Late Quaternary sea-level history of Saipan, Commonwealth of the Northern Mariana Islands, USA: A test of tectonic uplift and glacial isostatic adjustment models

In 1979, S. Uyeda and H. Kanamori proposed a tectonic model with two end members of a subduction-boundary continuum: the “Chilean” type (shallow dip of the subducting plate, great thrust events, compression, and uplift of the overriding plate) and a “Mariana” type (steep dip of the subducting plate, no great thrust events, tension, and no uplift). This concept has been used to explain variable rates of Quaternary uplift around the Pacific Rim, yet no uplift rates have been determined for the Mariana Islands themselves, one of the end members in this model. We studied the late Quaternary Tanapag Limestone, which rims much of the eastern and southern coasts of Saipan, Northern Mariana Islands, with elevations of ∼13 m to ∼30 m. Samples from 12 well-preserved corals (Acropora, Porites, and Goniastrea) yielded U-series ages ranging from ca. 134 ka to ca. 126 ka. These ages correlate the emergent reef of the Tanapag Limestone with the last interglacial period, when sea level was several meters above present. Ages and measured reef elevations from the Tanapag Limestone, along with paleo–sea-level data, yield relatively low late Quaternary uplift rates of 0.002–0.19 m/k.y., consistent with the Uyeda-Kanamori model. A review of data from other localities near subduction zones around the Pacific Basin, however, indicates that many coastlines do not fit the model. Uplift rates along the Chilean coast are predicted to be relatively high, but field studies indicate they are low. On some coastlines, relatively high uplift rates are better explained by subduction of seamounts or submarine ridges rather than subduction zone geometry. Despite the low long-term uplift rate on Saipan, the island also hosts an emergent, low-elevation (+3.9–4.0 m) reef with corals in growth position below a notch (+4.2 m). The corals are dated to 3.9–3.1 ka. The occurrence of this young, emergent reef is likely not due to tectonic uplift; instead, it is interpreted to be the result of glacial isostatic adjustment processes after the end of the last glacial period. Our findings are consistent with similar observations on tectonically stable or slowly uplifting islands elsewhere in the equatorial Pacific Ocean and agree with numerical models of a higher-than-present Holocene sea level in this region due to glacial isostatic adjustment processes

Uranium-series ages of fossil corals from Mallorca, Spain: The “Neotyrrhenian” high stand of the Mediterranean Sea revisited

The emergent marine deposits of the Mediterranean basin have been recognized as an important record of Quaternary sea level history for more than a century. Previous workers identified what have been interpreted to be two separate high stands of sea in the late Quaternary, namely the “Eutyrrhenian” (thought to be ~120 ka) and the “Neotyrrhenian” (thought to be either ~100 ka or ~80 ka). On Mallorca, Spain, both of these named deposits lie close to present sea level, implying paleo-sea levels slightly above present during both marine isotope stages (MIS) 5.5/5e and either 5.3/5c or 5.1/5a. If these interpretations are correct, they conflict, at least in part, with sea level records from far-field localities. Weanalyzed corals fromtheNeotyrrhenian beds onMallorca,which gave U-series ages from~126 ka to ~118 ka. These ages are consistent with previously published amino acid data that show that the Neotyrrhenian and Eutyrrhenian deposits are not significantly different in age. A fossil molluscan fauna from the Neotyrrhenian deposits onMallorca has a warm-water paleozoogeographic aspect, with nine southward-ranging species and four extralimital southern species. When compared with sea surface temperatures obtained from planktonic foraminifera and alkenones from ODP core 977 in the nearby Alboran Sea, the only time period that shows comparable warmth is MIS 5.5/5e, consistent with the U-series ages of corals from the Neotyrrhenian deposits. We propose that the Neotyrrhenian deposits are a beachrock facies of the same age as the Eutyrrhenian deposits. This interpretation is consistent with the differences in physical sedimentology of the two deposits, explains the U-series and amino acid data indicating the same age, is consistent with the very slight elevation difference of the Neotyrrhenian and Eutyrrhenian beds, and explains the similar, though not identical paleozoogeographic aspects of their fossil faunas

Uranium-series ages of fossil corals from Mallorca, Spain: The “Neotyrrhenian” high stand of the Mediterranean Sea revisited

The emergent marine deposits of the Mediterranean basin have been recognized as an important record of Quaternary sea level history for more than a century. Previous workers identified what have been interpreted to be two separate high stands of sea in the late Quaternary, namely the “Eutyrrhenian” (thought to be ~120 ka) and the “Neotyrrhenian” (thought to be either ~100 ka or ~80 ka). On Mallorca, Spain, both of these named deposits lie close to present sea level, implying paleo-sea levels slightly above present during both marine isotope stages (MIS) 5.5/5e and either 5.3/5c or 5.1/5a. If these interpretations are correct, they conflict, at least in part, with sea level records from far-field localities. Weanalyzed corals fromtheNeotyrrhenian beds onMallorca,which gave U-series ages from~126 ka to ~118 ka. These ages are consistent with previously published amino acid data that show that the Neotyrrhenian and Eutyrrhenian deposits are not significantly different in age. A fossil molluscan fauna from the Neotyrrhenian deposits onMallorca has a warm-water paleozoogeographic aspect, with nine southward-ranging species and four extralimital southern species. When compared with sea surface temperatures obtained from planktonic foraminifera and alkenones from ODP core 977 in the nearby Alboran Sea, the only time period that shows comparable warmth is MIS 5.5/5e, consistent with the U-series ages of corals from the Neotyrrhenian deposits. We propose that the Neotyrrhenian deposits are a beachrock facies of the same age as the Eutyrrhenian deposits. This interpretation is consistent with the differences in physical sedimentology of the two deposits, explains the U-series and amino acid data indicating the same age, is consistent with the very slight elevation difference of the Neotyrrhenian and Eutyrrhenian beds, and explains the similar, though not identical paleozoogeographic aspects of their fossil faunas

Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation

Despite rapid advances in the field of metal-free, “frustrated Lewis pair” (FLP)-catalyzed hydrogenation, the need for strictly anhydrous reaction conditions has hampered wide-scale uptake of this methodology. Herein, we report that, despite the generally perceived moisture sensitivity of FLPs, 1,4-dioxane solutions of B(C6F5)3 actually show appreciable moisture tolerance and can catalyze hydrogenation of a range of weakly basic substrates without the need for rigorously inert conditions. In particular, reactions can be performed directly in commercially available nonanhydrous solvents without subsequent drying or use of internal desiccants

A Practical Guide to Operator/ Surface-Owner Disputes and the Current State of the Accommodation Doctrine

This Article provides an overview of the operator\u27s rights and a practical guide to the procedures available to enforce them. Of particular emphasis, this Article will discuss how an operator can use injunctive relief to prevent surface-owner interference, and will specifically provide a checklist of sorts for how an operator can obtain a temporary restraining order. This Article will also address how the operator\u27s rights can be limited by the accommodation doctrine. In this regard, this Article will examine how the accommodation doctrine is triggered, what the surface owner must prove when asserting the accommodation doctrine, and whether the accommodation doctrine provides a mechanism for the surface owner to recover damages from the operator for unreasonable surface use

Sea-level history of past interglacial periods from uranium-series dating of corals, Curaçao, Leeward Antilles islands

Curaçao has reef terraces with the potential to provide sea-level histories of interglacial periods. Ages of the Hato (upper) unit of the “Lower Terrace” indicate that this reef dates to the last interglacial period, Marine Isotope Stage (MIS) 5.5. On Curaçao, this high sea stand lasted at least 8000 yr (~126 to ~118 ka). Elevations and age of this reef show that late Quaternary uplift rates on Curaçao are low, 0.026–0.054 m/ka, consistent with its tectonic setting. Ages of ~200 ka for corals from the older Cortalein unit of the Lower Terrace correlate this reef to MIS 7, with paleo-sea level estimates ranging from −3.3 m to +2.3 m. The estimates are in agreement with those for MIS 7 made fromother localities and indicate that the penultimate interglacial period was a time of significantwarmth, on a parwith the present interglacial period. The ~400 ka (MIS 11) Middle Terrace I on Curaçao, dated by others, may have formed froma paleo-sea level of+8.3 to+10.0 m, or (less likely)+17 mto+20 m. The lower estimates are conservative compared to previous studies, but still require major ice sheet loss from Greenland and Antarctica

Sr-Isotope Record of Quaternary Marine Terraces on the California Coast and off Hawaii

Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine 87Sr/86Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (\u3e0.02‰), rapid (\u3c100,000 yr) excursions in 87Sr/86Sr were resolved nor did we observe any samples with 87Sr/86Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in 87Sr/86Sr which, when compared to the trend of Quaternary marine 87Sr/86Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine 87Sr/86Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications i

Late Quaternary uplift along the North America-Caribbean plate boundary: Evidence from the sea level record of Guantanamo Bay, Cuba

The tectonic setting of the North America-Caribbean plate boundary has been studied intensively, but some aspects are still poorly understood, particularly along the Oriente fault zone. Guantanamo Bay, southern Cuba, is considered to be on a coastline that is under a transpressive tectonic regime along this zone, and is hypothesized to have a low uplift rate. We tested this by studying emergent reef terrace deposits around the bay. Reef elevations in the protected, inner part of the bay are ~11e12 m and outercoast, wave-cut benches are as high as ~14 m. Uranium-series analyses of corals yield ages ranging from ~133 ka to ~119 ka, correlating this reef to the peak of the last interglacial period, marine isotope stage (MIS) 5.5. Assuming a span of possible paleo-sea levels at the time of the last interglacial period yields long-term tectonic uplift rates of 0.02e0.11 m/ka, supporting the hypothesis that the tectonic uplift rate is low. Nevertheless, on the eastern and southern coasts of Cuba, east and west of Guantanamo Bay, there are flights of multiple marine terraces, at higher elevations, that could record a higher rate of uplift, implying that Guantanamo Bay may be anomalous. Southern Cuba is considered to have experienced a measurable but modest effect from glacial isostatic adjustment (GIA) processes. Thus, with a low uplift rate, Guantanamo Bay should show no evidence of emergent marine terraces dating to the ~100 ka (MIS 5.3) or ~80 ka (MIS 5.1) sea stands and results of the present study support this

Quaternary sea-level history of the United States

In the past 30 years, there have been tremendous advances in our understanding of Quaternary sea-level history, due directly to developments in Quaternary dating methods, particularly uranium-series disequilibrium and amino acid racemization. Another reason for this progress is that coastline history can now be tied to the oxygen-isotope record of foraminifera in deep-sea cores. Furthermore, both records have been linked to climate change on the scale of glacial-interglacial cycles that are thought to be forced by changes in Earth-Sun geometry, or “orbital forcing” (Milankovitch, 1941)

Late Quaternary uplift along the North America-Caribbean plate boundary: Evidence from the sea level record of Guantanamo Bay, Cuba

The tectonic setting of the North America-Caribbean plate boundary has been studied intensively, but some aspects are still poorly understood, particularly along the Oriente fault zone. Guantanamo Bay, southern Cuba, is considered to be on a coastline that is under a transpressive tectonic regime along this zone, and is hypothesized to have a low uplift rate. We tested this by studying emergent reef terrace deposits around the bay. Reef elevations in the protected, inner part of the bay are ~11e12 m and outercoast, wave-cut benches are as high as ~14 m. Uranium-series analyses of corals yield ages ranging from ~133 ka to ~119 ka, correlating this reef to the peak of the last interglacial period, marine isotope stage (MIS) 5.5. Assuming a span of possible paleo-sea levels at the time of the last interglacial period yields long-term tectonic uplift rates of 0.02e0.11 m/ka, supporting the hypothesis that the tectonic uplift rate is low. Nevertheless, on the eastern and southern coasts of Cuba, east and west of Guantanamo Bay, there are flights of multiple marine terraces, at higher elevations, that could record a higher rate of uplift, implying that Guantanamo Bay may be anomalous. Southern Cuba is considered to have experienced a measurable but modest effect from glacial isostatic adjustment (GIA) processes. Thus, with a low uplift rate, Guantanamo Bay should show no evidence of emergent marine terraces dating to the ~100 ka (MIS 5.3) or ~80 ka (MIS 5.1) sea stands and results of the present study support this