The treatment of mixing in core helium burning models - I. Implications for asteroseismology

The detection of mixed oscillation modes offers a unique insight into the internal structure of core helium burning (CHeB) stars. The stellar structure during CHeB is very uncertain because the growth of the convective core, and/or the development of a semiconvection zone, is critically dependent on the treatment of convective boundaries. In this study we calculate a suite of stellar structure models and their non-radial pulsations to investigate why the predicted asymptotic g-mode $\ell = 1$ period spacing $\Delta\Pi_1$ is systematically lower than is inferred from Kepler field stars. We find that only models with large convective cores, such as those calculated with our newly proposed "maximal-overshoot" scheme, can match the average $\Delta\Pi_1$ reported. However, we also find another possible solution that is related to the method used to determine $\Delta\Pi_1$: mode trapping can raise the observationally inferred $\Delta\Pi_1$ well above its true value. Even after accounting for these two proposed resolutions to the discrepancy in average $\Delta\Pi_1$, models still predict more CHeB stars with low $\Delta\Pi_1$ ($< 270$ s) than are observed. We establish two possible remedies for this: i) there may be a difficulty in determining $\Delta\Pi_1$ for early CHeB stars (when $\Delta\Pi_1$ is lowest) because of the effect that the sharp composition profile at the hydrogen burning shell has on the pulsations, or ii) the mass of the helium core at the flash is higher than predicted. Our conclusions highlight the need for the reporting of selection effects in asteroseismic population studies in order to safely use this information to constrain stellar evolution theory.Comment: 24 pages. 24 figures. Published in MNRA

Control Technology Needs for Electrified Aircraft Propulsion Systems

Electrified aircraft propulsion (EAP) systems hold potential for the reduction of aircraft fuel burn, emissions, and noise. Currently, NASA and other organizations are actively working to identify and mature technologies necessary to bring EAP designs to reality. This paper specifically focuses on the envisioned control technology challenges associated with EAP designs that include gas turbine technology. Topics discussed include analytical tools for the dynamic modeling and analysis of EAP systems, and control design strategies at the propulsion and component levels. This includes integrated supervisory control facilitating the coordinated operation of turbine and electrical components, control strategies that seek to minimize fuel consumption and lessen the challenges associated with thermal management, and dynamic control to ensure engine operability during system transients. These dynamic control strategies include innovative control approaches that either extract or supply power to engine shafts dependent upon operating phase, which may improve performance and reduced gas turbine engine weight. Finally, a discussion of control architecture design considerations to help alleviate the propulsion/aircraft integration and certification challenges associated with EAP systems is provided

First Asteroseismic Analysis of the Globular Cluster M80: Multiple Populations and Stellar Mass Loss

Asteroseismology provides a new avenue for accurately measuring the masses of evolved globular cluster (GC) stars through the detection of their solar-like oscillations. We present the first detections of solar-like oscillations in 47 red giant branch (RGB) and early asymptotic giant branch (EAGB) stars in the metal-poor GC M80; only the second ever with measured seismic masses. We investigate two major areas of stellar evolution and GC science; the multiple populations and stellar mass-loss. We detected a distinct bimodality in the EAGB mass distribution. We showed that this is likely due to sub-population membership. If confirmed, it would be the first direct measurement of a mass difference between sub-populations. A mass difference was not detected between the sub-populations in our RGB sample. We instead measured an average RGB mass of 0.782\pm0.009~\msun, which we interpret as the average between the sub-populations. Differing mass-loss rates on the RGB has been proposed as the second parameter that could explain the horizontal branch (HB) morphology variations between GCs. We calculated an integrated RGB mass-loss separately for each sub-population: 0.12\pm0.02~\msun (SP1) and 0.25\pm0.02~\msun (SP2). Thus, SP2 stars have greatly enhanced mass-loss on the RGB. Mass-loss is thought to scale with metallicity, which we confirm by comparing our results to a higher metallicity GC, M4. We also find that M80 stars have insignificant mass-loss on the HB. This is different to M4, suggesting that there is a metallicity and temperature dependence in the HB mass-loss. Finally, our study shows the robustness of the $\Delta\nu$-independent mass scaling relation in the low-metallicity (and low-surface gravity) regime.Comment: 20 pages, 11 figure

Bond activation in iron(II) and nickel(II) complexes of polypodal phosphanes

A pyridine-derived tetraphosphane ligand (donor set: NP4) has been found to undergo remarkably specific C-P bond cleavage reactions, thereby producing a ligand with an NP3 donor set. The reaction may be reversed under suitable conditions, with regeneration of the original NP4 ligand. In order to investigate the mechanism of this reaction, the NP3 donor ligand C5H3N[CMe(CH2PMe2)2][CMe2(CH2PMe2)] (11) was prepd., and its iron(II) complex 4 generated from Fe(BF4)2·6 H2O, with Me diethylphosphinite (7) as an addnl. monodentate ligand. Ligand 11 has, in addn. to the NP3 donor set, one Me group in close contact with the iron center, reminiscent of an agostic M···H-C interaction. Depending on the stoichiometric amt. of iron(II) salt, a side product 15 is formed, which has a diethylphosphane ligand instead of the phosphinite 7 coordinated to iron(II). While attempts to deprotonate the metal-coordinated Me group in 4 were unsuccessful, the reaction was shown to occur in an alternative complex (18), which is similar to 4 but has a trimethylphosphane ligand instead of the phosphinite 7. The reaction of complex 15 with CO gave two different products, which were both characterized by single-crystal X-ray diffraction. One (19) is the dicarbonyl iron(II) complex of the triphosphane ligand 11, the other (3) is the carbonyl iron(II) complex of the tetraphosphane C5H3N[CMe(CH2PMe2)2]2 (1). This suggests an intermol. mechanism for the C-P bond formation in question. [on SciFinder(R)

Role for polo-like kinase 4 in mediation of cytokinesis.

The mitotic protein polo-like kinase 4 (PLK4) plays a critical role in centrosome duplication for cell division. By using immunofluorescence, we confirm that PLK4 is localized to centrosomes. In addition, we find that phospho-PLK4 (pPLK4) is cleaved and distributed to kinetochores (metaphase and anaphase), spindle midzone/cleavage furrow (anaphase and telophase), and midbody (cytokinesis) during cell division in immortalized epithelial cells as well as breast, ovarian, and colorectal cancer cells. The distribution of pPLK4 midzone/cleavage furrow and midbody positions pPLK4 to play a functional role in cytokinesis. Indeed, we found that inhibition of PLK4 kinase activity with a small-molecule inhibitor, CFI-400945, prevents translocation to the spindle midzone/cleavage furrow and prevents cellular abscission, leading to the generation of cells with polyploidy, increased numbers of duplicated centrosomes, and vulnerability to anaphase or mitotic catastrophe. The regulatory role of PLK4 in cytokinesis makes it a potential target for therapeutic intervention in appropriately selected cancers

Experimental and Theoretical Investigation of Molecular Field Effects by Polarization-resolved Resonant Inelastic X-ray Scattering

We present a combined theoretical and experimental study of molecular field effects on molecular core levels. Polarization-dependent resonant inelastic x-ray scattering is observed experimentally after resonant K-shell excitation of CF3Cl and HCl. We explain the linear dichroism observed in spin-orbit level intensities as due to molecular field effects, including singlet-triplet exchange, and interpret this behavior in terms of population differences in the 2px,y,z inner-shell orbitals. We investigate theoretically the different factors that can affect the electronic populations and the dynamical R dependence of the spin-orbit ratio. Finally, the results obtained are used to interpret the L-shell absorption spectra of the two molecules

Effect of Arm Movement and Task Difficulty on Balance Performance in Children, Adolescents, and Young Adults

BACKGROUND: Studies have shown that restricted compared to free arm movement negatively affects balance performance during balance assessment and this is reinforced when the level of task difficulty (e.g., varying stance/walk conditions, sensory manipulations) is increased. However, it remains unclear whether these findings apply to individuals with differences in the development of the postural control system. Thus, we examined the influence of arm movement and task difficulty on balance performance in children, adolescents, and young adults. METHODS: Static, dynamic, and proactive balance performance were assessed in 40 children (11.5 ± 0.6 years), 30 adolescents (14.0 ± 1.1 years), and 41 young adults (24.7 ± 3.0 years) using the same standardized balance tests [i.e., one-legged stance (OLS) time with eyes opened/closed and/or on firm/foam ground, 3-m beam (width: 6, 4.5, or 3 cm) walking backward step number, Lower Quarter Y-Balance test (YBT-LQ) reach distance] with various difficulty levels under free vs. restricted arm movement conditions. RESULTS: In all but one test, balance performance was significantly better during free compared to restricted arm movement. Arm by age interactions were only observed for the YBT-LQ and post hoc analyses revealed significantly greater performance differences between free and restricted arm movement, especially, in young adults. Arm by age by task difficulty interactions were found for the OLS and the 3-m beam walking backward test. Post hoc analyses showed significantly greater performance differences between free and restricted arm movement during high vs. low levels of task difficulty and this was more pronounced in children and adolescents. CONCLUSIONS: Regardless of age, static, dynamic, and proactive balance performance benefited from arm movements and this was especially noted for youth performing difficult balance tasks

Linear Dichroism in Resonant Inelastic X-Ray Scattering to Molecular Spin-Orbit States

Polarization-dependent resonant inelastic x-ray scattering (RIXS) is shown to be a new probe of molecular-field effects on the electronic structure of isolated molecules. A combined experimental and theoretical analysis explains the linear dichroism observed in Cl 2p RIXS following Cl 1s excitation in HCl and CF3Cl as due to molecular-field effects, including singlet-triplet exchange, indicating polarized-RIXS provides a direct probe of spin-orbit-state populations applicable to any molecule

Angular and Dynamical Properties in Resonant Inelastic X-ray Scattering: Case Study of Chlorine-containing Molecules

Polarization-dependent resonant inelastic x-ray scattering (RIXS) has been shown to be a probe of molecular-field effects on the electronic structure of isolated molecules. In this experimental analysis we explain the linear dichroism observed in Cl 2p polarized RIXS following Cl 1s excitation of a series of chlorofluoromethanes (CF3Cl, CF2Cl2, CFCl3, and CCl4) as due to molecular-field effects, including singlet-triplet exchange. We present an approach to extract directly the 2p inner-shell electronic state populations from the experimental measurements. Using the angular properties of the measured KV emission we also are able to determine the value of the polarization anisotropy parameter βp for each resolved component of the KV emission spectra