Mentoring to reduce antisocial behaviour in childhood

The effects of social interventions need to be examined in real life situations as well as studie

Delocalised oxygen as the origin of two-level defects in Josephson junctions

One of the key problems facing superconducting qubits and other Josephson junction devices is the decohering effects of bi-stable material defects. Although a variety of phenomenological models exist, the true microscopic origin of these defects remains elusive. For the first time we show that these defects may arise from delocalisation of the atomic position of the oxygen in the oxide forming the Josephson junction barrier. Using a microscopic model, we compute experimentally observable parameters for phase qubits. Such defects are charge neutral but have non-zero response to both applied electric field and strain. This may explain the observed long coherence time of two-level defects in the presence of charge noise, while still coupling to the junction electric field and substrate phonons.Comment: 5 pages, 4 figures. This version streamlines presentation and focuses on the 2D model. Also fixed embarrassing typo (pF -> fF

Linear Connections in Non-Commutative Geometry

A construction is proposed for linear connections on non-commutative algebras. The construction relies on a generalisation of the Leibnitz rules of commutative geometry and uses the bimodule structure of $\Omega^1$. A special role is played by the extension to the framework of non-commutative geometry of the permutation of two copies of $\Omega^1$. The construction of the linear connection as well as the definition of torsion and curvature is first proposed in the setting of the derivations based differential calculus of Dubois- Violette and then a generalisation to the framework proposed by Connes as well as other non-commutative differential calculi is suggested. The covariant derivative obtained admits an extension to the tensor product of several copies of $\Omega^1$. These constructions are illustrated with the example of the algebra of $n \times n$ matrices.Comment: 15 pages, LMPM ../94 (uses phyzzx

Chirality and Dirac Operator on Noncommutative Sphere

We give a derivation of the Dirac operator on the noncommutative $2$-sphere within the framework of the bosonic fuzzy sphere and define Connes' triple. It turns out that there are two different types of spectra of the Dirac operator and correspondingly there are two classes of quantized algebras. As a result we obtain a new restriction on the Planck constant in Berezin's quantization. The map to the local frame in noncommutative geometry is also discussed.Comment: 24 pages, latex, no figure

Local methylthiolate adsorption geometry on Au(111) from photoemission core-level shifts

The local adsorption structure of methylthiolate in the ordered Au(111)-(√3×√3)R30° phase has been investigated using core-level-shift measurements of the surface and bulk components of the Au 4f7/2 photoelectron binding energy. The amplitude ratio of the core-level-shift components associated with surface Au atoms that are, and are not, bonded to the thiolate is found to be compatible only with the previously proposed Au-adatom-monothiolate moiety in which the thiolate is bonded atop Au adatoms in hollow sites, and not on an unreconstructed surface, or in Au-adatom-dithiolate species

A unified view of some representations of imprecise probabilities

International audienceSeveral methods for the practical representation of imprecise probabilities exist such as Ferson's p-boxes, possibility distributions, Neumaier's clouds, and random sets . In this paper some relationships existing between the four kinds of representations are discussed. A cloud as well as a p-box can be modelled as a pair of possibility distributions. We show that a generalized form of p-box is a special kind of belief function and also a special kind of cloud

Thiol density dependent classical potential for methyl-thiol on a Au(111) surface

A new classical potential for methyl-thiol on a Au(111) surface has been developed using density functional theory electronic structure calculations. Energy surfaces between methyl-thiol and a gold surface were investigated in terms of symmetry sites and thiol density. Geometrical optimization was employed over all the configurations while minimum energy and thiol height were determined. Finally, a new interatomic potential has been generated as a function of thiol density, and applications to coarse-grained simulations are presented