Subtask 5.3 - Water and Energy Sustainability and Technology

The overall goal of this Energy & Environmental Research Center project was to evaluate water capture technologies in a carbon capture and sequestration system and perform a complete systems analysis of the process to determine potential water minimization opportunities within the entire system. To achieve that goal, a pilot-scale liquid desiccant dehumidification system (LDDS) was fabricated and tested in conjunction with a coal-fired combustion test furnace outfitted with CO{sub 2} mitigation technologies, including the options of oxy-fired operation and postcombustion CO{sub 2} capture using an amine scrubber. The process gas stream for these tests was a coal-derived flue gas that had undergone conventional pollutant control (particulates, SO{sub 2}) and CO{sub 2} capture with an amine-based scrubber. The water balance data from the pilot-scale tests show that the packed-bed absorber design was very effective at capturing moisture down to levels that approach equilibrium conditions

The Spitzer c2d Survey Of Nearby Dense Cores. XI. Infrared And Submillimeter Observations Of CB130

We present new observations of the CB130 region composed of three separate cores. Using the Spitzer Space Telescope, we detected a Class 0 and a Class II object in one of these, CB130-1. The observed photometric data from Spitzer and ground-based telescopes are used to establish the physical parameters of the Class 0 object. Spectral energy distribution fitting with a radiative transfer model shows that the luminosity of the Class 0 object is 0.14-0.16 L-circle dot, which is low for a protostellar object. In order to constrain the chemical characteristics of the core having the low-luminosity object, we compare our molecular line observations to models of lines including abundance variations. We tested both ad hoc step function abundance models and a series of self-consistent chemical evolution models. In the chemical evolution models, we consider a continuous accretion model and an episodic accretion model to explore how variable luminosity affects the chemistry. The step function abundance models can match observed lines reasonably well. The best-fitting chemical evolution model requires episodic accretion and the formation of CO2 ice from CO ice during the low-luminosity periods. This process removes C from the gas phase, providing a much improved fit to the observed gas-phase molecular lines and the CO2 ice absorption feature. Based on the chemical model result, the low luminosity of CB130-1 is explained better as a quiescent stage between episodic accretion bursts rather than being at the first hydrostatic core stage.NASA 1224608, 1288664, 1407, NNX07AJ72G, 1279198, 1288806, 1342425NSF AST-0607793, AST-0708158Korea government (MEST) 2009-0062866Ministry of Education, Science and Technology 2010-0008704Astronom

The Spitzer c2d Survey of Nearby Dense Cores: VI. The Protostars of Lynds Dark Nebula 1221

Observations of Lynds Dark Nebula 1221 from the Spitzer Space Telescope are presented. These data show three candidate protostars towards L1221, only two of which were previously known. The infrared observations also show signatures of outflowing material, an interpretation which is also supported by radio observations with the Very Large Array. In addition, molecular line maps from the Five College Radio Astronomy Observatory are shown. One-dimensional dust continuum modelling of two of these protostars, IRS1 and IRS3, is described. These models show two distinctly different protostars forming in very similar environments. IRS1 shows a higher luminosity and larger inner radius of the envelope than IRS3. The disparity could be caused by a difference in age or mass, orientation of outflow cavities, or the impact of a binary in the IRS1 core.Comment: accepted for publication in Ap

The Protostellar Luminosity Function

The protostellar luminosity function (PLF) is the present-day luminosity function of the protostars in a region of star formation. It is determined using the protostellar mass function (PMF) in combination with a stellar evolutionary model that provides the luminosity as a function of instantaneous and final stellar mass. As in McKee & Offner (2010), we consider three main accretion models: the Isothermal Sphere model, the Turbulent Core model, and an approximation of the Competitive Accretion model. We also consider the effect of an accretion rate that tapers off linearly in time and an accelerating star formation rate. For each model, we characterize the luminosity distribution using the mean, median, maximum, ratio of the median to the mean, standard deviation of the logarithm of the luminosity, and the fraction of very low luminosity objects. We compare the models with bolometric luminosities observed in local star forming regions and find that models with an approximately constant accretion time, such as the Turbulent Core and Competitive Accretion models, appear to agree better with observation than those with a constant accretion rate, such as the Isothermal Sphere model. We show that observations of the mean protostellar luminosity in these nearby regions of low-mass star formation suggest a mean star formation time of 0.3$\pm$0.1 Myr. Such a timescale, together with some accretion that occurs non-radiatively and some that occurs in high-accretion, episodic bursts, resolves the classical "luminosity problem" in low-mass star formation, in which observed protostellar luminosities are significantly less than predicted. An accelerating star formation rate is one possible way of reconciling the observed star formation time and mean luminosity.Comment: 22 pages, 9 figures, accepted to Ap

Photonic Band Tuning in 2D Photonic Crystals by Atomic Layer Deposition

Atomic layer deposition (ALD) has become a powerful tool for the fabrication of high quality 3-dimentional photonic crystals (PCs) from both inorganic (opal) and organic (holographically patterned polymer) templates [1,2]. With ALD, highly conformal films can be grown with a precision of 0.05 nm, which, when combined with the availability of a wide range of low temperature film growth protocols, enables a high degree of control over material and structural properties to precisely tune optical properties [3]. Two-dimensional photonic crystals have been developed extensively for applications in optical interconnects, beam steering, and sensor devices; and are predominantly fabricated by electron-beam lithography. The optical properties of 2D photonic crystal slab waveguides are determined by the precision of the lithography process, with limited post fabrication tunability

Inferring Fitness Effects from Time-Resolved Sequence Data with a Delay-Deterministic Model.

A common challenge arising from the observation of an evolutionary system over time is to infer the magnitude of selection acting upon a specific genetic variant, or variants, within the population. The inference of selection may be confounded by the effects of genetic drift in a system, leading to the development of inference procedures to account for these effects. However, recent work has suggested that deterministic models of evolution may be effective in capturing the effects of selection even under complex models of demography, suggesting the more general application of deterministic approaches to inference. Responding to this literature, we here note a case in which a deterministic model of evolution may give highly misleading inferences, resulting from the nondeterministic properties of mutation in a finite population. We propose an alternative approach that acts to correct for this error, and which we denote the delay-deterministic model. Applying our model to a simple evolutionary system, we demonstrate its performance in quantifying the extent of selection acting within that system. We further consider the application of our model to sequence data from an evolutionary experiment. We outline scenarios in which our model may produce improved results for the inference of selection, noting that such situations can be easily identified via the use of a regular deterministic model

Spoken Digit Classification by In-Materio Reservoir Computing with Neuromorphic Atomic Switch Networks

Atomic Switch Networks (ASN) comprising silver iodide (AgI) junctions, a material previously unexplored as functional memristive elements within highly-interconnected nanowire networks, were employed as a neuromorphic substrate for physical Reservoir Computing (RC). This new class of ASN-based devices has been physically characterized and utilized to classify spoken digit audio data, demonstrating the utility of substrate-based device architectures where intrinsic material properties can be exploited to perform computation in-materio. This work demonstrates high accuracy in the classification of temporally analyzed Free-Spoken Digit Data (FSDD). These results expand upon the class of viable memristive materials available for the production of functional nanowire networks and bolster the utility of ASN-based devices as unique hardware platforms for neuromorphic computing applications involving memory, adaptation and learning.Comment: 11 pages, 7 figure

Desmoplastic myxoid tumor of pineal region, SMARCB1-mutant, in young adult

We present a young adult woman who developed a myxoid tumor of the pineal region having a SMARCB1 mutation, which was phenotypically similar to the recently described desmoplastic myxoid, SMARCB1-mutant tumor of the pineal region (DMT-SMARCB1). The 24-year-old woman presented with headaches, nausea, and emesis. Neuroimaging identified a hypodense lesion in CT scans that was T1-hypointense, hyperintense in both T2-weighted and FLAIR MRI scans, and displayed gadolinium enhancement. The resected tumor had an abundant, Alcian-blue positive myxoid matrix with interspersed, non-neoplastic neuropil-glial-vascular elements. It immunoreacted with CD34 and individual cells for EMA. Immunohistochemistry revealed loss of nuclear INI1 expression by the myxoid component but its retention in the vascular elements. Molecular analyses identified a SMARCB1 deletion and DNA methylation studies showed that this tumor grouped together with the recently described DMT-SMARCB1. A cerebrospinal fluid cytologic preparation had several cells morphologically similar to those in routine and electron microscopy. We briefly discuss the correlation of the pathology with the radiology and how this tumor compares with other SMARCB1-mutant tumors of the nervous system

The influence of a CYP1A2 polymorphism on the ergogenic effects of caffeine

<p>Abstract</p> <p>Background</p> <p>Although caffeine supplementation improves performance, the ergogenic effect is variable. The cause(s) of this variability are unknown. A (C/A) single nucleotide polymorphism at intron 1 of the cytochrome P450 (CYP1A2) gene influences caffeine metabolism and clinical outcomes from caffeine ingestion. The purpose of this study was to determine if this polymorphism influences the ergogenic effect of caffeine supplementation.</p> <p>Methods</p> <p>Thirty-five trained male cyclists (age = 25.0 ± 7.3 yrs, height = 178.2 ± 8.8 cm, weight = 74.3 ± 8.8 kg, VO₂max = 59.35 ± 9.72 ml·kg^-1·min^-1) participated in two computer-simulated 40-kilometer time trials on a cycle ergometer. Each test was performed one hour following ingestion of 6 mg·kg^-1of anhydrous caffeine or a placebo administered in double-blind fashion. DNA was obtained from whole blood samples and genotyped using restriction fragment length polymorphism-polymerase chain reaction. Participants were classified as AA homozygotes (N = 16) or C allele carriers (N = 19). The effects of treatment (caffeine, placebo) and the treatment × genotype interaction were assessed using Repeated Measures Analysis of Variance.</p> <p>Results</p> <p>Caffeine supplementation reduced 40 kilometer time by a greater (<it>p </it>< 0.05) magnitude in AA homozygotes (4.9%; caffeine = 72.4 ± 4.2 min, placebo = 76.1 ± 5.8 min) as compared to C allele carriers (1.8%; caffeine = 70.9 ± 4.3 min, placebo = 72.2 ± 4.2 min).</p> <p>Conclusions</p> <p>Results suggest that individuals homozygous for the A allele of this polymorphism may have a larger ergogenic effect following caffeine ingestion.</p