Hydrodynamic slip can align thin nanoplatelets in shear flow

The large-scale processing of nanomaterials such as graphene and MoS2 relies on understanding the flow behaviour of nanometrically-thin platelets suspended in liquids. Here we show, by combining non-equilibrium molecular dynamics and continuum simulations, that rigid nanoplatelets can attain a stable orientation for sufficiently strong flows. Such a stable orientation is in contradiction with the rotational motion predicted by classical colloidal hydrodynamics. This surprising effect is due to hydrodynamic slip at the liquid-solid interface and occurs when the slip length is larger than the platelet thickness; a slip length of a few nanometers may be sufficient to observe alignment. The predictions we developed by examining pure and surface-modified graphene is applicable to different solvent/2D material combinations. The emergence of a fixed orientation in a direction nearly parallel to the flow implies a slip-dependent change in several macroscopic transport properties, with potential impact on applications ranging from functional inks to nanocomposites.Energy Technolog

An extremely young massive clump forming by gravitational collapse in a primordial galaxy

When the cosmic star formation history peaks (z ~ 2), galaxies vigorously fed by cosmic reservoirs are gas dominated and contain massive star-forming clumps, thought to form by violent gravitational instabilities in highly turbulent gas-rich disks. However, a clump formation event has not been witnessed yet, and it is debated whether clumps survive energetic feedback from young stars, thus migrating inwards to form galaxy bulges. Here we report spatially resolved spectroscopy of a bright off-nuclear emission line region in a galaxy at z = 1.987. Although this region dominates the star formation in the galaxy disk, its stellar continuum remains undetected in deep imaging, revealing an extremely young (age < 10 Myr) massive clump, forming through the gravitational collapse of > 10$^9$ M$_{\odot}$ of gas. Gas consumption in this young clump is > 10 times faster than in the host galaxy, displaying high star formation efficiency during this phase, in agreement with our hydrodynamic simulations. The frequency of older clumps with similar masses coupled with our initial estimate of their formation rate (~ 2.5 Gyr$^{-1}$) supports long lifetimes (~ 500 Myr), favouring scenarios where clumps survive feedback and grow the bulges of present-day galaxies.Comment: Published in May 7 issue of Nature (http://dx.doi.org/10.1038/nature14409