97 research outputs found
Analysis of an 18O and D enhanced water spectrum and new assignments for HD18O and D218O in the near-infrared region (6000â7000 cmâ1) using newly calculated variational line lists
An experimental infrared spectrum due to Orphal and Ruth (2008) [10] recorded using isotopically enriched water in the 6000â7000 cmâ1 region is analysed and assigned. The assignment procedure is based on the use of known transition frequencies for H216O and H218O, existing variational line lists for HD16O and D216O, and newly calculated variational line lists for HD18O and D218O. These new variational line lists are presented herein. The main absorption comes from HD16O and HD18O, for which there are few previous assignments in the region. Assignments to 426 new HD18O lines are presented. In all 3254 of the 4768 lines observed in the spectrum are assigned, resulting in a number of newly determined energy levels. These assignments are in agreement with the recent work of Mikhailenko et al. (2012) [41]
Re-analysis of ammonia spectra: Updating the HITRAN 14NH3 database
AbstractThe data incorporated in the HITRAN database for 14NH3 are analyzed using a comprehensive and consistent set of quantum numbers, empirical lower energy levels and the BYTe variationally calculated line list as reference points. Labelings are checked to ensure that they obey both the usual selection rules and the HITRAN labeling formalisms; the problems identified are corrected where possible. Further assignments are brought into question by combination difference (CD) checking of implied upper energy levels. The CD analysis yields an 89% complete 14NH3 energy level list up to 6610cmâ1 and J=21, self-consistent to 0.1cmâ1. In combination with the 1723 previously unassigned and unlabeled lines in HITRAN a total of 2529 problem lines were identified for re-analysis. The compiled energy level list was used to label and assign the set of problem transitions, resulting in a total of 249 new assignments and a further 368 new labelings. Assignment by comparison with the reference line list resulted in 111 further new line assignments and 14 new labelings. Intensities are checked against recent measurements and BYTe. New intensities are proposed for the ν2 band with new intensities and line positions for the 2ν2âν2 and new line lists are created for the ν2âν2, ν2âν4 and ν4âν4 bands. BYTe band intensities are analyzed to identify other regions of missing intensity
Perceived Barriers that Prevent High School Students Seeking Help from Teachers for Bullying and their Effects on Disclosure Intentions
Many adolescents choose not to tell teachers when they have been bullied. Three studies with 12-16 year-old English adolescents addressed possible reasons. In study 1, students (N = 411, 208 females/203 males) identified reasons with no prompting. Three perceived negative outcomes were common; peers would disapprove, disclosers would feel weak/undermined, and disclosers desired autonomy. In study 2, students (N = 297, 153 females/134 males/10 unspecified) indicated how much they believed that the perceived negative outcomes would happen to them, and a substantial proportion did so. Perceived negative outcomes significantly predicted intentions to disclose being bullied. Study 3 (N = 231, 100 females/131 males) tested if the perceived negative outcomes would be strong enough to stop participants from telling a teacher even though the teacher would stop the bullying. This was the case for many of them. Participants did not report disliking peers who disclosed bullying. Theoretical and practical implications are discussed
Additive manufacturing (3D printing) of electrically conductive polymers and polymer nanocomposites and their applications
Additive manufacturing, or three-dimensional (3D) printing, offers a unique solution for fabricating complex geometries with high tolerances. Currently, many commercial additive manufacturing machines focus on the printing of polymers with limited functionalities. However, conductive polymers (CPs) can be processed to enable the additive manufacturing of conductive, low-density, and low-cost parts for a myriad of applications. This review summarizes the relevant achievements in the additive manufacturing of conductive polymers (CPs) and conductive polymer nanocomposites, with a discussion of the advantages and limitations of processing and printing these materials compared with alternative traditional manufacturing methods and their properties. Finally, the prospective applications of these additive manufacturing printed conductive materials are explored
3D printed graphene based energy storage devices
The final publication is available at Springer via http://dx.doi.org/10.1038/srep422333D printing technology provides a unique platform for rapid prototyping of numerous applications due to its ability to produce low cost 3D printed platforms. Herein, a graphene-based polylactic acid filament (graphene/PLA) has been 3D printed to fabricate a range of 3D disc electrode (3DE) configurations using a conventional RepRap fused deposition moulding (FDM) 3D printer, which requires no further modification/ex-situ curing step. To provide proof-of-concept, these 3D printed electrode architectures are characterised both electrochemically and physicochemically and are advantageously applied as freestanding anodes within Li-ion batteries and as solid-state supercapacitors. These freestanding anodes neglect the requirement for a current collector, thus offering a simplistic and cheaper alternative to traditional Li-ion based setups. Additionally, the ability of these devicesâ to electrochemically produce hydrogen via the hydrogen evolution reaction (HER) as an alternative to currently utilised platinum based electrodes (with in electrolysers) is also performed. The 3DE demonstrates an unexpectedly high catalytic activity towards the HER (â0.46 V vs. SCE) upon the 1000th cycle, such potential is the closest observed to the desired value of platinum at (â0.25 V vs. SCE). We subsequently suggest that 3D printing of graphene-based conductive filaments allows for the simple fabrication of energy storage devices with bespoke and conceptual designs to be realised
Comparison of sequencing-based methods to profile DNA methylation and identification of monoallelic epigenetic modifications.
Analysis of DNA methylation patterns relies increasingly on sequencing-based profiling methods. The four most frequently used sequencing-based technologies are the bisulfite-based methods MethylC-seq and reduced representation bisulfite sequencing (RRBS), and the enrichment-based techniques methylated DNA immunoprecipitation sequencing (MeDIP-seq) and methylated DNA binding domain sequencing (MBD-seq). We applied all four methods to biological replicates of human embryonic stem cells to assess their genome-wide CpG coverage, resolution, cost, concordance and the influence of CpG density and genomic context. The methylation levels assessed by the two bisulfite methods were concordant (their difference did not exceed a given threshold) for 82% for CpGs and 99% of the non-CpG cytosines. Using binary methylation calls, the two enrichment methods were 99% concordant and regions assessed by all four methods were 97% concordant. We combined MeDIP-seq with methylation-sensitive restriction enzyme (MRE-seq) sequencing for comprehensive methylome coverage at lower cost. This, along with RNA-seq and ChIP-seq of the ES cells enabled us to detect regions with allele-specific epigenetic states, identifying most known imprinted regions and new loci with monoallelic epigenetic marks and monoallelic expression
Aspirations to become an anaesthetist: longitudinal study of historical trends and trajectories of UK-qualified doctorsâ early career choices and of factors that have influenced their choices
WormBase 2016: expanding to enable helminth genomic research
WormBase (www.wormbase.org) is a central repository for research data on the biology, genetics and genomics of Caenorhabditis elegans and other nematodes. The project has evolved from its original remit to collect and integrate all data for a single species, and now extends to numerous nematodes, ranging from evolutionary comparators of C. elegans to parasitic species that threaten plant, animal and human health. Research activity using C. elegans as a model system is as vibrant as ever, and we have created new tools for community curation in response to the ever-increasing volume and complexity of data. To better allow users to navigate their way through these data, we have made a number of improvements to our main website, including new tools for browsing genomic features and ontology annotations. Finally, we have developed a new portal for parasitic worm genomes. WormBase ParaSite (parasite.wormbase.org) contains all publicly available nematode and platyhelminth annotated genome sequences, and is designed specifically to support helminth genomic research
Promoting Junior School Studentsâ Anti-bullying Beliefs with the CATZ Cross-age Teaching Zone Intervention
In tackling the widespread problem of bullying victimisation, researchers have acknowledged the value of focusing on changing bullying-related beliefs and using peer-based interventions. In three studies (Nâ=â419, 237 intervention and 182 controls), we tested the effectiveness of the CATZ cross-age teaching programme by inviting small groups of 11-year-olds to incorporate information supporting positive beliefs (concerning non-physical forms of bullying, the value of disclosing being bullied to adults, and helping victims) into a lesson they devised for themselves and to deliver that to small groups of 9-year-olds. Specifically, we examined if the intervention would promote that (i) non-physical forms of bullying are unacceptable (study 1), (ii) disclosing bullying to adults and getting the right kind of help have value and importance (study 2), and (iii) victims can be assisted in safe ways (study 3). Self-reports of nine specific aspects of these beliefs were collected from CATZ tutors and age-matched controls prior to and following the intervention, and at five-week follow-up in one study, using both open and closed questions. Results indicated significant positive effects of CATZ on all nine outcome variables, with mostly medium and high effect sizes. These findings support the use of CATZ to foster positive anti-bullying beliefs, and issues related to its wider uptake are discussed.N/
Cover Picture: NextâGeneration Additive Manufacturing: Tailorable Graphene/Polylactic(acid) Filaments Allow the Fabrication of 3D Printable Porous Anodes for Utilisation within LithiumâIon Batteries (Batteries & Supercaps 5/2019)
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