197 research outputs found

    Aggregation enhanced emission (AEE) in organic salt: A structure-property correlation based on single crystal studies

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    Salt formation has been shown as a simple strategy to induce aggregated induced emission or aggregated enhanced emission in primary ammonium salts derived from 9-anthracene carboxylic acid, 1-pyrene carboxylic acid, 3-coumarin carboxylic acid and histamine. All the salts displayed enhanced fluorescence in their solid state compared to that in their solution state. Single crystal structure of the salt of 9-anthracene carboxylic acid i.e., His-anthracene revealed that restricted intramolecular rotation of the fluorphoric moiety (anthracene) was responsible for such radiative pathway leading to enhanced emission

    Shock Wave Mixing in Einstein and Dilaton Gravity

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    We consider possible mixing of electromagnetic and gravitational shock waves, in the Planckian energy scattering of point particles in Minkowski space. By boosting a Reissner-Nordstr\"om black hole solution to the velocity of light, it is shown that no mixing of shock waves takes place for arbitrary finite charge carried by the black hole. However, a similar boosting procedure for a charged black hole solution in dilaton gravity yields some mixing : the wave function of even a neutral test particle, acquires a small additional phase factor depending on the dilatonic black hole charge. Possible implications for poles in the amplitudes for the dilaton gravity case are discussed.Comment: 11 pages, revtex file, no figure

    Quantum Black Hole Entropy

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    We derive an exact formula for the dimensionality of the Hilbert space of the boundary states of SU(2) Chern-Simons theory, which, according to the recent work of Ashtekar et al, leads to the Bekenstein-Hawking entropy of a four dimensional Schwarzschild black hole. Our result stems from the relation between the (boundary) Hilbert space of the Chern-Simons theory with the space of conformal blocks of the Wess-Zumino model on the boundary 2-sphere.Comment: 7 pages, Revtex, some new references adde

    Synthesis of 13C-labelled, bicyclic mimetics of natural enediynes

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    Using a versatile synthesis with 13CH3PPh3I and CH313CO2Et as 13C sources, the first examples of nine membered chromophores, which have been differentially labelled with 13C in their carbocyclic enediyne cores, are described

    Aspects of Planckian scattering beyond the eikonal

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    Sherpa Romeo green journal. Permission to archive final published version.We discuss an approach to compute two-particle scattering amplitudes for spinless light particles colliding at Planckian centre-of-mass energies, with increasing momentum transfer away from the eikonal limit. The leading corrections to the eikonal amplitude, in our 'external metric' approach, are shown to be vanishingly small in the limit of the source particle mass going to zero. For massless charged particles, the electromagnetic and gravitational interactions decouple in the eikonal limit, hut mix non-trivially for the leading order corrections.Ye

    Electromagnetic charge-monopole versus gravitational scattering at Planckian energies

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    Sherpa Romeo green journal. Permission to archive final published version.The amplitude for the scattering of a point magnetic monopole and a point charge, at center-of- mass energies much larger than the masses of the particles, and in the limit of low momentum transfer, is shown to be proportional to the (integer-valued) monopole strength, assuming the Dirac quantization condition for the monopole-charge system. It is demonstrated that, for small momentum transfer, charge-monopole electromagnetic effects remain comparable to those due to the gravitational interaction between the particles even at Planckian center-of-mass energies.Ye

    Cosmic optical activity from an inhomogeneous Kalb-Ramond field

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    The effects of introducing a harmonic spatial inhomogeneity into the Kalb-Ramond field, interacting with the Maxwell field according to a `string-inspired' proposal made in earlier work are investigated. We examine in particular the effects on the polarization of synchrotron radiation from cosmologically distant (i.e. of redshift greater than 2) galaxies, as well as the relation between the electric and magnetic components of the radiation field. The rotation of the polarization plane of linearly polarized radiation is seen to acquire an additional contribution proportional to the square of the frequency of the dual Kalb-Ramond axion wave, assuming that it is far smaller compared to the frequency of the radiation field.Comment: 9 pages, Revtex, no figure
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