Chlorine and Sulfur in Nearby Planetary Nebulae and H II Regions

We derive the chlorine abundances in a sample of nearby planetary nebulae (PNe) and H II regions that have some of the best available spectra. We use a nearly homogeneous procedure to derive the abundance in each object and find that the Cl/H abundance ratio shows similar values in H II regions and PNe. This supports our previous interpretation that the underabundance we found for oxygen in the H II regions is due to the depletion of their oxygen atoms into organic refractory dust components. For other elements, the bias introduced by ionization correction factors in their derived abundances can be very important, as we illustrate here for sulfur using photoionization models. Even for low-ionization PNe, the derived sulfur abundances can be lower than the real ones by up to 0.3 dex, and the differences found with the abundances derived for H II regions that have similar S/H can reach 0.4 dex.Comment: 2 pages, 1 figure, proceedings of the IAU Symposium No. 283, Planetary Nebulae: an Eye to the Futur

Oxygen enrichment in carbon-rich planetary nebulae

We study the relation between the chemical composition and the type of dust present in a group of 20 Galactic planetary nebulae (PNe) that have high quality optical and infrared spectra. The optical spectra are used, together with the best available ionization correction factors, to calculate the abundances of Ar, C, Cl, He, N, Ne, and O relative to H. The infrared spectra are used to classify the PNe in two groups depending on whether the observed dust features are representative of oxygen-rich or carbon-rich environments. The sample contains one object from the halo, eight from the bulge, and eleven from the local disc. We compare their chemical abundances with nucleosynthesis model predictions and with the ones obtained in seven Galactic H II regions of the solar neighbourhood. We find evidence of O enrichment (by $\sim$ 0.3 dex) in all but one of the PNe with carbon-rich dust (CRD). Our analysis shows that Ar, and especially Cl, are the best metallicity indicators of the progenitors of PNe. There is a tight correlation between the abundances of Ar and Cl in all the objects, in agreement with a lockstep evolution of both elements. The range of metallicities implied by the Cl abundances covers one order of magnitude and we find significant differences in the initial masses and metallicities of the PNe with CRD and oxygen-rich dust (ORD). The PNe with CRD tend to have intermediate masses and low metallicities, whereas most of the PNe with ORD show higher enrichments in N and He, suggesting that they had high-mass progenitors.Comment: Accepted for publication in MNRAS. 14 pages, 8 figures, 5 table

Sustainable enhancement of district heating and cooling configurations by combining thermal energy storage and life cycle assessment

District heating and cooling systems are designed and optimized to respond to the latest challenges of reducing energy demands while fulfilling comfort standards. Thermal energy storage (TES) with phase change materials can be employed to reduce the energy demands of buildings. This study considers a residential district located in Spain, where a general framework has been established to identify optimal combinations of energy conversion, delivery technologies, and operating rules. The Life Cycle Assessment (LCA) methodology was implemented within a mathematical model, and the objective function considered the minimization of environmental loads. Two environmental impact assessment methods were applied within the LCA methodology: IPCC 2013 GWP 100y and ReCiPe. Four optimal configurations were considered: a reference system (gas boiler and split-type air conditioners) and then three TES-based systems: one sensible (STES, water) and two latent (LTES1—paraffin emulsion and LTES2—sodium acetate trihydrate). Hourly environmental loads associated with electricity imports from the national grid were available. The conventional energy system always presented the worst performance from an environmental viewpoint, being penalized by the high consumption of natural gas. Regarding carbon emissions, LTES1 showed the lowest emissions, followed by STES and LTES2. Reductions in energy demands compensated the impact of paraffin, and results of STES are strongly dependent on tank design. However, considering the ReCiPe method, STES presented the lowest loads, followed by LTES1 and LTES2. Overall impacts of LTES1 with paraffin are higher than STES with water, mainly due to the paraffin and the high volume required

A nonlinear age-dependent model with spatial diffusion

The main goal of this paper is to study the existence and uniqueness of positive solution for a nonlinear age-dependent equation with spatial diffusion. For that, we mainly use properties of an eigenvalue problem related to the equation and the subsupersolution method. We justify that this method works for this kind of equation, in which appears a potential blowing-up and a non-local initial condition.Ministerio de Ciencia y Tecnologí

Algunos modelos estacionarios de dinámica de poblaciones estructurados en edad con difusión

En este trabajo, daremos algunos resultados de existencia y unicidad de solución para un problema de dinámica de poblaciones estructurado en edad con difusión. Primero describiremos un método de sub-supersolución para este tipo de problemas. A continuación, utilizaremos dicho método para dar resultados de existencia y no existencia en el caso particular de la ecuación logística, usando principalmente propiedades del problema de autovalores asociado a dicha ecuación.Ministerio de Educación y CienciaFondo Europeo de Desarrollo Regiona