Molecular architecture of softwood revealed by solid-state NMR

Economically important softwood from conifers is mainly composed of the polysaccharides cellulose, galactoglucomannan and xylan, and the phenolic polymer, lignin. The interactions between these polymers lead to wood mechanical strength and must be overcome in biorefining. Here, we use 13C multidimensional solid-state NMR to analyse the polymer interactions in never-dried cell walls of the softwood, spruce. In contrast to some earlier softwood cell wall models, most of the xylan binds to cellulose in the two-fold screw conformation. Moreover, galactoglucomannan alters its conformation by intimately binding to the surface of cellulose microfibrils in a semi-crystalline fashion. Some galactoglucomannan and xylan bind to the same cellulose microfibrils, and lignin is associated with both of these cellulose-bound polysaccharides. We propose a model of softwood molecular architecture which explains the origin of the different cellulose environments observed in the NMR experiments. Our model will assist strategies for improving wood usage in a sustainable bioeconomy

Combined ultraviolet studies of astronomical sources

Ultraviolet studies of astronomical sources are discussed. Some studies utilized IVE data. Non-radiative shock at the edge of the Cygnses Loop, stellar flares, local interestellar medium, hot galaxies, stellar mass ejection, contact binaries, double quasars, and stellar chromosphere and coronae are discussed

NGC 1866: First Spectroscopic Detection of Fast Rotating Stars in a Young LMC Cluster

High-resolution spectroscopic observations were taken of 29 extended main sequence turn-off (eMSTO) stars in the young ($\sim$200 Myr) LMC cluster, NGC 1866 using the Michigan/Magellan Fiber System and MSpec spectrograph on the Magellan-Clay 6.5-m telescope. These spectra reveal the first direct detection of rapidly rotating stars whose presence has only been inferred from photometric studies. The eMSTO stars exhibit H-alpha emission (indicative of Be-star decretion disks), others have shallow broad H-alpha absorption (consistent with rotation $\gtrsim$150 km s$^{-1}$), or deep H-alpha core absorption signaling lower rotation velocities ($\lesssim$150 km s$^{-1}$ ). The spectra appear consistent with two populations of stars - one rapidly rotating, and the other, younger and slowly rotating.Comment: 9 pages, 4 figures, Accepted for publication in ApJ Letter

Photometric Variability in Kepler Target Stars: The Sun Among Stars -- A First Look

The Kepler mission provides an exciting opportunity to study the lightcurves of stars with unprecedented precision and continuity of coverage. This is the first look at a large sample of stars with photometric data of a quality that has heretofore been only available for our Sun. It provides the first opportunity to compare the irradiance variations of our Sun to a large cohort of stars ranging from vary similar to rather different stellar properties, at a wide variety of ages. Although Kepler data is in an early phase of maturity, and we only analyze the first month of coverage, it is sufficient to garner the first meaningful measurements of our Sun's variability in the context of a large cohort of main sequence stars in the solar neighborhood. We find that nearly half of the full sample is more active than the active Sun, although most of them are not more than twice as active. The active fraction is closer to a third for the stars most similar to the Sun, and rises to well more than half for stars cooler than mid K spectral types.Comment: 13 pages, 4 figures, accepted to ApJ Letter

TW Hya: Spectral Variability, X-Rays, and Accretion Diagnostics

The nearest accreting T Tauri star, TW Hya was observed with spectroscopic and photometric measurements simultaneous with a long se gmented exposure using the CHANDRA satellite. Contemporaneous optical photometry from WASP-S indicates a 4.74 day period was present during this time. Absence of a similar periodicity in the H-alpha flux and the total X-ray flux points to a different source of photometric variations. The H-alpha emission line appears intrinsically broad and symmetric, and both the profile and its variability suggest an origin in the post-shock cooling region. An accretion event, signaled by soft X-rays, is traced spectroscopically for the first time through the optical emission line profiles. After the accretion event, downflowing turbulent material observed in the H-alpha and H-beta lines is followed by He I (5876A) broadening. Optical veiling increases with a delay of about 2 hours after the X-ray accretion event. The response of the stellar coronal emission to an increase in the veiling follows about 2.4 hours later, giving direct evidence that the stellar corona is heated in part by accretion. Subsequently, the stellar wind becomes re-established. We suggest a model that incorporates this sequential series of events: an accretion shock, a cooling downflow in a supersonically turbulent region, followed by photospheric and later, coronal heating. This model naturally explains the presence of broad optical and ultraviolet lines, and affects the mass accretion rates determined from emission line profiles.Comment: 61 pages; 22 figures; to appear in The Astrophysical Journa

The Observations Of The X-Ray Source Hz Herculis-Hercules X-1

NASAESASRCAstronom

HST Observations of Chromospheres in Metal Deficient Field Giants

HST high resolution spectra of metal-deficient field giants more than double the stars in previous studies, span about 3 magnitudes on the red giant branch, and sample an abundance range [Fe/H]= -1 to -3. These stars, in spite of their age and low metallicity, possess chromospheric fluxes of Mg II (2800 Angstrom) that are within a factor of 4 of Population I stars, and give signs of a dependence on the metal abundance at the lowest metallicities. The Mg II k-line widths depend on luminosity and correlate with metallicity. Line profile asymmetries reveal outflows that occur at lower luminosities (M_V = -0.8) than detected in Ca K and H-alpha lines in metal-poor giants, suggesting mass outflow occurs over a larger span of the red giant branch than previously thought, and confirming that the Mg II lines are good wind diagnostics. These results do not support a magnetically dominated chromosphere, but appear more consistent with some sort of hydrodynamic, or acoustic heating of the outer atmospheres.Comment: 36 pages, 12 figures, 7 tables, and accepted for publication in The Astronomical Journa

Discovery of the Transiting Planet Kepler-5B

We present 44 days of high duty cycle, ultra precise photometry of the 13th magnitude star Kepler-5 (KIC 8191672, T(eff) = 6300 K, log g = 4.1), which exhibits periodic transits with a depth of 0.7%. Detailed modeling of the transit is consistent with a planetary companion with an orbital period of 3.548460 +/- 0.000032 days and a radius of 1.431(-0.052)(+0.041) R(J). Follow-up radial velocity measurements with the Keck HIRES spectrograph on nine separate nights demonstrate that the planet is more than twice as massive as Jupiter with a mass of 2.114(-0.059)(+0.056) M(J) and a mean density of 0.894 +/- 0.079 g cm(-3).NASA's Science Mission DirectorateAstronom

Quantum Disordered Regime and Spin Gap in the Cuprate Superconductors

We discuss the crossover from the quantum critical, $z\!=\!1$, to the quantum disordered regime in high-T$_c$ materials in relation to the experimental data on the nuclear relaxation, bulk susceptibility, and inelastic neutron scattering. In our scenario, the spin excitations develop a gap $\Delta\!\sim\!1/\xi$ well above T$_c$, which is supplemented by the quasiparticle gap below T$_c$. The above experiments yield consistent estimates for the value of the spin gap, which increases as the correlation length decreases.Comment: 14 pages, REVTeX v3.0, PostScript file for 3 figures is attached, UIUC-P-93-07-06