Antiferromagnetic interactions in single crystalline Zn1-xCoxO thin films

In a rather contradictory situation regarding magnetic data on Co-doped ZnO, we have succeeded in fabricating high-quality single crystalline Zn1-xCoxO (x=0.003-0.07) thin films. This gives us the possibility, for the first time, to examine the it intrinsic magnetic properties of ZnO:Co at a quantitative level and therefore to address several unsolved problems, the major one being the nature of the Co-Co interaction in the ZnO structure.Comment: 4 pages, 4 figures,accepted for publication in PR

The INTERNODES method for applications in contact mechanics and dedicated preconditioning techniques

The mortar finite element method is a well-established method for the numerical solution of partial differential equations on domains displaying non-conforming interfaces. The method is known for its application in computational contact mechanics. However, its implementation remains challenging as it relies on geometrical projections and unconventional quadrature rules. The INTERNODES (INTERpolation for NOn-conforming DEcompositionS) method, instead, could overcome the implementation difficulties thanks to flexible interpolation techniques. Moreover, it was shown to be at least as accurate as the mortar method making it a very promising alternative for solving problems in contact mechanics. Unfortunately, in such situations the method requires solving a sequence of ill-conditioned linear systems. In this paper, preconditioning techniques are designed and implemented for the efficient solution of those linear systems

Bleaching of sol-gel glass film with embedded gold nanoparticles by thermal poling

Gold clusters embedded in glass are expected to be hard to dissolve in the form of ions since gold is essentially a nonreactive metal. In spite of that, bleaching of Au-doped nanocomposite sol-gel glass film on a soda-lime glass substrate is demonstrated in which electric-field thermal poling is employed to effectively dissolve randomly distributed gold nanoparticles (15 nm in diameter) embedded in a low conductivity sol-gel glass film with a volume filling factor as small as 2.3%. The surface plasmon absorption band at 520 nm is suppressed in the region covered by the anodic electrode. The phenomenon is explained by the ionization of the gold nanoparticles and the redistribution of gold ions in the glass matrix due to the action of the extremely high electrostatic field locally developed during poling

Bioinspired coating for bird-safe glazing optimised for avian and human vision

Bird-window collisions often lead to the death of the bird and damage to the window. However, many animals, including birds, can perceive UV light. Many species have hence developed visual communication in this wavelength range, for instance, thanks to photonic structures. Such structures allowed us to design a new UV-reflecting multilayered coating for bird-safe glazing, through a bioinspiration approach. This coating was optimised for bird and human visual perception.</p

Magnetic Anisotropy of Co2+ as Signature of Intrinsic Ferromagnetism in ZnO:Co

We report on the magnetic properties of thoroughly characterized Zn1-xCoxO epitaxial thin films, with low Co concentration, x=0.003-0.005. Magnetic and EPR measurements, combined with crystal field theory, reveal that isolated Co2+ ions in ZnO possess a strong single ion anisotropy which leads to an "easy plane" ferromagnetic state when the ferromagnetic Co-Co interaction is considered. We suggest that the peculiarities of the magnetization process of this state can be viewed as a signature of intrinsic ferromagnetism in ZnO:Co materials.Comment: 4 pages, 4 figure

Bioinspired coating for bird-safe glazing optimised for avian and human vision

Bird-window collisions often lead to the death of the bird and damage to the window. However, many animals, including birds, can perceive UV light. Many species have hence developed visual communication in this wavelength range, for instance, thanks to photonic structures. Such structures allowed us to design a new UV-reflecting multilayered coating for bird-safe glazing, through a bioinspiration approach. This coating was optimised for bird and human visual perception.</p

Quasi-ordered photonic structures colour the bluespotted ribbontail ray

Due to the scarcity of blue colour exhibited by natural organisms, highlighting the underlying this colour mechanisms is always very impactful for the understanding of the natural world. In this research, the colour of the blue rounded spots occurring in the skin of Taeniura lymma stingray was unveiled by a combination of experimental and numerical techniques. Our results demonstrated that this blue colour arises from coherent scattering in quasi-ordered photonic structures occurring in the skin of this stingray.</p

Quasi-ordered photonic structures colour the bluespotted ribbontail ray

Due to the scarcity of blue colour exhibited by natural organisms, highlighting the underlying this colour mechanisms is always very impactful for the understanding of the natural world. In this research, the colour of the blue rounded spots occurring in the skin of Taeniura lymma stingray was unveiled by a combination of experimental and numerical techniques. Our results demonstrated that this blue colour arises from coherent scattering in quasi-ordered photonic structures occurring in the skin of this stingray.</p

Toward an experimental proof of superhydrophobicity enhanced by quantum fluctuations freezing on a broadband-absorber metamaterial

Previous theoretical works suggested that superhydrophobicity could be enhanced through partial inhibition of the quantum vacuum modes at the surface of a broadband-absorber metamaterial which acts in the extreme ultraviolet frequency domain. This effect would then compete with the classical Cassie-Baxter interpretation of superhydrophobicity. In this article, we first theoretically establish the expected phenomenological features related to such a kind of "quantum" superhydrophobicity. Then, relying on this theoretical framework, we experimentally study patterned silicon surfaces on which organosilane molecules were grafted, all the coated surfaces having similar characteristic pattern sizes but different profiles. Some of these surfaces can indeed freeze quantum photon modes while others cannot. While the latter ones allow hydrophobicity, only the former ones allow for superhydrophobicity. We believe these results lay the groundwork for further complete assessment of superhydrophobicity induced by quantum fluctuations freezing.Comment: 10 pages, 5 figures, final version, accepted for publication in Journal of Applied Physic