Femtosecond pump/supercontinuum-probe spectroscopy: Optimized setup and signal analysis for single-shot spectral referencing

A setup for pump/supercontinuum-probe spectroscopy is described which (i) is optimized to cancel fluctuations of the probe light by single-shot referencing, and (ii) extends the probe range into the near-uv (1000–270 nm). Reflective optics allow 50 μm spot size in the sample and upon entry into two separate spectrographs. The correlation γsame between sample and reference readings of probe light level at every pixel exceeds 0.99, compared to γconsec<0.92 reported for consecutive referencing. Statistical analysis provides the confidence interval of the induced optical density, ΔOD. For demonstration we first examine a dye (Hoechst 33258) bound in the minor groove of double-stranded DNA. A weak 1.1 ps spectral oscillation in the fluorescence region, assigned to DNA breathing, is shown to be significant. A second example concerns the weak vibrational structure around t=0 which reflects stimulated Raman processes. With 1% fluctuations of probe power, baseline noise for a transient absorption spectrum becomes 25 μOD rms in 1 s at 1 kHz, allowing to record resonance Raman spectra of flavine adenine dinucleotide in the S0 and S1 stateWe are grateful to the Deutsche Forschungsgemeinschaft for support (SFB 450 and Cluster of Excellence “Unifying Concepts in Catalysis”)S

New model for system of mesoscopic Josephson contacts

Quantum fluctuations of the phases of the order parameter in 2D arrays of mesoscopic Josephson junctions and their effect on the destruction of superconductivity in the system are investigated by means of a quantum-cosine model that is free of the incorrect application of the phase operator. The proposed model employs trigonometric phase operators and makes it possible to study arrays of small superconducting granules, pores filled with superfluid helium, or Josephson junctions in which the average number of particles $n_0$ (effective bosons, He atoms, and so on) is small, and the standard approach employing the phase operator and the particle number operator as conjugate ones is inapplicable. There is a large difference in the phase diagrams between arrays of macroscopic and mesoscopic objects for $n_0 < 5$ and $U<J$ ($U$ is the characteristic interaction energy of the particle per granule and $J$ is the Josephson coupling constant). Reentrant superconductivity phenomena are discussed.Comment: 4 pages, 3 Postscript figure

Electron Correlations in an Electron Bilayer at Finite Temperature: Landau Damping of the Acoustic Plasmon

We report angle-resolved Raman scattering observations of the temperature dependent Landau damping of the acoustic plasmon in an electron bilayer system realised in a GaAs double quantum well structure. Corresponding calculations of the charge-density excitation spectrum of the electron bilayer using forms of the random phase approximation (RPA), and the static local field formalism of Singwi, Tosi, Land and Sj\"{o}lander (STLS) extended to incorporate non-zero electron temperature $T_{\rm e}$ and phenomenological damping, are also presented. The STLS calculations include details of the temperature dependence of the intra- and inter-layer local field factors and pair-correlation functions. Good agreement between experiment and the various theories is obtained for the acoustic plasmon energy and damping for $T_{\rm e} \lesssim T_{\rm F}/2$, the Fermi temperature. However, contrary to current expectations, all of the calculations show significant departures from our experimental data for $T_{\rm e} \gtrsim T_{\rm F}/2$. From this, we go on to demonstrate unambiguously that real local field factors fail to provide a physically accurate description of exchange correlation behaviour in low dimensional electron gases. Our results suggest instead that one must resort to a {\em{dynamical}} local field theory, characterised by a {\em{complex}} field factor to provide a more accurate description.Comment: 53 pages, 16 figure

HIGH-RESOLUTION LAMB DIP SPECTROSCOPY ON OD AND SiCl IN A MOLECULAR BEAM

Contains fulltext : 99073.pdf (publisher's version ) (Open Access

Statistical Mechanics of Structural Fluctuations

The theory of mesoscopic fluctuations is applied to inhomogeneous solids consisting of chaotically distributed regions with different crystalline structure. This approach makes it possible to describe statistical properties of such mixture by constructing a renormalized Hamiltonian. The relative volumes occupied by each of the coexisting structures define the corresponding geometric probabilities. In the case of a frozen heterophase system these probabilities should be given a priori. And in the case of a thermal heterophase mixture the structural probabilities are to be defined self-consistently by minimizing a thermodynamical potential. This permits to find the temperature behavior of the probabilities which is especially important near the points of structural phase transitions. The presense of these structural fluctuations yields a softening of a crystal and a decrease of the effective Debye temperature. These effects can be directly seen by nuclear gamma resonance since the occurrence of structural fluctuations is accompanied by a noticeable sagging of the M\"ossbauer factor at the point of structural phase transition. The structural fluctuations also lead to the attenuation of sound and increase of isothermic compressibility.Comment: 1 file, 18 pages, RevTex, no figure

Temperature dependence of the EPR linewidth of Yb3+ - ions in Y0.99Yb0.01Ba2Cu3OX compounds: Evidence for an anomaly near TC

Electron paramagnetic resonance experiments on doped Yb3+ ions in YBaCuO compounds with different oxygen contents have been made. We have observed the strong temperature dependence of the EPR linewidth in the all investigated samples caused by the Raman processes of spin-lattice relaxation. The spin-lattice relaxation rate anomaly revealed near TC in the superconducting species can be assigned to the phonon density spectrum changesComment: 10 pages, 4 figures Renewed versio