Emission of Toxic HCN During NOx Removal by Ammonia SCR in the Exhaust of Lean-Burn Natural Gas Engines

Reducing greenhouse gas and pollutant emissions is one of the most stringent priorities of our society to minimize their dramatic effects on health and environment. Natural gas (NG) engines, in particular at lean conditions, emit less CO$_{2}$ in comparison to combustion engines operated with liquid fuels but NG engines still require emission control devices for NO$_{x}$ removal. Using state‐of‐the‐art technologies for selective catalytic reduction (SCR) of NO$_{x}$ with NH$_{3}$, we evaluated the interplay of the reducing agent NH$_{3}$ and formaldehyde, which is always present in the exhaust of NG engines. Our results show that a significant amount of highly toxic hydrogen cyanide (HCN) is formed. All catalysts tested partially convert formaldehyde to HCOOH and CO. Additionally, they form secondary emissions of HCN due to catalytic reactions of formaldehyde and its oxidation intermediates with NH$_{3}$. With the present components of the exhaust gas aftertreatment system the HCN emissions are not efficiently converted to non‐polluting gases. The development of more advanced catalyst formulations with improved oxidation activity is mandatory to solve this novel critical issue

Competition and Selection Among Conventions

In many domains, a latent competition among different conventions determines which one will come to dominate. One sees such effects in the success of community jargon, of competing frames in political rhetoric, or of terminology in technical contexts. These effects have become widespread in the online domain, where the data offers the potential to study competition among conventions at a fine-grained level. In analyzing the dynamics of conventions over time, however, even with detailed on-line data, one encounters two significant challenges. First, as conventions evolve, the underlying substance of their meaning tends to change as well; and such substantive changes confound investigations of social effects. Second, the selection of a convention takes place through the complex interactions of individuals within a community, and contention between the users of competing conventions plays a key role in the convention's evolution. Any analysis must take place in the presence of these two issues. In this work we study a setting in which we can cleanly track the competition among conventions. Our analysis is based on the spread of low-level authoring conventions in the eprint arXiv over 24 years: by tracking the spread of macros and other author-defined conventions, we are able to study conventions that vary even as the underlying meaning remains constant. We find that the interaction among co-authors over time plays a crucial role in the selection of them; the distinction between more and less experienced members of the community, and the distinction between conventions with visible versus invisible effects, are both central to the underlying processes. Through our analysis we make predictions at the population level about the ultimate success of different synonymous conventions over time--and at the individual level about the outcome of "fights" between people over convention choices.Comment: To appear in Proceedings of WWW 2017, data at https://github.com/CornellNLP/Macro

Proton acceleration by irradiation of isolated spheres with an intense laser pulse

We report on experiments irradiating isolated plastic spheres with a peak laser intensity of 2-3 x 10(20) W cm(-2). With a laser focal spot size of 10 mu m full width half maximum (FWHM) the sphere diameter was varied between 520 nm and 19.3 mu m. Maximum proton energies of similar to 25 MeV are achieved for targets matching the focal spot size of 10 mu m in diameter or being slightly smaller. For smaller spheres the kinetic energy distributions of protons become nonmonotonic, indicating a change in the accelerating mechanism from ambipolar expansion towards a regime dominated by effects caused by Coulomb repulsion of ions. The energy conversion efficiency from laser energy to proton kinetic energy is optimized when the target diameter matches the laser focal spot size with efficiencies reaching the percent level. The change of proton acceleration efficiency with target size can be attributed to the reduced cross-sectional overlap of subfocus targets with the laser. Reported experimental observations are in line with 3D3V particle in cell simulations. They make use of well-defined targets and point out pathways for future applications and experiments.DFG via the Cluster of Excellence Munich-Centre for Advanced Photonics (MAP) Transregio SFB TR18NNSA DE-NA0002008Super-MUC pr48meIvo CermakCGC Instruments in design and realization of the Paul trap systemIMPRS-APSLMUexcellent Junior Research FundDAAD|ToIFEEuropean Union's Horizon research and innovation programme 633053Physic

NH3_{3}-SCR over V-W/TiO2_{2} Investigated by Operando X-ray Absorption and Emission Spectroscopy

V–W/TiO$_{2}$-based catalysts, which are used for the removal of NO$_{x}$ from the exhaust of diesel engines and stationary sources via selective catalytic reduction with NH$_{3}$ (NH$_{3}$-SCR), were studied by operando X-ray absorption spectroscopy (XAS) and emerging photon-in/photon-out techniques. In order to minimize the influence of highly X-ray absorbing tungsten and the fluorescence of titanium, we used a high-energy-resolution fluorescence setup that is able to separate efficiently the V Kβ$_{1,3}$ emission lines and additionally allows to record valence-to-core (vtc) X-ray emission lines. High-energy resolution fluorescence-detected XAS (HERFD-XAS) and vtc X-ray emission spectroscopy (vtc-XES) proved to be the only way to perform an operando V K edge X-ray spectroscopic study on industrially relevant V–W/TiO$_{2}$ catalysts so far. The V–W/TiO$_{2}$ and V/TiO$_{2}$ samples synthesized by incipient wetness impregnation and grafting exhibited high activity toward NH$_{3}$-SCR. Raman spectroscopy showed that they mainly contained highly dispersed, isolated, and polymeric V-oxo species. HERFD-XAS and XES identified redox cycling of vanadium species between V$^{4+}$ and V$^{5+}$. With respect to most of the potential NH$_{3}$ adsorption complexes, density functional theory calculations further showed that vtc-XES is more limited than surface-sensitive techniques such as infrared spectroscopy; hence, a combination of X-ray techniques with IR or similar spectroscopies is required to unequivocally identify the mechanism of NH$_{3}$-SCR over vanadia-based catalysts

Observation of Parity Violation in the Omega-minus -> Lambda + K-minus Decay

The alpha decay parameter in the process Omega-minus -> Lambda + K-minus has been measured from a sample of 4.50 million unpolarized Omega-minus decays recorded by the HyperCP (E871) experiment at Fermilab and found to be [1.78 +/- 0.19(stat) +/- 0.16(syst)]{\times}10^{-2}. This is the first unambiguous evidence for a nonzero alpha decay parameter, and hence parity violation, in the Omega-minus -> Lambda + K-minus decay.Comment: 10 pages, 7 figure

Neutrino induced transitions between the ground states of the A=12 triad

Neutrino induced reactions on $^{12}$C, an ingredient of liquid scintillators, have been studied in several experiments. We show that for currently available neutrino energies, $E_{\nu} \le$ 300 MeV, calculated exclusive cross sections $^{12}$C$_{gs}(\nu,l)$$^{12}$N$_{gs}$ for both muon and electron neutrinos are essentially model independent, provided the calculations simultaneously describe the rates of several other reactions involving the same states or their isobar analogs. The calculations agree well with the measured cross sections, which can be therefore used to check the normalization of the incident neutrino spectrum and the efficiency of the detector.Comment: 9 pages REVTEX, 2 postscript figures, text and figures available at http://www.krl.caltech.edu/preprints/MAP.htm

Tricritical behavior of the frustrated XY antiferromagnet

Extensive histogram Monte-Carlo simulations of the XY antiferromagnet on a stacked triangular lattice reveal exponent estimates which strongly favor a scenario of mean-field tricritical behavior for the spin-order transition. The corresponding chiral-order transition occurs at the same temperature but appears to be decoupled from the spin-order. These results are relevant to a wide class of frustrated systems with planar-type order and serve to resolve a long-standing controversy regarding their criticality.Comment: J1K 2R1 4 pages (RevTex 3.0), 4 figures available upon request, Report# CRPS-94-0

de Haas-van Alphen Effect in the Two-Dimensional and the Quasi-Two-Dimensional Systems

We study the de Haas-van Alphen (dHvA) oscillation in two-dimensional and quasi-two-dimensional systems. We give a general formula of the dHvA oscillation in two-dimensional multi-band systems. By using this formula, the dHvA oscillation and its temperature-dependence for the two-band system are shown. By introducing the interlayer hopping $t_z$, we examine the crossover from the two-dimension, where the oscillation of the chemical potential plays an important role in the magnetization oscillation, to the three-dimension, where the oscillation of the chemical potential can be neglected as is well know as the Lifshitz and Kosevich formula. The crossover is seen at $4 t_z \sim 8 ta b H /\phi_0$, where a and b are lattice constants, $\phi_0$ is the flux quantum and 8t is the width of the total energy band. We also study the dHvA oscillation in quasi-two-dimensional magnetic breakdown systems. The quantum interference oscillations such as $\beta-\alpha$ oscillation as well as the fundamental oscillations are suppressed by the interlayer hopping $t_z$, while the $\beta+\alpha$ oscillation gradually increases as $t_z$ increases and it has a maximum at $t_z/t\approx 0.025$. This interesting dependence on the dimensionality can be observed in the quasi-two-dimensional organic conductors with uniaxial pressure.Comment: 11 pages, 14 figure

The critical behavior of frustrated spin models with noncollinear order

We study the critical behavior of frustrated spin models with noncollinear order, including stacked triangular antiferromagnets and helimagnets. For this purpose we compute the field-theoretic expansions at fixed dimension to six loops and determine their large-order behavior. For the physically relevant cases of two and three components, we show the existence of a new stable fixed point that corresponds to the conjectured chiral universality class. This contradicts previous three-loop field-theoretical results but is in agreement with experiments.Comment: 4 pages, RevTe