Beyond Yield Optimization: The Impact of Organosolv Process Parameters on Lignin Structure

When optimizing the process parameters of the acidic ethanolic organosolv process, the aim is usually to maximize the delignification and/or lignin purity. However, process parameters such as temperature, time, ethanol and catalyst concentration, respectively, can also be used to vary the structural properties of the obtained organosolv lignin, including the molecular weight and the ratio of aliphatic versus phenolic hydroxyl groups, among others. This review particularly focuses on these influencing factors and establishes a trend analysis between the variation of the process parameters and the effect on lignin structure. Especially when larger data sets are available, as for process temperature and time, correlations between the distribution of depolymerization and condensation reactions are found, which allow direct conclusions on the proportion of lignin's structural features, independent of the diversity of the biomass used. The newfound insights gained from this review can be used to tailor organosolv lignins isolated for a specific application

Lignin-Depolymerisation via UV-Photolysis and Titanium Dioxide Photocatalysis

Today, more than 70 million tons of lignin are produced by the pulp and paper industry every year. However, the utilization of lignin as a source for chemical synthesis is still limited due to the complex and heterogeneous lignin structure. The purpose of this study was a selective photodegradation of industrially available kraft lignin in order to obtain appropriate fragments and building block chemicals for further utilization, e.g. polymerization. Thus, kraft lignin obtained from soft wood black liquor by acidification was dissolved in sodium hydroxide and irradiated at a wavelength of 254 nm with and without the presence of titanium dioxide in various concentrations. Analyses of the irradiated products via SEC showed decreasing molar masses and decreasing polydispersity indices over time. At the end of the irradiation period the lignin was depolymerised to form fragments as small as the lignin monomers. TOC analyses showed minimal mineralisation due to the depolymerisation process

Approximation solution for steel concrete beam accounting high-order shear deformation using trigonometric-series

Steel concrete beams have a reasonable structure in terms of using material and high load carrying capacity. This paper deals with an approximate solution based on a trigonometric series for the static of steel concrete beams. The displacement field is based on the higher-order theory using Reddy’s hypothesis. The governing equations are derived from variation principles. An approximate solution based on the representation of displacement fields by trigonometric series is developed to solve the static problem of steel concrete beams. In order to verify the accuracy of the present approximate solution, numerical results are compared with those of exact solutions using classical beam theory. The displacements and nominal stress distributions in the depth direction are obtained with various high of beams. The present approximate approach can accurately predict the displacements and stresses of steel concrete beams

Approximation solution for steel concrete beam accounting high-order shear deformation using trigonometric-series

Steel concrete beams have a reasonable structure in terms of using material and high load carrying capacity. This paper deals with an approximate solution based on a trigonometric series for the static of steel concrete beams. The displacement field is based on the higher-order theory using Reddy’s hypothesis. The governing equations are derived from variation principles. An approximate solution based on the representation of displacement fields by trigonometric series is developed to solve the static problem of steel concrete beams. In order to verify the accuracy of the present approximate solution, numerical results are compared with those of exact solutions using classical beam theory. The displacements and nominal stress distributions in the depth direction are obtained with various high of beams. The present approximate approach can accurately predict the displacements and stresses of steel concrete beams

HỢP TÁC VIỆT - NGA TRONG CHẾ TẠO VÀ THỬ NGHIỆM MÁY THĂM DÒ ĐIỆN TỔ HỢP TEC-2 PHỤC VỤ KHẢO SÁT MÔI TRƯỜNG ĐỊA CHẤT TẦNG NÔNG

The geophysical investigation system named TEC-2 (Tomography Electric Complex-2) was designed, installed and tested in Institute of Marine Geology and Geophysics. This TEC-2 is the scientific cooperation product of Geomagnetic and Geoelectric Department of and POI and Geo - environmental Department of IMGG-VAST. The test results using TEC-2 show the capability of investigating by using certain pole system, short investigation time, high stability, the accuracy of two investigation times being more than 92%. The distributed design of electric poles, measuring operation, parameter selection, … are programmed and controlled automatically by computer. The TEC-2 system was used for investigating the weak structures in islands of Song Tu Tay, Son Ca, Nam Yet and Sinh Ton in Truong Sa Archipelagos and shallow geological environment in the area of Red River bank in Son Tay Hanoi. The acquired data  contributed to the success of the scientific projects managed by IMGG in the National Program of Bien Dong and islands in the period of 2011 - 2013 and VAST’s research project in the period of 2013 - 2014.Máy đo điện tổ hợp TEC-2 (Tomography Electric Complex-2)  được thiết kế, lắp ráp và thử nghiệm tại Viện Địa chất và Địa vật lý biển là sản phẩm hợp tác khoa học giữa phòng Địa từ điện của Viện Hàn lâm Khoa học Nga chi nhánh Viễn Đông (POI) và phòng Địa môi trường thuộc Viện Địa chất và Địa vật lý biển (IMGG). Kết quả đo thử nghiệm máy TEC-2 cho thấy khả năng đo tổ hợp nhiều phương pháp trên hệ điện cực bố trí sẵn, thời gian đo nhanh, độ ổn định của kết quả đo cao, độ chính xác giữa hai lần đo đạt trên 92%. Các thiết kế hệ điện cực, thao tác đo, chọn tham số được lập trình và điều khiển tự động bằng máy tính. Máy TEC-2 đã được sử dụng để nghiên cứu các đới cấu trúc yếu thuộc các đảo san hô Song Tử Tây, Cơn Ca, Nam Yết và Sinh Tồn thuộc quần đảo Trường Sa và môi trường địa chất tầng nông khu vực ven bờ Sông Hồng khu vực Sơn Tây Hà Nội. Các kết quả thu thập được đã đóng góp một phần quan trọng cho sự thành công của đề tài nghiên cứu do Viện Địa chất và Địa Vật lý biển chủ trì thuộc Chương trình Biển Đông và Hải đảo giai đoạn 2011 - 2013 và đề tài cấp Viện Hàn lâm Khoa học và Công nghệ Việt Nam giai đoạn 2013 - 2014

Research on marine environment and coral distribution on Nam Yet island using VNRedsat-1 and QuickBird images

Based on the processing of VNRedsat-1 and QuickBird images in the area of Truong Sa archipelago, the research results showed the efficiency of assessing marine environmental characteristics in surroundings of these islands. In this paper, we presented the research results on Nam Yet island and adjacent area. The marine parameters in this research include sea surface temperature (SST) and chlorophyll-a concentration in the surface layer as well as in the deep layers of 20m and 40m, the distributions of the ground objects such as coral shelf, sand accumulation, coral reef combined with seagrass and seaweed. The accuracy of assessment of supervised and unsupervised classified results is approximate of 87.8%. The research results allowed assessing the environmental characteristics, warning of the risk of erosion and coastal line change in the study area

Sesquiterpenes and sterols from the soft coral Sinularia cruciata

Two sesquiterpenes as sinularianin D (1) and 1S*,4S*,5S*,10R*-4,10-guaianediol (2), and three sterols as 24-methylenecholestane-3β,5α,6β-triol-6-monoacetate (3), 3β,7α-dihydroxyergosta-5,24(28)-diene (4), and 3β-hydroxyandrost-5-ene-17-one (5), were isolated from a methanol extract of the soft coral Sinularia cruciata. Their structures were elucidated by 1D and 2D-NMR experiments and comparison of their NMR data with reported values. This is the first report of these compounds from S. cruciat

A Bibliometric Analysis of the Global Research Trend in Child Maltreatment

Child maltreatment remains a major health threat globally that requires the understanding of socioeconomic and cultural contexts to craft effective interventions. However, little is known about research agendas globally and the development of knowledge-producing networks in this field of study. This study aims to explore the bibliometric overview on child maltreatment publications to understand their growth from 1916 to 2018. Data from the Web of Science Core Collection were collected in May 2018. Only research articles and reviews written in the English language were included, with no restrictions by publication date. We analyzed publication years, number of papers, journals, authors, keywords and countries, and presented the countries collaboration and co-occurrence keywords analysis. From 1916 to 2018, 47, 090 papers (53.0% in 2010–2018) were published in 9442 journals. Child Abuse & Neglect (2576 papers; 5.5%); Children and Youth Services Review (1130 papers; 2.4%) and Pediatrics (793 papers, 1.7%) published the most papers. The most common research areas were Psychology (16, 049 papers, 34.1%), Family Studies (8225 papers, 17.5%), and Social Work (7367 papers, 15.6%). Among 192 countries with research publications, the most prolific countries were the United States (26, 367 papers), England (4676 papers), Canada (3282 papers) and Australia (2664 papers). We identified 17 authors who had more than 60 scientific items. The most cited papers (with at least 600 citations) were published in 29 journals, headed by the Journal of the American Medical Association (JAMA) (7 papers) and the Lancet (5 papers). This overview of global research in child maltreatment indicated an increasing trend in this topic, with the world’s leading centers located in the Western countries led by the United States. We called for interdisciplinary research approaches to evaluating and intervening on child maltreatment, with a focus on low-middle income countries (LMICs) settings and specific contexts