88 research outputs found
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Surface-to-Bulk Redox Coupling through Thermally Driven Li Redistribution in Li- and Mn-Rich Layered Cathode Materials.
Li- and Mn-rich (LMR) layered cathode materials have demonstrated impressive capacity and specific energy density thanks to their intertwined redox centers including transition metal cations and oxygen anions. Although tremendous efforts have been devoted to the investigation of the electrochemically driven redox evolution in LMR cathode at ambient temperature, their behavior under a mildly elevated temperature (up to ∼100 °C), with or without electrochemical driving force, remains largely unexplored. Here we show a systematic study of the thermally driven surface-to-bulk redox coupling effect in charged Li1.2Ni0.15Co0.1Mn0.55O2. We for the first time observed a charge transfer between the bulk oxygen anions and the surface transition metal cations under ∼100 °C, which is attributed to the thermally driven redistribution of Li ions. This finding highlights the nonequilibrium state and dynamic nature of the LMR material at deeply delithiated state upon a mild temperature perturbation
Testing general relativity with accretion onto compact objects
The X-ray emission of neutron stars and black holes presents a rich
phenomenology that can lead us to a better understanding of their nature and to
address more general physics questions: Does general relativity apply in the
strong gravity regime? Is spacetime around black holes described by the Kerr
metric? This white paper considers how we can investigate these questions by
studying reverberation mapping and quasi-periodic oscillations in accreting
systems with a combination of high-spectral and high-timing resolution. In the
near future, we will be able to study compact objects in the X-rays in a new
way: advancements in transition-edge sensors (TES) technology will allow for
electron-volt-resolution spectroscopy combined with nanoseconds-precision
timing.Comment: White paper submitted for Astro2020 Decadal Survey. 8 pages, 2
figure
L-Edge Spectroscopy of Dilute, Radiation-Sensitive Systems Using a Transition-Edge-Sensor Array
We present X-ray absorption spectroscopy and resonant inelastic X-ray
scattering (RIXS) measurements on the iron L-edge of 0.5 mM aqueous
ferricyanide. These measurements demonstrate the ability of high-throughput
transition-edge-sensor (TES) spectrometers to access the rich soft X-ray
(100-2000eV) spectroscopy regime for dilute and radiation-sensitive samples.
Our low-concentration data are in agreement with high-concentration
measurements recorded by conventional grating-based spectrometers. These
results show that soft X-ray RIXS spectroscopy acquired by high-throughput TES
spectrometers can be used to study the local electronic structure of dilute
metal-centered complexes relevant to biology, chemistry and catalysis. In
particular, TES spectrometers have a unique ability to characterize frozen
solutions of radiation- and temperature-sensitive samples.Comment: 19 pages, 4 figure
The Atacama Cosmology Telescope: Dusty Star-Forming Galaxies and Active Galactic Nuclei in the Southern Survey
We present a catalog of 191 extragalactic sources detected by the Atacama
Cosmology Telescope (ACT) at 148 GHz and/or 218 GHz in the 2008 Southern
survey. Flux densities span 14-1700 mJy, and we use source spectral indices
derived using ACT-only data to divide our sources into two sub-populations: 167
radio galaxies powered by central active galactic nuclei (AGN), and 24 dusty
star-forming galaxies (DSFGs). We cross-identify 97% of our sources (166 of the
AGN and 19 of the DSFGs) with those in currently available catalogs. When
combined with flux densities from the Australian Telescope 20 GHz survey and
follow-up observations with the Australia Telescope Compact Array, the
synchrotron-dominated population is seen to exhibit a steepening of the slope
of the spectral energy distribution from 20 to 148 GHz, with the trend
continuing to 218 GHz. The ACT dust-dominated source population has a median
spectral index of 3.7+0.62-0.86, and includes both local galaxies and sources
with redshifts as great as 5.6. Dusty sources with no counterpart in existing
catalogs likely belong to a recently discovered subpopulation of DSFGs lensed
by foreground galaxies or galaxy groups.Comment: 13 pages, 8 figures, 4 table
The Atacama Cosmology Telescope: The LABOCA/ACT Survey of Clusters at All Redshifts
We present a multi-wavelength analysis of eleven Sunyaev Zel'dovich effect
(SZE)-selected galaxy clusters (ten with new data) from the Atacama Cosmology
Telescope (ACT) southern survey. We have obtained new imaging from the Large
APEX Bolometer Camera (345GHz; LABOCA) on the Atacama Pathfinder EXperiment
(APEX) telescope, the Australia Telescope Compact Array (2.1GHz; ATCA), and the
Spectral and Photometric Imaging Receiver (250, 350, and ;
SPIRE) on the Herschel Space Observatory. Spatially-resolved 345GHz SZE
increments with integrated S/N > 5 are found in six clusters. We compute 2.1GHz
number counts as a function of cluster-centric radius and find significant
enhancements in the counts of bright sources at projected radii . By extrapolating in frequency, we predict that the combined
signals from 2.1GHz-selected radio sources and 345GHz-selected SMGs contaminate
the 148GHz SZE decrement signal by ~5% and the 345GHz SZE increment by ~18%.
After removing radio source and SMG emission from the SZE signals, we use ACT,
LABOCA, and (in some cases) new Herschel SPIRE imaging to place constraints on
the clusters' peculiar velocities. The sample's average peculiar velocity
relative to the cosmic microwave background is .Comment: 19 pages, 11 figures, Accepted for Publication in The Astrophysical
Journa
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