Influence of low-density polyethylene addition on coking pressure

Different amounts of low-density polyethylene (LDPE) were added to a bituminous coal used to produce metallurgical coke. The effect of the plastic waste on the carbonization process and more exactly, on the coking pressure were investigated. A movable wall oven at semi-pilot scale was used for measuring coking pressure generated. It was found that coking pressure increases for low LDPE addition levels (1-3 wt.%); however higher amounts of LDPE reduce coking pressure. To explain this behavior different blends of the coal and the residue were pyrolysed at three different temperatures (450, 500 and 600 C) in a Gray-King apparatus. The results show that LDPE causes a modification in the pyrolysis process and also influences the swelling process of the plastic stage. The increase of the coking pressure at low LDPE addition rates is associated with a less permeable coal plastic layer, which prevents the removal of the decomposition products and causes their retention in the semicoke matrix, evolving them in the post-plastic stage. Coking pressure decrease at high LDPE addition rates can be due to the charge shrinkage and the better permeability to the migration of oil components, which suggest a lower interaction between the coal and the LDPE. A delay in the degradation of LDPE is confirmed by the data provided by DRIFT and SEM

Relevance of the composition of municipal plastic wastes for metallurgical coke production

This study is concerned with the effects of the composition of mixed plastic wastes on the thermoplastic properties of coal, the generation of coking pressure and the quality of the resulting cokes in a movable wall oven at semipilot scale. The mixed plastic wastes were selected to cover a wide spectrum in the relative proportions of high- and low-density polyethylenes (HDPE and LDPE), polypropylene (PP), polystyrene (PS) and polyethylene terephthalate (PET). From the results it was deduced that the reduction in Gieseler fluidity in the coal blend is linked to the total amount of polyolefins in the waste. It was also found that these thermoplastics increase the pressure exerted against the wall in the course of the coking process and that coke quality is maintained or even improved. However, when the level of aromatic polymers such PS and PET are increased at the expense of polyolefins, the coking pressure decreases. Thus, the amount of aromatic polymers such as PS and PET in the waste is critical, not only for controlling Gieseler fluidity and coking pressure, but also for avoiding deterioration in coke quality (reactivity towards CO CRI and mechanical strength of the partially-gasified coke CSR). An amount of polyolefins in the waste lower than 65 wt.% for a secure coking pressure is established

Phase-locked magnetoconductance oscillations as a probe of Majorana edge states

We calculate the Andreev conductance of a superconducting ring interrupted by a flux-biased Josephson junction, searching for electrical signatures of circulating edge states. Two-dimensional pair potentials of spin-singlet d-wave and spin-triplet p-wave symmetry support, respectively, (chiral) Dirac modes and (chiral or helical) Majorana modes. These produce h/e-periodic magnetoconductance oscillations of amplitude \simeq (e^{2}/h)N^{-1/2}, measured via an N-mode point contact at the inner or outer perimeter of the grounded ring. For Dirac modes the oscillations in the two contacts are independent, while for an unpaired Majorana mode they are phase locked by a topological phase transition at the Josephson junction.Comment: 10 pages, 6 figures. New appendix on the gauge invariant discretization of the Bogoliubov-De Gennes equation. Accepted for publication in PR

Candida albicans pathogenicity mechanisms

Peer reviewedPublisher PD

Experimental measurements and diffusion in Harbor and coastal zones

Experimental results of turbulent flows in the sea surface near the coastline have been performed using both Lagrangian and Eulerian methods, field tests are presented using video recordings and velocity sensors. The spatial and temporal resolution is limited by the measuring instruments, which results in “filtering” out the very small scales. The experimental field-results obtained during the large-scale surf zone experiments carried out in the Ebro Delta, (Spain), under spilling/plunging breaking waves are compared with experiments performed at the Barcelona harbour. The field-measurements include several tests across the surf zone with high vertical resolution. The measured turbulent properties are compared with macroturbulence characteristics and length parameterisations. Diffusion is measured and related to the local velocity spectra so that a generalized Richardson law may be used

Pruritus is a common feature in sheep infected with the BSE agent.

BACKGROUND: The variability in the clinical or pathological presentation of transmissible spongiform encephalopathies (TSEs) in sheep, such as scrapie and bovine spongiform encephalopathy (BSE), has been attributed to prion protein genotype, strain, breed, clinical duration, dose, route and type of inoculum and the age at infection. The study aimed to describe the clinical signs in sheep infected with the BSE agent throughout its clinical course to determine whether the clinical signs were as variable as described for classical scrapie in sheep. The clinical signs were compared to BSE-negative sheep to assess if disease-specific clinical markers exist. RESULTS: Forty-seven (34%) of 139 sheep, which comprised 123 challenged sheep and 16 undosed controls, were positive for BSE. Affected sheep belonged to five different breeds and three different genotypes (ARQ/ARQ, VRQ/VRQ and AHQ/AHQ). None of the controls or BSE exposed sheep with ARR alleles were positive. Pruritus was present in 41 (87%) BSE positive sheep; the remaining six were judged to be pre-clinically infected. Testing of the response to scratching along the dorsum of a sheep proved to be a good indicator of clinical disease with a test sensitivity of 85% and specificity of 98% and usually coincided with weight loss. Clinical signs that were displayed significantly earlier in BSE positive cases compared to negative cases were behavioural changes, pruritic behaviour, a positive scratch test, alopecia, skin lesions, teeth grinding, tremor, ataxia, loss of weight and loss of body condition. The frequency and severity of each specific clinical sign usually increased with the progression of disease over a period of 16-20 weeks. CONCLUSION: Our results suggest that BSE in sheep presents with relatively uniform clinical signs, with pruritus of increased severity and abnormalities in behaviour or movement as the disease progressed. Based on the studied sheep, these clinical features appear to be independent of breed, affected genotype, dose, route of inoculation and whether BSE was passed into sheep from cattle or from other sheep, suggesting that the clinical phenotype of BSE is influenced by the TSE strain more than by other factors. The clinical phenotype of BSE in the genotypes and breed studied was indistinguishable from that described for classical scrapie cases

Dense conjugate initialization for deterministic PSO in applications: ORTHOinit+

This paper describes a class of novel initializations in Deterministic Particle Swarm Optimization (DPSO) for approximately solving costly unconstrained global optimization problems. The initializations are based on choosing specific dense initial positions and velocities for particles. These choices tend to induce in some sense orthogonality of particles’ trajectories, in the early iterations, in order to better explore the search space. Our proposal is inspired by both a theoretical analysis on a reformulation of PSO iteration, and by possible limits of the proposals reported in Campana et al. (2010); Campana et al. (2013). We explicitly show that, in comparison with other initializations from the literature, our initializations tend to scatter PSO particles, at least in the first iterations. The latter goal is obtained by imposing that the initial choice of particles’ position/velocity satisfies specific conjugacy conditions, with respect to a matrix depending on the parameters of PSO. In particular, by an appropriate condition on particles’ velocities, our initializations also resemble and partially extend a general paradigm in the literature of exact methods for derivative-free optimization. Moreover, we propose dense initializations for DPSO, so that the final approximate global solution obtained is possibly not too sparse, which might cause troubles in some applications. Numerical results, on both Portfolio Selection and Computational Fluid Dynamics problems, validate our theory and prove the effectiveness of our proposal, which applies also in case different neighborhood topologies are adopted in DPSO