two different lattice structures are considered: (a) one-dimensional chain with intersite Coulomb interaction of nearest neighbor V_1 and that of next-nearest neighbor V_2, and (b) two-dimensional square lattice with V_1 along the squares and V_2 along one of the diagonals. From previous studies, charge ordered insulating states are known to be unstable in the frustrated region, i.e., V_1 \simeq 2V_2 for case (a) and V_1 \simeq V_2 for case (b), resulting in a robust metallic phase even when the interaction strenghs are strong. By applying the Lanczos exact diagonalization to finite-size clusters, we have found that fluctuations of different charge order patterns exist in the frustration-induced metallic phase, showing up as characteristic low energy modes in dynamical correlation functions. Comparison of such features between the two models are discussed, whose difference will be ascribed to the dimensionality effect. We also point out incommensurate correlation in the charge sector due to the frustration, found in one-dimensional clusters.Comment: 8 pages, 9 figure

Asymmetric total synthesis of (+)-virosine a via sequential nucleophilic cyclizations onto an activated formamide

Abstract: The first synthesis of tetracyclic alkaloid virosine A is reported. The natural alkaloid was prepared in only 13 steps, in an enantioenriched form. The azabicyclo[2.2.2]octane core was efficiently assembled using a key Vilsmeier–Haack and Mannich cyclizations sequence performed in one pot