Experimental tests of reaction rate theory: Mu+H2 and Mu+D2

Copyright @ 1987 American Institute of Physics.Bimolecular rate constants for the thermal chemical reactions of muonium (Mu) with hydrogen and deuterium—Mu+H2→MuH+H and Mu+D2→MuD+D—over the temperature range 473–843 K are reported. The Arrhenius parameters and 1σ uncertainties for the H2 reaction are log A (cm3 molecule-1 s-1)=-9.605±0.074 and Ea =13.29±0.22 kcal mol-1, while for D2 the values are -9.67±0.12 and 14.73±0.40, respectively. These results are significantly more precise than those reported earlier by Garner et al. For the Mu reaction with H2 our results are in excellent agreement with the 3D quantum mechanical calculations of Schatz on the Liu–Siegbahn–Truhlar–Horowitz potential surface, but the data for both reactions compare less favorably with variational transition-state theory, particularly at the lower temperatures.NSERC (Canada) and the Petroleum Research Foundation of the Americal Chemical Society

Reaction kinetics of muonium with the halogen gases (F2, Cl2, and Br2)

Copyright @ 1989 American Institute of PhysicsBimolecular rate constants for the thermal chemical reactions of muonium (Mu) with the halogen gases—Mu+X2→MuX+X—are reported over the temperature ranges from 500 down to 100, 160, and 200 K for X2=F2,Cl2, and Br2, respectively. The Arrhenius plots for both the chlorine and fluorine reactions show positive activation energies Ea over the whole temperature ranges studied, but which decrease to near zero at low temperature, indicative of the dominant role played by quantum tunneling of the ultralight muonium atom. In the case of Mu+F2, the bimolecular rate constant k(T) is essentially independent of temperature below 150 K, likely the first observation of Wigner threshold tunneling in gas phase (H atom) kinetics. A similar trend is seen in the Mu+Cl2 reaction. The Br2 data exhibit an apparent negative activation energy [Ea=(−0.095±0.020) kcal mol−1], constant over the temperature range of ∼200–400 K, but which decreases at higher temperatures, indicative of a highly attractive potential energy surface. This result is consistent with the energy dependence in the reactive cross section found some years ago in the atomic beam data of Hepburn et al. [J. Chem. Phys. 69, 4311 (1978)]. In comparing the present Mu data with the corresponding H atom kinetic data, it is found that Mu invariably reacts considerably faster than H at all temperatures, but particularly so at low temperatures in the cases of F2 and Cl2. The current transition state calculations of Steckler, Garrett, and Truhlar [Hyperfine Interact. 32, 779 (986)] for Mu+X2 account reasonably well for the rate constants for F2 and Cl2 near room temperature, but their calculated value for Mu+Br2 is much too high. Moreover, these calculations seemingly fail to account for the trend in the Mu+F2 and Mu+Cl2 data toward pronounced quantum tunneling at low temperatures. It is noted that the Mu kinetics provide a crucial test of the accuracy of transition state treatments of tunneling on these early barrier HX2 potential energy surfaces.NSERC (Canada), Donors of the Petroleum Research Fund, administered by the American Chemical Society, for their partial support of this research and the Canada Council

Gamma ray constraints on the Galactic supernova rate

We perform Monte Carlo simulations of the expected gamma ray signatures of Galactic supernovae of all types to estimate the significance of the lack of a gamma ray signal due to supernovae occurring during the last millenium. Using recent estimates of the nuclear yields, we determine mean Galactic supernova rates consistent with the historic supernova record and the gamma ray limits. Another objective of these calculations of Galactic supernova histories is their application to surveys of diffuse Galactic gamma ray line emission

A GBT Survey for HI 21 cm Absorption in the Disks and Halos of Low-Redshift Galaxies

We present an HI 21 cm absorption survey with the Green Bank Telescope (GBT) of galaxy-quasar pairs selected by combining data from the Sloan Digital Sky Survey (SDSS) and the Faint Images of the Radio Sky at Twenty-Centimeters (FIRST) survey. Our sample consists of 23 sightlines through 15 low-redshift foreground galaxy - background quasar pairs with impact parameters ranging from 1.7 kpc up to 86.7 kpc. We detected one absorber in the GBT survey from the foreground dwarf galaxy, GQ1042+0747, at an impact parameter of 1.7 kpc and another possible absorber in our follow-up Very Large Array (VLA) imaging of the nearby foreground galaxy, UGC 7408. Both of the absorbers are narrow (FWHM of 3.6 and 4.8 km/s), have sub Damped Lyman alpha column densities, and most likely originate in the disk gas of the foreground galaxies. We also detected H I emission from three foreground galaxies, including UGC 7408. Although our sample contains both blue and red galaxies, the two H I absorbers as well as the H I emissions are associated with blue galaxies. We discuss the physical conditions in the 21 cm absorbers and some drawbacks of the large GBT beam for this type of survey.Comment: 15 pages, 6 figures, 3 table

Statistical Inference, Distinguishability of Quantum States, And Quantum Entanglement

We argue from the point of view of statistical inference that the quantum relative entropy is a good measure for distinguishing between two quantum states (or two classes of quantum states) described by density matrices. We extend this notion to describe the amount of entanglement between two quantum systems from a statistical point of view. Our measure is independent of the number of entangled systems and their dimensionality.Comment: 11 pages no figures, to appear in Phys. Rev.

Photochemical production and loss rates of ozone at Sable Island, Nova Scotia during the North Atlantic Regional Experiment (NARE) 1993 summer intensive

Three weeks of summertime surface‐based chemical and meteorological observations at Sable Island, Nova Scotia during the North Atlantic Regional Experiment (NARE) 1993 summer intensive are used to study instantaneous photochemical production and loss rates of ozone by means of a numerical photochemical model. Results are most sensitive to the averaging scheme of data used to constrain the model and the ambient variability of the measurements. Model simulations driven by a time series of 5 min averaged data, most representative of the chemistry at the site, yield an average net photochemical ozone production of 3.6 ppbv/d. Estimates of net ozone production designed to filter out local sources, by using 1000–1400 LT median values of observations to drive the model and by excluding short‐lived hydrocarbons, give values ranging from 1 to 4 ppbv/d. These positive values of net ozone production within the marine boundary layer over Sable Island demonstrate the impact of polluted continental plumes on the background photochemistry of the region during the intensive. The dominant ambient variables controlling photochemical production and loss rates of ozone at the site during the measurement campaign appear to be levels of nitrogen oxides, ozone, nonmethane hydrocarbons, and solar intensity determined by cloud cover. The model partitioning of nitrogen oxides agrees for the most part with measurements, lending credence to calculated photochemical production and loss rates of ozone as well as inferred levels of peroxy radicals not measured at the site. Discrepancies, however, often occur during episodes of intermittent cloud cover, fog, and rain, suggesting the influence of cloud processes on air masses reaching the site

Spray timing to control Botrytis fruit rot and tarnished plant bug in day-neutral strawberries, 1991I

The trial was held at the Iowa State University Horticulture Farm in 1991. Day-neutral strawberries planted in May 1991 on sand loam (fine, loamy, mixed mesic, Typic Halpudoll) soil were arranged in a randomized complete block design with five replications and 3 treatments. Each block was a 100-ft-long double row of plants with 12-in. spacing between plants, and treatment subplots within blocks were 20-ft segments of the double row. Data were taken only from the center 15 ft of each subplot. Timing of fungicide sprays for Botrytis fruit rot in the model-driven treatment was based on a leaf wetness-temperature model proposed by M. Ellis (pers. comm., Department of Plant Pathology, OARDC, Wooster, Ohio and Bulger et al, Phytopathology 77:1225-1230). Timing of insecticide sprays for tarnished plant bug in the modeldriven treatment was based on published criteria (Kovach et al. 1990. Strawberry Scouting Procedures. Bulletin No . 203, New York State IPM Program. p. 18). In the weekly treatment, insecticides and fungicides were applied at 7-day inter-vals. No pesticide sprays were applied in either treatment until blooms appeared (5 Jul). Fungicides used (rates per 100 gal) were Ronilan FL (0.5 pt) or Rovral 50 WP (8 oz), tank-mixed with Captan 50 WP (2 lb). The insecticide used was Sevin 50 WP (2 lb). Pesticides were applied to runoff, using a Solo backpack sprayer (Model No. 425) with a flat-fan nozzle at approximately 30 psi pressure. Leaf wetness and temperature were measured in an apple orchard 0.3 mi from the strawberry plot, using a CR-10 micrologger and appropriate sensors (Campbell Scientific, Logan, UT). Tar-nished plant bug (TPB) populations were monitored weekly by tapping 10 fruit clusters per subplot into a white plastic dish and counting the number of TPB nymphs. The action threshold for insecticide spraying in the modeldriven treatment was a mean count of 0.5 nymphs/cluster. Ripe fruit were picked by hand, counted, and weighed one to three times/wk. At each picking, damaged berries were classed by the probable source of damage, and these classes were counted and weighed

Fit for work? Health, employability and challenges for the UK welfare reform agenda

This article introduces a special issue of Policy Studies entitled “Fit for work? Health, employability and challenges for the UK welfare reform agenda”. Growing from a shared concern over the need to expand the evidence base around the processes that led to large numbers of people claiming disability benefits in the UK, it brings together contributions from leading labour market and social policy researchers providing evidence and commentary on major reforms to Incapacity Benefit (IB) in the UK. This special issue address three key questions: what are the main causes of the long-term rise in the number of people claiming IBs; what will reduce the number of claimants; and what is likely to deliver policy effectively and efficiently? This introduction first explains and examines the challenges to reforms to IB in the UK, and then, in conclusion, highlights the answers to the previous three questions – first, labour market restructuring and marginalisation have driven the rise in numbers claiming IBs. Second, economic regeneration in the Britain’s less prosperous areas coupled with intensive and sustained supply-side support measures will bring numbers down. Third, delivery need to be flexible and tailored to individual needs and needs to be able to access local and expert knowledge in a range of organisations, including Job Centre Plus, the NHS as well as the private and voluntary sectors

Genome Sequencing of a Marine Spirillum, Oceanospirillum multiglobuliferum ATCC 33336T, from Japan

Oceanospirillum multiglobuliferum ATCC 33336T is a motile gammaproteobacterium with bipolar tufted flagella, noted for its low salt tolerance compared to other marine spirilla. This strain was originally isolated from the putrid infusions of Crassostrea gigas near Hiroshima, Japan. This paper presents a draft genome sequence for O. multiglobuliferum ATCC 33336T