118 research outputs found
Texture and shape of two-dimensional domains of nematic liquid crystal
We present a generalized approach to compute the shape and internal structure
of two-dimensional nematic domains. By using conformal mappings, we are able to
compute the director field for a given domain shape that we choose from a rich
class, which includes drops with large and small aspect ratios, and sharp
domain tips as well as smooth ones. Results are assembled in a phase diagram
that for given domain size, surface tension, anchoring strength, and elastic
constant shows the transitions from a homogeneous to a bipolar director field,
from circular to elongated droplets, and from sharp to smooth domain tips. We
find a previously unaccounted regime, where the drop is nearly circular, the
director field bipolar and the tip rounded. We also find that bicircular
director fields, with foci that lie outside the domain, provide a remarkably
accurate description of the optimal director field for a large range of values
of the various shape parameters.Comment: 12 pages, 10 figure
Formation of disclination lines near a free nematic interface
We have studied the nucleation and the physical properties of a -1/2 wedge
disclination line near the free surface of a confined nematic liquid crystal.
The position of the disclination line has been related to the material
parameters (elastic constants, anchoring energy and favored anchoring angle of
the molecules at the free surface). The use of a planar model for the structure
of the director field (whose predictions have been contrasted to those of a
fully three-dimensional model) has allowed us to relate the experimentally
observed position of the disclination line to the relevant properties of the
liquid crystals. In particular, we have been able to observe the collapse of
the disclination line due to a temperature-induced anchoring angle transition,
which has allowed us to rule out the presence of a real disclination line near
the nematic/isotropic front in directional growth experiments.
61.30.Jf,61.30.G
Parity Breaking in Nematic Tactoids
We theoretically investigate under what conditions the director field in a
spindle-shaped nematic droplet or tactoid obtains a twisted, parity-broken
structure. By minimizing the sum of the bulk elastic and surface energies, we
show that a twisted director field is stable if the twist and bend elastic
constants are small enough compared to the splay elastic constant, but only if
the droplet volume is larger than some minimum value. We furthermore show that
the transition from an untwisted to a twisted director-field structure is a
sharp function of the various control parameters. We predict that suspensions
of rigid, rod-like particles cannot support droplets with a parity broken
structure, whereas they could possibly occur in those of semi-flexible,
worm-like particles.Comment: 20 pages, 9 figures, submitted to Journal of Physics: Condensed
Matte
Confinement-Induced Transition of Topological Defects in Smectic Liquid Crystals: From a Point to a Line and Pearls
We report a study on the confinement-induced transition of the topological defects of liquid crystals (LCs) using smectic-A LCs confined in prolate spheroids with homeotropic anchoring. Upon increasing the aspect ratio of a LC droplet, dispersed in a stretched elastomer film, the topological defect undergoes a transition from a point to a line of which the length is a function of the aspect ratio. Additionally, when the size of a droplet is larger than a certain value, the defect has a pearl-necklace-like texture. We propose a simple model to understand the formation of these defects in terms of the misorientation and undulation instability of the smectic layersclose9
Ordering of droplets and light scattering in polymer dispersed liquid crystal films
We study the effects of droplet ordering in initial optical transmittance
through polymer dispersed liquid crystal (PDLC) films prepared in the presence
of an electrical field. The experimental data are interpreted by using a
theoretical approach to light scattering in PDLC films that explicitly relates
optical transmittance and the order parameters characterizing both the
orientational structures inside bipolar droplets and orientational distribution
of the droplets. The theory relies on the Rayleigh-Gans approximation and uses
the Percus-Yevick approximation to take into account the effects due to droplet
positional correlations.Comment: revtex4, 18 pages, 8 figure
Topological Defects and Interactions in Nematic Emulsions
Inverse nematic emulsions in which surfactant-coated water droplets are
dispersed in a nematic host fluid have distinctive properties that set them
apart from dispersions of two isotropic fluids or of nematic droplets in an
isotropic fluid. We present a comprehensive theoretical study of the
distortions produced in the nematic host by the dispersed droplets and of
solvent mediated dipolar interactions between droplets that lead to their
experimentally observed chaining. A single droplet in a nematic host acts like
a macroscopic hedgehog defect. Global boundary conditions force the nucleation
of compensating topological defects in the nematic host. Using variational
techniques, we show that in the lowest energy configuration, a single water
droplet draws a single hedgehog out of the nematic host to form a tightly bound
dipole. Configurations in which the water droplet is encircled by a
disclination ring have higher energy. The droplet-dipole induces distortions in
the nematic host that lead to an effective dipole-dipole interaction between
droplets and hence to chaining.Comment: 17 double column pages prepared by RevTex, 15 eps figures included in
text, 2 gif figures for Fig. 1
Non-isothermal model for the direct isotropic/smectic-A liquid crystalline transition
An extension to a high-order model for the direct isotropic/smectic-A liquid
crystalline phase transition was derived to take into account thermal effects
including anisotropic thermal diffusion and latent heat of phase-ordering.
Multi-scale multi-transport simulations of the non-isothermal model were
compared to isothermal simulation, showing that the presented model extension
corrects the standard Landau-de Gennes prediction from constant growth to
diffusion-limited growth, under shallow quench/undercooling conditions.
Non-isothermal simulations, where meta-stable nematic pre-ordering precedes
smectic-A growth, were also conducted and novel non-monotonic
phase-transformation kinetics observed.Comment: First revision: 20 pages, 7 figure
Action spectroscopy of gas-phase carboxylate anions by multiple photon IR electron detachment/attachment
We report on a form of gas-phase anion action spectroscopy based on infrared
multiple photon electron detachment and subsequent capture of the free
electrons by a neutral electron scavenger in a Fourier Transform Ion Cyclotron
Resonance (FTICR) mass spectrometer. This method allows one to obtain
background-free spectra of strongly bound anions, for which no dissociation
channels are observed. The first gas-phase spectra of acetate and propionate
are presented using SF6 as electron scavenger and a free electron laser as
source of intense and tunable infrared radiation. To validate the method, we
compare infrared spectra obtained through multiple photon electron
detachment/attachment and multiple photon dissociation for the benzoate anion.
In addition, different electron acceptors are used, comparing both associative
and dissociative electron capture. The relative energies of dissociation (by
CO2 loss) and electron detachment are investigated for all three anions by DFT
and CCSD(T) methods. DFT calculations are also employed to predict vibrational
frequencies, which provide a good fit to the infrared spectra observed. The
frequencies of the symmetric and antisymmetric carboxylate stretching modes for
the aliphatic carboxylates are compared to those previously observed in
condensed-phase IR spectra and to those reported for gas-phase benzoate,
showing a strong influence of the solution environment and a slight substituent
effect on the antisymmetric stretch.Comment: Revised version, Submitted to J Phys Chem
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