Computational studies on the behaviour of anionic and nonionic surfactants at the SiO2_{2} (silicon dioxide)/water interface

Molecular dynamics simulations to study the behaviour of anionic (Sodium Dodecylsulfate, SDS) and nonionic (Monooleate of Sorbitan, SPAN80) surfactants close to a SiO$_{2}$ (silicon dioxide) surface were carried out. Simulations showed that a water layer was first adsorbed on the surface and then the surfactants were attached on that layer. Moreover, it was observed that water behaviour close to the surface influenced the surfactant adsorption since a semi-spherical micelle was formed on the SiO$_{2}$ surface with SDS molecules whereas a cylindrical micelle was formed with SPAN80 molecules. Adsorption of the micelles was conducted in terms of structural properties (density profiles and angular distributions) and dynamical behaviour (diffusion coefficients) of the systems. Finally, it was also shown that some water molecules moved inside the solid surface and located at specific sites of the solid surface.Comment: 8 pages, 6 fiigure

When Do Central Bank Interventions Influence Intra-Daily and Longer-Term Exchange Rate Movements?

This paper examines dollar interventions by the G3 since 1989, and the reasons that trader reactions to these interventions might differ over time and across central banks. Market microstructure theory provides a framework for understanding the process by which sterilized central bank interventions are observed and interpreted by traders, and how this process in turn, might influence exchange rates. Using intra-daily and daily exchange-rate and intervention data, the paper analyzes the influence of interventions on exchange-rate volatility, finding evidence of both within day and daily impact effects, but little evidence that interventions influence longer term volatility.central bank intervention, exchange rate volatility, market-microstructure

Azimuthal Correlations in p-p collisions

We report the analysis of experimental azimuthal correlations measured by STAR in p-p collisions at $\sqrt{s_{NN}}$ = 200 GeV. We conclude that for a fit of data using Pythia event generator we need to include two values of $k_{T}$.Comment: 4 page, 3 figures. Prepared for X Mexican Workshop on Particles and Fields. Morelia Mich. Nov 7-12, 200

Temperature dependence of the microscopic structure and density anomaly of the SPC/E and TIP4P-Ew water models. Molecular dynamics simulation results

We have investigated temperature trends of the microscopic structure of the SPC/E and TIP4P-Ew water models in terms of the pair distribution functions, coordination numbers, the average number of hydrogen bonds, the distribution of bonding states of a single molecule as well as the angular distribution of molecules by using the constant pressure molecular dynamics simulations. The evolution of the structure is put in correspondence with the dependence of water density on high temperatures down to the region of temperatures where the system becomes supercooled. It is shown that the fraction of molecules with three and four bonds determine the maximum density for both models. Moreover, the temperature dependence of the dielectric constant is obtained and analyzed.Comment: 11 pages, 5 figure

Intentionally disordered superlattices with high dc conductance

We study disordered quantum-well-based semiconductor superlattices where the disorder is intentional and short-range correlated. Such systems consist of quantum-wells of two different thicknesses randomly distributed along the growth direction, with the additional constraint that wells of one kind always appears in pairs. Imperfections due to interface roughness are considered by allowing the quantum-well thicknesses to fluctuate around their {\em ideal} values. As particular examples, we consider wide-gap (GaAs-Ga$_{1-x}$Al$_{x}$As) and narrow-gap (InAs-GaSb) superlattices. We show the existence of a band of extended states in perfect correlated disordered superlattices, giving rise to a strong enhancement of their finite-temperature dc conductance as compared to usual random ones whenever the Fermi level matches this band. This feature is seen to survive even if interface roughness is taken into account. Our predictions can be used to demonstrate experimentally that structural correlations inhibit the localization effects of disorder, even in the presence of imperfections. This effect might be the basis of new, filter-like or other specific-purpose electronic devices.Comment: REVTeX 3.0, 20 pages, 7 uuencoded compressed PostScript figures as a separate file. Submitted to IEEE J Quantum Elec

History of the special procedures: a ‘learning-by-doing’ approach to human rights implementation

The existence of UN Special Procedures is the unintended result of the competence accorded to the United Nations Commission on Human Rights and the Sub-Commission on the Prevention of Discrimination and Protection of Minorities in the 1967 Economic and Social Council Resolution 1235 (XLII). The Resolution authorised both bodies ‘to examine information relevant to gross violations of human rights and fundamental freedoms’. The lack of foresight in the creation of such mechanisms, now known as ‘special procedures’, is a fundamental factor in explaining the evolution of methods of work developed by different mandate holders. The ‘soft’ legal basis and geo-political factors surrounding the creation and renewal of mandates explains the freedom and flexibility they have enjoyed in establishing innovative monitoring activities that are more intrusive upon state sovereignty than any other UN human rights mechanism. As the significance of the Special Procedures’ work has grown, attempts to curtail their autonomy and impact have increased accordingly, facilitated precisely by what has been seen as, until recently, their major strength: the lack of a strong institutional and coherent legal framework regulating their activities. This chapter analyses this evolution and outlines the major challenges mandate holders face in maintaining their relevance