Nonlinear dynamics in superlattices driven by high frequency ac-fields

We investigate the dynamical processes taking place in nanodevices driven by high-frequency electromagnetic fields. We want to elucidate the role of different mechanisms that could lead to loss of quantum coherence. Our results show how the dephasing effects of disorder that destroy after some periods coherent oscillations, such as Rabi oscillations, can be overestimated if we do not consider the electron-electron interactions that can reduce dramatically the decoherence effects of the structural imperfections. Experimental conditions for the observation of the predicted effects are discussed.Comment: REVTEX (8 pages) and 4 figures (Postscript

Inertial and dimensional effects on the instability of a thin film

We consider here the effects of inertia on the instability of a flat liquid film under the effects of capillary and intermolecular forces (van der Waals interaction). Firstly, we perform the linear stability analysis within the long wave approximation, which shows that the inclusion of inertia does not produce new regions of instability other than the one previously known from the usual lubrication case. The wavelength, $\lambda_m$, corresponding to he maximum growth, $\omega_m$, and the critical (marginal) wavelength do not change at all. The most affected feature of the instability under an increase of the Laplace number is the noticeable decrease of the growth rates of the unstable modes. In order to put in evidence the effects of the bidimensional aspects of the flow (neglected in the long wave approximation), we also calculate the dispersion relation of the instability from the linearized version of the complete Navier-Stokes (N-S) equation. Unlike the long wave approximation, the bidimensional model shows that $\lambda_m$ can vary significantly with inertia when the aspect ratio of the film is not sufficiently small. We also perform numerical simulations of the nonlinear N-S equations and analyze to which extent the linear predictions can be applied depending on both the amount of inertia involved and the aspect ratio of the film

Emergence of massless Dirac fermions in graphene's Hofstadter butterfly at switches of the quantum Hall phase connectivity

The fractal spectrum of magnetic minibands (Hofstadter butterfly), induced by the moir\'e super- lattice of graphene on an hexagonal crystal substrate, is known to exhibit gapped Dirac cones. We show that the gap can be closed by slightly misaligning the substrate, producing a hierarchy of conical singularities (Dirac points) in the band structure at rational values Phi = (p/q)(h/e) of the magnetic flux per supercell. Each Dirac point signals a switch of the topological quantum number in the connected component of the quantum Hall phase diagram. Model calculations reveal the scale invariant conductivity sigma = 2qe^2 / pi h and Klein tunneling associated with massless Dirac fermions at these connectivity switches.Comment: 4 pages, 6 figures + appendix (3 pages, 1 figure

Copper(I)-Phosphinite Complexes in Click Cycloadditions: Three-Component Reactions and Preparation of 5-Iodotriazoles

© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.The remarkable activity displayed by copper(I)–phosphinite complexes of general formula [CuBr(L)] in two challenging cycloadditions is reported: a) the one-pot azidonation/cycloaddition of boronic acids, NaN3, and terminal alkynes; b) the cycloaddition of azides and iodoalkynes. These air-stable catalysts led to very good results in both cases and the expected triazoles could be isolated in pure form under ‘Click-suitable’ conditions

Andreev reflection from a topological superconductor with chiral symmetry

It was pointed out by Tewari and Sau that chiral symmetry (H -> -H if e h) of the Hamiltonian of electron-hole (e-h) excitations in an N-mode superconducting wire is associated with a topological quantum number Q\in\mathbb{Z} (symmetry class BDI). Here we show that Q=Tr(r_{he}) equals the trace of the matrix of Andreev reflection amplitudes, providing a link with the electrical conductance G. We derive G=(2e^2/h)|Q| for |Q|=N,N-1, and more generally provide a Q-dependent upper and lower bound on G. We calculate the probability distribution P(G) for chaotic scattering, in the circular ensemble of random-matrix theory, to obtain the Q-dependence of weak localization and mesoscopic conductance fluctuations. We investigate the effects of chiral symmetry breaking by spin-orbit coupling of the transverse momentum (causing a class BDI-to-D crossover), in a model of a disordered semiconductor nanowire with induced superconductivity. For wire widths less than the spin-orbit coupling length, the conductance as a function of chemical potential can show a sequence of 2e^2/h steps - insensitive to disorder.Comment: 10 pages, 5 figures. Corrected typo (missing square root) in equations A13 and A1

Extended topological group structure due to average reflection symmetry

We extend the single-particle topological classification of insulators and superconductors to include systems in which disorder preserves average reflection symmetry. We show that the topological group structure of bulk Hamiltonians and topological defects is exponentially extended when this additional condition is met, and examine some of its physical consequences. Those include localization-delocalization transitions between topological phases with the same boundary conductance, as well as gapless topological defects stabilized by average reflection symmetry.Comment: 8 pages, 5 figures, 1 table; improved section 4 "Extended topological classification" incl. example of stacked QSH layer