Reflectance spectroscopy of indoor settled dust in Tel Aviv, Israel: comparison between the spring and the summer seasons

International audienceThe influence of mineral and anthropogenic dust components on the VIS-NIR-SWIR spectral reflectance of artificial laboratory dust mixtures was evaluated and used in combination with Partial Least Squares (PLS) regression to construct a model that correlates the dust content with its reflectance. Small amounts of dust (0.018?0.33 mg/cm2) were collected using glass traps placed in different indoor environments in Tel Aviv, Israel during the spring and summer of 2005. The constructed model was applied to reflectance spectroscopy measurements derived from the field dust samples to assess their mineral content. Additionally, field samples were examined using Principal Component Analysis (PCA) to identify the most representative spectral pattern for each season. Across the visible range of spectra two main spectral shapes were observed, convex and concave, though spectra exhibiting hybrid shapes were also seen. Spectra derived from spring season dust samples were characterized mostly by a convex shape, which indicates a high mineral content. In contrast, the spectra generated from summer samples were characterized generally by a concave shape, which indicates a high organic matter content. In addition to this seasonal variation in spectral patterns, spectral differences were observed associated with the dwelling position in the city. Samples collected in the city center showed higher organic content, whereas samples taken from locations at the city margins, near the sea and next to open areas, exhibited higher mineral content. We conclude that mineral components originating in the outdoor environment influence indoor dust loads, even when considering relatively small amounts of indoor settled dust. The sensitive spectral-based method developed here has potentially many applications for environmental researchers and policy makers concerned with dust pollution

The Interplay of Structure and Dynamics in the Raman Spectrum of Liquid Water over the Full Frequency and Temperature Range

While many vibrational Raman spectroscopy studies of liquid water have investigated the temperature dependence of the high-frequency O-H stretching region, few have analyzed the changes in the Raman spectrum as a function of temperature over the entire spectral range. Here, we obtain the Raman spectra of water from its melting to boiling point, both experimentally and from simulations using an ab initio-trained machine learning potential. We use these to assign the Raman bands and show that the entire spectrum can be well described as a combination of two temperature-independent spectra. We then assess which spectral regions exhibit strong dependence on the local tetrahedral order in the liquid. Further, this work demonstrates that changes in this structural parameter can be used to elucidate the temperature dependence of the Raman spectrum of liquid water and provides a guide to the Raman features that signal water ordering in more complex aqueous systems

Stability of Relativistic Matter with Magnetic Fields for Nuclear Charges up to the Critical Value

We give a proof of stability of relativistic matter with magnetic fields all the way up to the critical value of the nuclear charge $Z\alpha=2/\pi$.Comment: LaTeX2e, 12 page

Mineral content analysis of atmospheric dust using hyperspectralinformation from space

The Bodélé depression of northern Chad is considered one of the world\u27s largest sources of atmospheric mineral dust. Mineral composition of such transported dust is essential to our understanding of climate forcing, mineralogy of dust sources, aerosol optical properties, and mineral deposition to Amazon forests. In this study we examine hyperspectral information acquired over the Bodélé by EO‐1 Hyperion satellite during a dust storm event and during a calm clean day. We show that, for the suspended dust, the absorption signature can be decoupled from scattering, allowing detection of key minerals. Our results, based on the visible and shortwave infrared hyperspectral data, demonstrate that the Bodélé surface area is composed of iron‐oxides, clays (kaosmectite) and sulfate groups (gypsum). Atmospheric dust spectra downwind of Bodélé reveal striking differences in absorption signatures across shortwave infrared from those of the underlying surface

Magnetization switching in ferromagnets by adsorbed chiral molecules without current or external magnetic field

Ferromagnets are commonly magnetized by either external magnetic fields or spin polarized currents. The manipulation of magnetization by spin-current occurs through the spin-transfer-torque effect, which is applied, for example, in modern magnetoresistive random access memory. However, the current density required for the spin-transfer torque is of the order of 1 × 106 A·cm−2, or about 1 × 1025 electrons s−1 cm−2. This relatively high current density significantly affects the devices’ structure and performance. Here we demonstrate magnetization switching of ferromagnetic thin layers that is induced solely by adsorption of chiral molecules. In this case, about 1013 electrons per cm2 are sufficient to induce magnetization reversal. The direction of the magnetization depends on the handedness of the adsorbed chiral molecules. Local magnetization switching is achieved by adsorbing a chiral self-assembled molecular monolayer on a gold-coated ferromagnetic layer with perpendicular magnetic anisotropy. These results present a simple low-power magnetization mechanism when operating at ambient conditions

Compressible flow structures interaction with a two-dimensional ejector: a cold-flow study

An experimental study has been conducted to examine the interaction of compressible flow structures such as shocks and vortices with a two-dimensional ejector geometry using a shock-tube facility. Three diaphragm pressure ratios ofP4 =P1 = 4, 8, and 12 have been employed, whereP4 is the driver gas pressure andP1 is the pressure within the driven compartment of the shock tube. These lead to incident shock Mach numbers of Ms = 1:34, 1.54, and 1.66, respectively. The length of the driver section of the shock tube was 700 mm. Air was used for both the driver and driven gases. High-speed shadowgraphy was employed to visualize the induced flowfield. Pressure measurements were taken at different locations along the test section to study theflow quantitatively. The induced flow is unsteady and dependent on the degree of compressibility of the initial shock wave generated by the rupture of the diaphragm