Materials and techniques of Art Nouveau architecture in Italy and Portugal: a first insight for an European route to consistent restoration

The results of the investigations on building materials and techniques of Casa Major Pessoa, a typical Art Nouveau construction in Aveiro (Portugal), and two coeval Art Nouveau buildings in Bologna (Italy) are presented as a methodological contribution to the restoration of this kind of buildings. This is the first step to ascertain the existence of a common thread between local materials, technologies and architecture in European countries at the same period. A holistic approach was adopted: materials were investigated along with architectural, structural and technological features, in order to achieve a first insight into the Art Nouveau architecture in Europe in particular for its consistent restoration without loss of historical memory

A new sensorized ceramic plug for the remote monitoring of moisture in historic masonry walls: First results from laboratory and onsite testing

The presence of moisture in historic buildings, especially from rising damp, is extremely widespread and severe, causing materials' deterioration, internal discomfort and bad thermal insulation of external walls. Although this phenomenon is widely studied in the literature, the available solutions are frequently only partially effective, also due to the lack of reliable and compatible techniques to monitor the amount of moisture inside porous building materials, especially in heritage buildings where multiple restrictions exist. In this paper, a new sensorized ceramic plug was developed, to be inserted in historic masonry walls for the remote monitoring of moisture. The plug includes a moisture sensor that is currently used for soil irrigation purpose in agriculture and a ceramic envelope of tailored properties. The plug was developed in laboratory following a step-by-step testing program, which took into account both the specific features of the sensor (requiring a strong research effort to be transferred to building materials) and those of historic walls. After a first set of laboratory tests, the sensorized ceramic plug was validated in small-scale laboratory walls and in a real historic masonry in the monumental Certosa cemetery in Bologna, Italy. The results are extremely encouraging, as they show how the new plug can provide valuable information about the rising damp evolution, and in fact, the data were correlated with the changes in the concurrent environmental parameters in the area of the cemetery. The results also suggest some possible measures to improve the sensorized ceramic plug in the near future

Consolidation of sugaring marble by hydroxyapatite: some recent developments on producing and treating decayed samples

Consolidation of sugaring marble (i.e., marble affected by granular disaggregation) still lacks fully effective solutions. Consequently, the use of an innovative phosphate-based treatment, aimed at bonding calcite grains by formation of hydroxyapatite at grain boundaries, has recently been proposed. In this paper, firstly a novel method for producing artificially decayed marble samples, by contact with a heating plate, is proposed. Then, some results are presented about the effectiveness and the compatibility of two different formulations of the phosphate treatment, differing in terms of concentration of the phosphate precursor (3.0 M or 0.1 M aqueous solutions of diammonium hydrogen phosphate, DAP), possible ethanol addition to the DAP solution and number of DAP solution applications (1 or 2). The results of the study point out that the new weathering method allows to obtain specimens with a gradient in microstructural and mechanical properties with thickness, just like naturally weathered samples. Both phosphate treatments were able to significantly improve marble cohesion, without causing significant changes in thermal behaviour and aesthetic appearance after treatment. The addition of small quantities of ethanol to the DAP solution seems to be a very promising method for favouring HAP formation and improving the treatment performance

Materiales y tecnologías en la Arquitectura Modernista: casos de estudio de decoración de fachadas en Italia, Portugal y Polonia persiguiendo una restauración racional

The results of a diagnostic survey on the materials of representative Art Nouveau buildings in Italy, Portugal and Poland are here presented and compared, as a contribution to their understanding and, hence, to support compatible restoration. In particular, the facade decorations were investigated for the appraisal of their materials and technologies, often neglected in current maintenance/restoration works and so cancelled, leading to a severe loss in architectural image. The ongoing diagnostic campaign, in collaboration among different universities, is aimed to set up a database on materials and technologies of Art Nouveau facade decorations at a European scale, as a technical-scientific background for the highlighting of preservation guidelines

Electrodeposition of hydroxyapatite coatings for marble protection: Preliminary results

Surface coatings made of hydroxyapatite (HAP) have been proposed to protect marble artworks from dissolution in rain, originated by the aqueous solubility of calcite. However, HAP coatings formed by wet chemistry exhibit incomplete coverage of marble surface, which results in limited protective efficacy. In this study, electrodeposition was explored as a new route to possibly form continuous coatings over the marble surface, leaving no bare areas. Electrodeposition was performed by placing marble samples in poultices containing the electrolyte (an aqueous solution with calcium and phosphate precursors) and the electrodes. The influence of several parameters was investigated, namely the role of the working electrode (cathode or anode), the distance between the marble sample and the working electrode, the deposition conditions (potentiostatic or galvanostatic), the electrolyte composition and concentration, the applied voltage, and time. The coating morphology and composition were assessed by SEM/EDS and FT-IR. The protective ability of the most promising formulations was then evaluated, in all cases comparing electrodeposition with traditional wet synthesis methods. The results of the study suggest that electrodeposition is able to accelerate and improve formation of HAP coatings over the marble surface, even though the obtained protective efficacy is not complete yet

I materiali dell’ Arte Nova portoghese in Casa Major Pessoa ad Aveiro: caratterizzazione e confronto con edifici coevi in Bologna

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An integrated approach to the monitoring of rising damp in historic brick masonry

Monitoring rising damp in historic masonry buildings requires an integrated approach, including not only the quantification of moisture in materials over time, but also the investigation of the supply of water from the ground, the evaporative capacity of the surrounding air, and the presence of potentially hygroscopic salts. However, this approach is seldom applied, hence our knowledge of the phenomenon of rising damp in real historic masonry structures is often only partial. In this paper, the proposed approach was applied to the church of Santa Croce in Ravenna, Italy, an outstanding example of masonry building affected by rising damp and related materials’ deterioration. Santa Croce is a Byzantine church surrounded by an archaeological site and the whole area is presently located under the water table level, requiring a continuously operating pumping system to prevent the flooding of the entire zone. The testing and monitoring of moisture and salts in the church's materials started in September 2020 and is presently running. The data collected so far are presented and discussed in this paper, providing a contribution to a better understanding of this phenomenon. Moreover, during the monitoring period, a pumping system failure caused the flooding of the area in the period August-November 2021, allowing to investigate the impact of this event on the moisture in the materials. The protocol of testing described in this paper may provide a promising and effective method to investigate rising damp and is a starting point in view of its mitigation

SGI como instrumento complementar na avaliação do impacto ambiental da agricultura.

Divulga a metodologia, desenvolvida pelo Núcleo, de caracterização e avaliação do impacto ambiental da agricultura, baseada no uso de SGI. O projeto foi executado sobre conjuntos de pequenas propriedades com diferentes sistemas de produção. Na escala municipal articulou espacialmente, via SGI, o uso das terras e os coeficientes técnicos dos sistemas de produção aferentes. Foram geradas 32 cartas de impacto ambiental da atividade agrícola, por recursos e insumos

Influence of Calcined Clay on Workability of Mortars with Low-carbon Cement

The second-largest industrial global emitter of CO2 (Carbon dioxide) is the cement sector. The technology roadmap of low carbon transition for cement industries includes the introduction of calcined clay (CC) as supplementary cementitious material. A new type of alternative binder, called Limestone Calcined Clay Cement (LC3), was recently proposed. This cement can reduce CO2 emissions of cement production by up to 40% and it is prepared using limestone (LS) and clay which are globally available. Many scientific studies aimed to investigate the hydration of LC3 to understand the contribution of CC to the development of the compressive strength. However, recent studies showed that other cement properties, like workability and water demand, are highly impacted by calcined clay. Despite some papers state that an increase in superplasticizer (SP) dosage compensate this effect, such concrete is usually sticky, and hard to handle and deal with. In this sense, a proper understanding of the mechanisms regulating rheology of LC3 is needed. The objective of this study is to analyze workability of CC-based cement pastes and mortar, specifically investigating the role of free water in particle suspensions. Preliminary results show that CC highly influences workability of mortars and pastes. The flow table test results highlight a need to increase SP dosage to achieve target workability with CC cements. Differential scanning calorimetry (DSC) and 1 H time domain-nuclear magnetic resonance (TD-NMR) results clarify that the capillary unbound water is rapidly consumed by CC, being thus unavailable to fluidify cement pastes. This multi-method approach provides a further step in understanding CC impact on workability of mortars with low-carbon cement and opens new ways to understand paste, mortar, and concrete workability

Salt-Induced Deterioration on FRP-Brick Masonry Bond

In the past decades, several studies have shown how fiber reinforced polymer (FRP) composites are an effective technique to strengthen unreinforced brick masonry structures. However, very little is known about their durability against environmental aggression such as salt attack and freeze-thaw cycles, or elevated moisture content. This paper presents an investigation on influence of salt attack on the stress transfer between the FRP composite and the masonry substrate. In fact, it is well known that, in certain conditions, soluble salts crystallize within the pores of materials, leading to crystallization pressures that may overcome their tensile strength. To investigate this effect, FRP-masonry joints were subjected to salt crystallization cycles according to a conditioning procedure designed by the authors. After conditioning, direct shear tests were conducted on the masonry joints to investigate the interfacial bond between the substrate and the composite. Materials characterization was carried out in order correlate the results of the direct shear tests with the salt distribution within the specimens. For comparison, direct shear tests were conducted on FRP-masonry joints that were not subjected to any cycle and therefore used as control