Electron impact promoted fragmentation of alkyl-N-(1-Phenylethyl)-carbamates of primary, secondary and tertiary alcohols

Mass spectra of alkyl carbamates derived from primary, secondary, and teriary alcohols by use of deuterium labeling and high resolution mass spectroscop

Grouping Individual Investment Preferences in Retirement Savings: A Cluster Analysis of a USS Members Risk Attitude Survey

Cluster analysis is used to identify homogeneous groups of members of USS in terms of risk attitudes. There are two distinct clusters of members in their 40s and 50s. One had previously ‘engaged’ with USS by making additional voluntary contributions. It typically had higher pay, longer tenure, less interest in ethical investing, lower risk capacity, a higher percentage of males, and a higher percentage of academics than members of the ‘disengaged’ cluster. Conditioning only on the attitude to risk responses, there are 18 clusters, with similar but not identical membership, depending on which clustering method is used. The differences in risk aversion across the 18 clusters could be explained largely by differences in the percentage of females and the percentage of couples. Risk aversion increases as the percentage of females in the cluster increases, while it reduces as the percentage of couples increases because of greater risk sharing within the household. Characteristics that other studies have found important determinants of risk attitudes, such as age, income and (pension) wealth, do not turn out to be as significant for USS members. Further, despite being on average more highly educated than the general population, USS members are marginally more risk averse than the general population, controlling for salary, although the difference is not significant

One size fits all: How many default funds does a pension scheme need?

In this paper, we analyse the number of default investment funds appropriate for an occupational defined contribution pension scheme. Using a unique dataset of member risk attitudes and characteristics from a survey of a large UK pension scheme, we apply cluster analysis to identify two distinct groups of members in their 40s and 50s. Further analysis indicated that the risk attitudes of the two groups were not significantly different, allowing us to conclude that a single lifestyle default fund is appropriate

Recovery from repeated on-court tennis sessions: Combining cold-water immersion, compression, and sleep interventions

To investigate the effects of combining cold-water immersion (CWI), full-body compression garments (CG), and sleep-hygiene recommendations on physical, physiological, and perceptual recovery after 2-a-day on-court training and match-play sessions. Methods: In a crossover design, 8 highly trained tennis players completed 2 sessions of on-court tennis-drill training and match play, followed by a recovery or control condition. Recovery interventions included a mixture of 15 min CWI, 3 h of wearing full-body CG, and following sleep-hygiene recommendations that night, while the control condition involved postsession stretching and no regulation of sleeping patterns. Technical performance (stroke and error rates), physical performance (accelerometry, countermovement jump [CMJ]), physiological (heart rate, blood lactate), and perceptual (mood, exertion, and soreness) measures were recorded from each on-court session, along with sleep quantity each night. Results: While stroke and error rates did not differ in the drill session (P > .05, d .05, d > 0.90). Although accelerometry values did not differ between conditions (P > .05, d .05, d = 0.90). Furthermore, CWI and CG resulted in faster postsession reductions in heart rate and lactate and reduced perceived soreness (P > .05, d > 1.00). In addition, sleep-hygiene recommendations increased sleep quantity (P > .05, d > 2.00) and maintained lower perceived soreness and fatigue (P 2.00). Conclusions: Mixed-method recovery interventions (CWI and CG) used after tennis sessions increased ensuing time in play and lower-body power and reduced perceived soreness. Furthermore, sleep-hygiene recommendations helped reduce perceived soreness. © 2014 Human Kinetics, Inc

Comparison of athlete-coach perceptions of internal and external load markers for elite junior tennis training

Purpose: To investigate the discrepancy between coach and athlete perceptions of internal load and notational analysis of external load in elite junior tennis. Methods: Fourteen elite junior tennis players and 6 international coaches were recruited. Ratings of perceived exertion (RPEs) were recorded for individual drills and whole sessions, along with a rating of mental exertion, coach rating of intended session exertion, and athlete heart rate (HR). Furthermore, total stroke count and unforced-error count were notated using video coding after each session, alongside coach and athlete estimations of shots and errors made. Finally, regression analyses explained the variance in the criterion variables of athlete and coach RPE. Results: Repeated-measures analyses of variance and interclass correlation coefficients revealed that coaches significantly (P < .01) underestimated athlete session RPE, with only moderate correlation (r = .59) demonstrated between coach and athlete. However, athlete drill RPE (P = .14; r = .71) and mental exertion (P = .44; r = .68) were comparable and substantially correlated. No significant differences in estimated stroke count were evident between athlete and coach (P = .21), athlete notational analysis (P = .06), or coach notational analysis (P = .49). Coaches estimated significantly greater unforced errors than either athletes or notational analysis (P < .01). Regression analyses found that 54.5% of variance in coach RPE was explained by intended session exertion and coach drill RPE, while drill RPE and peak HR explained 45.3% of the variance in athlete session RPE. Conclusion: Coaches misinterpreted session RPE but not drill RPE, while inaccurately monitoring error counts. Improved understanding of external- and internal-load monitoring may help coach-athlete relationships in individual sports like tennis avoid maladaptive training. © 2014 Human Kinetics, Inc

A comparison of the perceptual and technical demands of tennis training, simulated match play, and competitive tournaments

© 2016 Human Kinetics, Inc. Purpose: High-performance tennis environments aim to prepare athletes for competitive demands through simulated-match scenarios and drills. With a dearth of direct comparisons between training and tournament demands, the current investigation compared the perceptual and technical characteristics of training drills, simulated match play, and tournament matches. Methods: Data were collected from 18 high-performance junior tennis players (gender: 10 male, 8 female; age 16 ± 1.1 y) during 6 ± 2 drill-based training sessions, 5 ± 2 simulated match-play sessions, and 5 ± 3 tournament matches from each participant. Tournament matches were further distinguished by win or loss and against seeded or nonseeded opponents. Notational analysis of stroke and error rates, winners, and serves, along with rating of perceived physical exertion (RPE) and mental exertion was measured postsession. Results: Repeated-measures analyses of variance and effect-size analysis revealed that training sessions were significantly shorter in duration than tournament matches (P .05; d = 1.26, d = 1.05, respectively). Mental exertion in training was lower than in both simulated match play and tournaments (P >.05; d = 1.10, d = 0.86, respectively). Stroke rates during tournaments exceeded those observed in training (P .05, d < 0.80). Conclusions: Training in the form of drills or simulated match play appeared to inadequately replicate tournament demands in this cohort of players. Coaches should be mindful of match demands to best prescribe sessions of relevant duration, as well as internal (RPE) and technical (stroke rate) load, to aid tournament preparation

A descriptive analysis of internal and external loads for elite-level tennis drills

Purpose: Planning tennis sessions accentuating physical development requires an understanding of training load (TL). The aims were to describe the external and internal TL of drills and analyze relationships between ratings of perceived exertion (RPE), TL, and other measures. Methods: Fourteen elite-level junior tennis athletes completed 259 individual drills. Six coaches helped devise classifications for all drills: recovery/defensive, open pattern, accuracy, 2-on-1 open, 2-on-1 net play, closed technical, point play, and match play. Notational analysis on stroke and error rates was performed postsession. Drill RPE and mental exertion were collected postdrill, while heart rate (HR) was recorded continuously. Results: Recovery/defensive, open pattern, and point play were significantly greater than closed technical drills (P .05) between categories. Substantial correlations existed for drill RPE and TL with mental exertion (r > .62) for several categories. TL was substantially correlated with total strokes (r > .65), while HR and stroke and error rates were in slight to moderate agreement with RPE and TL (r < .51). Conclusions: Recovery/defensive drills are highest in physiological stress, making them ideal for maximizing physicality. Recovery/defensive drills compromised training quality, eliciting high error rates. In contrast, 2-on-1 net-play drills provided the lowest error rates, potentially appropriate for error-amelioration practice. Open-pattern drills were characterized by significantly higher stroke rates, suggesting congruence with high-repetition practice. Finally, with strong relationships between physical and mental perception, mental exertion may complement currently used monitoring strategies (TL and RPE). © 2014 Human Kinetics, Inc

Effects of long-haul transmeridian travel on player preparedness: Case study of a national team at the 2014 FIFA World Cup

© 2016 Sports Medicine Australia Objectives Describe the effects of eastward long-haul transmeridian air travel on subjective jet-lag, sleep and wellness in professional football (soccer) players prior to the 2014 FIFA World Cup in Brazil. Design Single cohort involving twenty-two male professional football players representing a national football team. Methods Data was collected from players prior to and following international travel from Sydney, Australia to Vitoria, Brazil. In total there were three flights, 19-h and 14,695 km of travel east across 11 time-zones. Training load and wellness measures were obtained in the week prior to and following travel, whilst sleep and jet-lag measures were collected on the day prior to travel (Pre), the day of arrival and for five days following travel (Post 1–5). Results Compared to Pre, perceived jet-lag was significantly increased on Post 1 to 4, with significantly greater levels on Post 1 compared to Post 5 (p < 0.05). Self-reported sleep duration during travel was 5.9 (4.8–7.0) h, which was significantly lower than all other nights (p ˂ 0.01), except for the night of arrival, where time in bed and sleep duration were significantly reduced compared to Post 1–4 (p ˂ 0.01). Lastly, compared to the week prior to travel, mean wellness was significantly reduced during the week following travel (p ˂ 0.01). Conclusions Self-reported sleep disruption during and following eastward long-haul transmeridian air travel, together with exacerbated jet-lag symptoms may result in reduced player wellness. Consequently, player preparedness for subsequent training and competition may be impeded, though physical performance data is lacking

Avatars of Eurocentrism in the critique of the liberal peace

Recent scholarly critiques of the so-called liberal peace raise important political and ethical challenges to practices of postwar intervention in the global South. However, their conceptual and analytic approaches have tended to reproduce rather than challenge the intellectual Eurocentrism underpinning the liberal peace. Eurocentric features of the critiques include the methodological bypassing of target subjects in research, the analytic bypassing of subjects through frameworks of governmentality, the assumed ontological split between the ‘liberal’ and the ‘local’, and a nostalgia for the liberal subject and the liberal social contract as alternative bases for politics. These collectively produce a ‘paradox of liberalism’ that sees the liberal peace as oppressive but also the only true source of emancipation. However, the article suggests that a repoliticization of colonial difference offers an alternative ‘decolonizing’ approach to critical analysis through repositioning the analytic gaze. Three alternative research strategies for critical analysis are briefly developed

Battlezone: An examination of the physiological responses, movement demands and reproducibility of small-sided cricket games

As cricket training typically involves separate skill and conditioning sessions, this study reported on the movement demands, physiological responses and reproducibility of the demands of small-sided cricket games. Thirteen amateur, male cricket players (age: 22.8 ± 3.5 years, height: 1.78 ± 0.06 m, body mass: 78.6 ± 7.1 kg) completed two sessions of a generic small-sided cricket game, termed Battlezone; consisting of six repeat 8-over bouts. Heart rate and movement demands were continuously recorded, whilst blood lactate concentration and perceived exertion were recorded after each respective bout. Batsmen covered the greatest distance (1147 ± 175 m) and demonstrated the greatest mean movement speed (63 ± 9 m · min-1) during each bout. The majority of time (65-86%) was spent with a heart rate of between 51-85% HRmax and a blood lactate concentration of 1.1-2.0 mmol · L-1. Rating of perceived exertion ranged between 4.2-6.0. Movement demands and physiological responses did not differ between standardised sessions within respective playing positions (P > 0.05). The reliability for the majority of movement demands and physiological responses were moderate to high (CV: 5-17%; ICC: 0.48-1.00) within all playing positions. These results suggest that the physiological responses and movement characteristics of generic small-sided cricket games were consistent between sessions within respective playing positions. © 2013 Copyright Taylor and Francis Group, LLC