A New Method for Characterization of Natural Zeolites and Organic Nanostructure using Atomic Force Microscopy

In order to study and develop an economic solution to environmental pollution in water, a wide variety of materials were investigated. Natural zeolites emerge from that research as the best in class of this category. Zeolites are natural materials relatively abundant and non biodegradable, economic and good to perform processes of environmental remediation. This paper contains a full description of a new method to characterize superficial properties of natural zeolites of exotic provenience (Caribbean Islets) with atomic force microscopy (AFM). AFM works with the optical microscope simplicity and the high resolution typical of a transmission electron microscope (TEM). Structural information of mesoporous material is obtained using scanning and transmission electron microscopy (SEM and TEM), only if the sample is conductive, otherwise the sample has to be processed through the grafitation technique, but this procedure induces errors of topography. Therefore, the existing AFM method, to observe zeolite powders, is made in a liquid cell-head scanner, but this work puts in evidence and confirms that it is possible to use an ambient air-head scanner to obtain a new kind of microtopography. Once optimized, this new method allows investigating of organic micelles, very soft nanostructure, of cetyltriammonium bromide (CTAB) upon an inorganic surface such as natural zeolites. It is shown some correlation between SEM microphotographies and AFM 3D images

Domain-independent neural underpinning of task-switching: an fMRI investigation

The ability to shift between different tasks according to internal or external demands, which is at the core of our behavioral flexibility, has been generally linked to the functionality of left fronto-parietal regions. Traditionally, the left and right hemispheres have also been associated with verbal and spatial processing, respectively. We therefore investigated with functional MRI whether the processes engaged during task-switching interact in the brain with the domain of the tasks to be switched, that is, verbal or spatial. Importantly, physical stimuli were exactly the same and participants\u2019 performance was matched between the two domains. The fMRI results showed a clearly left-lateralized involvement of fronto-parietal regions when contrasting task-switching vs. single task blocks in the context of verbal rules. A more bilateral pattern, especially in the prefrontal cortex, was instead observed for switching between spatial tasks. Moreover, while a conjunction analysis showed that the core regions involved in task-switching, independently of the switching context, were localized both in left inferior prefrontal and parietal cortices and in bilateral supplementary motor area, a direct analysis of functional lateralization revealed that hemispheric asymmetries in the frontal lobes were more biased toward the left side for the verbal domain than for the spatial one and vice versa. Overall, these findings highlight the role of left fronto-parietal regions in task-switching, above and beyond the specific task requirements, but also show that hemispheric asymmetries may be modulated by the more specific nature of the tasks to be performed during task-switching

Flow curvature effects on dynamic behaviour of a novel vertical axis tidal current turbine: numerical and experimental analysis

The paper deals with performances analysis of vertical axis turbine to exploit tidal marine currents. Flow curvature effects on performences of a novel vertical axis turbine have been investuigated. It has been shown that the flow curvature effect allows to design properly an accurate airfoil shape to increase turbine performances

Endoscopic scores for inflammatory bowel disease in the era of 'mucosal healing'. old problem, new perspectives

The importance of the endoscopic evaluation in inflammatory bowel disease (IBD) management has been recognized for many years. However, the modalities for reporting endoscopic activity represent an ongoing challenge. To address this, several endoscopic scores have been proposed. Very few have been properly validated, and the use of such tools remains sub-optimal and is mainly restricted to clinical trials. In recent years, a growing emphasis of the concept of 'mucosal healing' as a prognostic marker and therapeutic goal has increased the need for a more accurate definition of endoscopic activity in both ulcerative colitis (UC) and Crohn's Disease (CD). In the present review, the evolution of the challenges related to endoscopic scores in IBD has been analyzed, with particular attention paid to the renewed relevance of endoscopic activity in recent years. Currently, despite the growing relevance of endoscopic activity, evaluating this activity in IBD is still a challenge. The implementation of efficacious endoscopic scores and a better definition of the absence of activity (mucosal healing) are needed.The importance of the endoscopic evaluation in inflammatory bowel disease (IBD) management has been recognized for many years. However, the modalities for reporting endoscopic activity represent an ongoing challenge. To address this, several endoscopic scores have been proposed. Very few have been properly validated, and the use of such tools remains sub-optimal and is mainly restricted to clinical trials. In recent years, a growing emphasis of the concept of 'mucosal healing' as a prognostic marker and therapeutic goal has increased the need for a more accurate definition of endoscopic activity in both ulcerative colitis (UC) and Crohn's Disease (CD). In the present review, the evolution of the challenges related to endoscopic scores in IBD has been analyzed, with particular attention paid to the renewed relevance of endoscopic activity in recent years. Currently, despite the growing relevance of endoscopic activity, evaluating this activity in IBD is still a challenge. The implementation of efficacious endoscopic scores and a better definition of the absence of activity (mucosal healing) are needed

Improvement of heart rate recovery after exercise training in older people.

Twenty-four subjects aged 70 and older were retrospectively selected from our archives and screened for symptoms of cardiovascular disease. Baseline exercise test was negative for myocardial ischemia in all subjects. All subjects had completed an 8-week program, performed for a variety of indications and consisting of an aerobic physical training program including 30 minutes of cycling three times per week at 65% to 75% of maximum heart rate achieved at peak exercise test performed at enrollment, an educational intervention, dietary advice, and psychological support. All subjects underwent a cardiopulmonary exercise test (CPX) before and at the end of exercise training. At the end of each CPX, peak oxygen uptake (VO2peak), the rate of increase of ventilation per unit of increase of carbon dioxide production (VE/VCO2slope), and HRR were recorded. Twenty-five healthy subjects younger than 60 with no evidence of exercise-induced myocardial ischemia and not enrolled in any exercise training program were also retrospectively selected from our archives and used as a control group for analyzing HRR. These patients performed two exercise tests several weeks apart. Several studies have shown that changes in vagal tone can be used as an outcome tool that helps identify patients or subjects with or without cardiovascular disease at risk for a cardiovascular event, although the evidence of a prognostic value of HRR in older subjects without cardiovascular disease is rather poor. In this study, exercise training resulted in HRR improvement in healthy elderly subjects, suggesting that exercise training improves vagal/sympathetic balance in older subjects without cardiovascular disease as well. Whether the observed improvement in HRR may have long-term beneficial prognostic effects was not the aim of the study, although a beneficial effect might be postulated, in light of the Framingham dat

noRANSAC for fundamental matrix estimation

The estimation of the fundamental matrix from a set of corresponding points is a relevant topic in epipolar stereo geometry [10]. Due to the high amount of outliers between the matches, RANSAC-based approaches [7, 13, 29] have been used to obtain the fundamental matrix. In this paper two new contributes are presented: a new normalized epipolar error measure which takes into account the shape of the features used as matches [17] and a new strategy to compare fundamental matrices. The proposed error measure gives good results and it does not depend on the image scale. Moreover, the new evaluation strategy describes a valid tool to compare different RANSAC-based methods because it does not rely on the inlier ratio, which could not correspond to the best allowable fundamental matrix estimated model, but it makes use of a reference ground truth fundamental matrix obtained by a set of corresponding points given by the use

Intertwined Rashba, Dirac and Weyl Fermions in Hexagonal Hyperferroelectrics

By means of density functional theory based calculations, we study the role of spin-orbit coupling in the new family of ABC hyperferroelectrics [Phys. Rev. Lett. 112, 127601 (2014)]. We unveil an extremely rich physics strongly linked to ferroelectric properties, ranging from the electric control of bulk Rashba effect to the existence of a three dimensional topological insulator phase, with concomitant topological surface states even in the ultrathin film limit. Moreover, we predict that the topological transition, as induced by alloying, is followed by a Weyl semi-metal phase of finite concentration extension, which is robust against disorder, putting forward hyperferroelectrics as promising candidates for spin-orbitronic applications.Comment: 5 pages, 3 figure

Asymptotic Expansion for the Wave Function in a one-dimensional Model of Inelastic Interaction

We consider a two-body quantum system in dimension one composed by a test particle interacting with an harmonic oscillator placed at the position $a>0$. At time zero the test particle is concentrated around the position $R_0$ with average velocity $\pm v_0$ while the oscillator is in its ground state. In a suitable scaling limit, corresponding for the test particle to a semi-classical regime with small energy exchange with the oscillator, we give a complete asymptotic expansion of the wave function of the system in both cases $R_0 <a$ and $R_0 >a$.Comment: 23 page

Experimental validation of the exact analytical solution to the steady periodic heat transfer problem in a PCM layer

Phase change materials (PCM) are used in many industrial and residential applications for their advantageous characteristic of high capacity of latent thermal storage by means of an isothermal process. In this context, it is very useful to have predictive mathematical models for the analysis of the thermal performance and for the thermal design of these layers. In this work, an experimental validation of an analytical model that resolves the steady periodic heat transfer problem in a finite layer of PCM is presented. The experimental investigation was conducted employing a PCM with thermophysical and thermochemical behavior very close to those hypothesized in the formulation of the analytical model. For the evaluation of the thermophysical properties of the PCM sample used, an experimental procedure created by the authors was employed. In all tests realized in a sinusoidal and non-sinusoidal periodic regime, the comparison between the measured and calculated trends of the temperature at different sample heights and of the surface heat fluxes show an excellent agreement. Moreover, also having verified the analytical total stored energy, the analytical model constitutes a valid instrument for the evaluation of the latent and sensible contribution and the trend in time of the position of the bi-phase interface.The work was partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER), ENE2015-64117-C5-3-R (MINECO/FEDER), and ULLE10-4E-1305). GREA is certified agent TECNIO in the category of technology developers from the Government of Catalonia. The authors would like to thank the Catalan Government for the quality accreditation given to their research group (2014 SGR 123). This project has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) under Grant agreement Nº PIRSES-GA-2013-610692 (INNOSTORAGE) and from European Union's Horizon 2020 research and innovation programme under grant agreement Nº 657466 (INPATH-TES). Alvaro de Gracia would like to thank Ministerio de Economia y Competitividad de España for Grant Juan de la Cierva, FJCI-2014-19940. Julià Coma would like to thank the Departament d'Universitats, Recerca i Societat de la Informació de la Generalitat de Catalunya for his research fellowship (2016FI_B2 00147). Aran Solé would like to thank Ministerio de Economía y Competitividad de España for Grant Juan de la Cierva, FJCI-2015-25741