A Laplace Transform Method for Molecular Mass Distribution Calculation from Rheometric Data

Polydisperse linear polymer melts can be microscopically described by the tube model and fractal reptation dynamics, while on the macroscopic side the generalized Maxwell model is capable of correctly displaying most of the rheological behavior. In this paper, a Laplace transform method is derived and different macroscopic starting points for molecular mass distribution calculation are compared to a classical light scattering evaluation. The underlying assumptions comprise the modern understanding on polymer dynamics in entangled systems but can be stated in a mathematically generalized way. The resulting method is very easy to use due to its mathematical structure and it is capable of calculating multimodal molecular mass distributions of linear polymer melts

Comparison of Theory and Direct Numerical Simulations of Drag Reduction by Rodlike Polymers in Turbulent Channel Flows

Numerical simulations of turbulent channel flows, with or without additives, are limited in the extent of the Reynolds number \Re and Deborah number \De. The comparison of such simulations to theories of drag reduction, which are usually derived for asymptotically high \Re and \De, calls for some care. In this paper we present a study of drag reduction by rodlike polymers in a turbulent channel flow using direct numerical simulation and illustrate how these numerical results should be related to the recently developed theory

A multi-wavelength view of galaxy evolution with AKARI

AKARI's all-sky survey resolves the far-infrared emission in many thousands of nearby galaxies, providing essential local benchmarks against which the evolution of high-redshift populations can be measured. This review presents some recent results in the resolved galaxy populations, covering some well-known nearby targets, as well as samples from major legacy surveys such as the Herschel Reference Survey and the JCMT Nearby Galaxies Survey. This review also discusses the prospects for higher redshifts surveys, including strong gravitational lens clusters and the AKARI NEP field.Comment: Accepted for Publications of the Korean Astronomical Society (September 30, 2012 issue, volume 27, No. 3), Proceedings of the Second AKARI conference, Legacy of AKARI: A Panoramic View of the Dusty Universe. 6 page

Cyclic motion and inversion of surface flow direction in a dense polymer brush under shear

Using molecular simulations, we study the properties of a polymer brush in contact with an explicit solvent under Couette and Poiseuille flow. The solvent is comprised of chemically identical chains. We present evidence that individual, unentangled chains in the dense brush exhibit cyclic, tumbling motion and non-Gaussian fluctuations of the molecular orientations similar to the behaviour of isolated tethered chains in shear flow. The collective molecular motion gives rise to an inversion of hydrodynamic flow direction in the vicinity of the brush-coated surface. Utilising Couette and Poiseuille flow, we investigate to what extend the effect of a brush-coated surface can be described by a Navier slip condition.Comment: 6 pages, 6 figures, submitted for publicatio

Turbulent Drag Reduction by Flexible and Rodlike Polymers: Crossover Effects at Small Concentrations

Drag reduction by polymers is bounded between two universal asymptotes, the von-K\'arm\'an log-law of the law and the Maximum Drag Reduction (MDR) asymptote. It is theoretically understood why the MDR asymptote is universal, independent of whether the polymers are flexible or rodlike. The cross-over behavior from the Newtonian von-K\'arm\'an log-law to the MDR is however not universal, showing different characteristics for flexible and rodlike polymers. In this paper we provide a theory for this cross-over phenomenology.Comment: 5 pages, 4 figures, submitted to Physical Review

Conformational transformations induced by the charge-curvature interaction at finite temperature

The role of thermal fluctuations on the conformational dynamics of a single closed filament is studied. It is shown that, due to the interaction between charges and bending degrees of freedom, initially circular aggregates may undergo transformation to polygonal shape. The transition occurs both in the case of hardening and softening charge-bending interaction. In the former case the charge and curvature are smoothly distributed along the chain while in the latter spontaneous kink formation is initiated. The transition to a non-circular conformation is analogous to the phase transition of the second kind.Comment: 23 pages (Latex), 10 figures (Postscript), 2 biblio file (bib-file and bbl-file

Mean first passage times for bond formation for a Brownian particle in linear shear flow above a wall

Motivated by cell adhesion in hydrodynamic flow, here we study bond formation between a spherical Brownian particle in linear shear flow carrying receptors for ligands covering the boundary wall. We derive the appropriate Langevin equation which includes multiplicative noise due to position-dependent mobility functions resulting from the Stokes equation. We present a numerical scheme which allows to simulate it with high accuracy for all model parameters, including shear rate and three parameters describing receptor geometry (distance, size and height of the receptor patches). In the case of homogeneous coating, the mean first passage time problem can be solved exactly. In the case of position-resolved receptor-ligand binding, we identify different scaling regimes and discuss their biological relevance.Comment: final version after minor revision

Morphological Classification of Galaxies by Shapelet Decomposition in the Sloan Digital Sky Survey II: Multiwavelength Classification

We describe the application of the `shapelet' linear decomposition of galaxy images to multi-wavelength morphological classification using the $u,g,r,i,$ and $z$-band images of 1519 galaxies from the Sloan Digital Sky Survey. We utilize elliptical shapelets to remove to first-order the effect of inclination on morphology. After decomposing the galaxies we perform a principal component analysis on the shapelet coefficients to reduce the dimensionality of the spectral morphological parameter space. We give a description of each of the first ten principal component's contribution to a galaxy's spectral morphology. We find that galaxies of different broad Hubble type separate cleanly in the principal component space. We apply a mixture of Gaussians model to the 2-dimensional space spanned by the first two principal components and use the results as a basis for classification. Using the mixture model, we separate galaxies into three classes and give a description of each class's physical and morphological properties. We find that the two dominant mixture model classes correspond to early and late type galaxies, respectively. The third class has, on average, a blue, extended core surrounded by a faint red halo, and typically exhibits some asymmetry. We compare our method to a simple cut on $u-r$ color and find the shapelet method to be superior in separating galaxies. Furthermore, we find evidence that the $u-r=2.22$ decision boundary may not be optimal for separation between early and late type galaxies, and suggest that the optimal cut may be $u-r \sim 2.4$.Comment: 42 pages, 18 figs, revised version in press at AJ. Some modification to the technique, more discussion, addition/deletion/modification of several figures, color figures have been added. A high resolution version may be obtained at http://bllac.as.arizona.edu/~bkelly/shapelets/shapelets_ugriz.ps.g

Confinement and Viscoelastic effects on Chain Closure Dynamics

Chemical reactions inside cells are typically subject to the effects both of the cell's confining surfaces and of the viscoelastic behavior of its contents. In this paper, we show how the outcome of one particular reaction of relevance to cellular biochemistry - the diffusion-limited cyclization of long chain polymers - is influenced by such confinement and crowding effects. More specifically, starting from the Rouse model of polymer dynamics, and invoking the Wilemski-Fixman approximation, we determine the scaling relationship between the mean closure time t_{c} of a flexible chain (no excluded volume or hydrodynamic interactions) and the length N of its contour under the following separate conditions: (a) confinement of the chain to a sphere of radius D, and (b) modulation of its dynamics by colored Gaussian noise. Among other results, we find that in case (a) when D is much smaller than the size of the chain, t_{c}\simND^{2}, and that in case (b), t_{c}\simN^{2/(2-2H)}, H being a number between 1/2 and 1 that characterizes the decay of the noise correlations. H is not known \`a priori, but values of about 0.7 have been used in the successful characterization of protein conformational dynamics. At this value of H (selected for purposes of illustration), t_{c}\simN^3.4, the high scaling exponent reflecting the slow relaxation of the chain in a viscoelastic medium

An Extended Network Model with a Packages Diffusion Process

The dynamics of a packages diffusion process within a selforganized network is analytically studied by means of an extended $f$% -spin facilitated kinetic Ising model (Fredrickson-Andersen model) using a Fock-space representation for the master equation. To map the three component system (active, passive and packages cells) onto a lattice we apply two types of second quantized operators. The active cells correspond to mobile states whereas the passive cells correspond to immobile states of the Fredrickson-Andersen model. An inherent cooperativity is included assuming that the local dynamics and subsequently the local mobilities are restricted by the occupation of neighboring cells. Depending on a temperature-like parameter $h^{-1}$ (interconnectivity) the diffusive process of the packages (information) can be almost stopped, thus we get a well separation of the time regimes and a quasi-localization for the intermediate range at low temperatures.Comment: 13 pages and 1 figur