Zinc depolarized electrochemical CO2 concentration

Two zinc depolarized electrochemical carbon dioxide concentrator concepts were analytically and experimentally evaluated for portable life support system carbon dioxide (CO2) removal application. The first concept, referred to as the zinc hydrogen generator electrochemical depolarized CO2 concentrator, uses a ZHG to generate hydrogen for direct use in an EDC. The second concept, referred to as the zinc/electrochemical depolarized concentrator, uses a standard EDC cell construction modified for use with the Zn anode. The Zn anode is consumed and subsequently regenerated, thereby eliminating the need to supply H2 to the EDC for the CO2 removal process. The evaluation was based primarily on an analytical evaluation of the two ZnDCs at projected end item performance and hardware design levels. Both ZnDC concepts for PLSS CO2 removal application were found to be noncompetitive in both total equivalent launch weight and individual extravehicular activity mission volume when compared to other candidate regenerable PLSS CO2 scrubbers

Regenerative CO2 removal for PLSS application

Various concepts for the design of the nonelectrochemical absorber were defined and evaluated. A preliminary design based on the use of hollow fiber membranes was developed. Small scale bench testing demonstrated the carbon dioxide removal capability and provided design data for scale-up to the one person level. A full scale conceptual design of the absorbent regeneration hardware using six electrochemical cells was also completed. The design was supported by single cell testing and showed that a full scale regeneration system, operating continuously over 24 hours, can regenerate the absorbent from one extravehicular activity mission. The single cell regeneration hardware was operated for over 800 hours

X-ray Timing of PSR J1852+0040 in Kesteven 79: Evidence of Neutron Stars Weakly Magnetized at Birth

The 105-ms X-ray pulsar J1852+0040 is the central compact object (CCO) in SNR Kes 79. We report a sensitive upper limit on its radio flux density of 12 uJy at 2 GHz using the NRAO GBT. Timing using XMM and Chandra over a 2.4 yr span reveals no significant change in its spin period. The 2 sigma upper limit on the period derivative leads, in the dipole spin-down formalism, to an energy loss rate E-dot < 7e33 ergs/s, surface magnetic field strength B_p < 1.5e11 G, and characteristic age tau_c = P/2P-dot > 8 Myr. This tau_c exceeds the age of the SNR by 3 orders of magnitude, implying that the pulsar was born spinning at its current period. However, the X-ray luminosity of PSR J1852+0040, L(bol) ~ 3e33(d/7.1 kpc)^2 ergs/s is a large fraction of E-dot, which challenges the rotation-powered assumption. Instead, its high blackbody temperature, 0.46+/-0.04 keV, small blackbody radius ~ 0.8 km, and large pulsed fraction, ~ 80%, may be evidence of accretion onto a polar cap, possibly from a fallback disk made of supernova debris. If B_p < 1e10 G, an accretion disk can penetrate the light cylinder and interact with the magnetosphere while resulting torques on the neutron star remain within the observed limits. A weak B-field is also inferred in another CCO, the 424-ms pulsar 1E 1207.4-5209, from its steady spin and soft X-ray absorption lines. We propose this origin of radio-quiet CCOs: the B-field, derived from a turbulent dynamo, is weaker if the NS is formed spinning slowly, which enables it to accrete SN debris. Accretion excludes neutron stars born with both B_p 0.1 s from radio pulsar surveys, where B_p 40 Myr) or recycled pulsars. Finally, such a CCO, if born in SN 1987A, could explain the non-detection of a pulsar there.Comment: 8 pages, 3 figures, to appear in The Astrophysical Journa

Technology advancement of the electrochemical CO2 concentrating process

Two multicell, liquid-cooled, advanced electrochemical depolarized carbon dioxide concentrator modules were fabricated. The cells utilized advanced, lightweight, plated anode current collectors, internal liquid cooling and lightweight cell frames. Both were designed to meet the carbon dioxide removal requirements of one-person, i.e., 1.0 kg/d (2.2 lb/d)

Biophysical, morphological, canopy optical property, and productivity data from the Superior National Forest

Described here are the results of a NASA field experiment conducted in the Superior National Forest near Ely, Minnesota, during the summers of 1983 and 1984. The purpose of the experiment was to examine the use of remote sensing to provide measurements of biophysical parameters in the boreal forests. Leaf area index, biomass, net primary productivity, canopy coverage, overstory and understory species composition data are reported for about 60 sites, representing a range of stand density and age for aspen and spruce. Leaf, needle, and bark high-resolution spectral reflectance and transmittance data are reported for the major boreal forest species. Canopy bidirectional reflectance measurements are provided from a helicopter-mounted Barnes Multiband Modular Radiometer (MMR) and the Thematic Mapper Simulator (TMS) on the NASA C-130 aircraft

One-man electrochemical air revitalization system evaluation

A program to evaluate the performance of a one man capacity, self contained electrochemical air revitalization system was successfully completed. The technology readiness of this concept was demonstrated by characterizing the performance of this one man system over wide ranges in cabin atmospheric conditions. The electrochemical air revitalization system consists of a water vapor electrolysis module to generate oxygen from water vapor in the cabin air, and an electrochemical depolarized carbon dioxide concentrator module to remove carbon dioxide from the cabin air. A control/monitor instrumentation package that uses the electrochemical depolarized concentrator module power generated to partially offset the water vapor electrolysis module power requirements and various structural fluid routing components are also part of the system. The system was designed to meet the one man metabolic oxygen generation and carbon dioxide removal requirements, thereby controlling cabin partial pressure of oxygen at 22 kN/sq m and cabin pressure of carbon dioxide at 400 N/sq m over a wide range in cabin air relative humidity conditions

Technology advancement of the electrochemical CO2 concentrating process

The overall objectives of the present program are to: (1) improve the performance of the electrochemical CO2 removal technique by increasing CO2 removal efficiencies at pCO2 levels below 400 Pa, increasing cell power output and broadening the tolerance of electrochemical cells for operation over wide ranges of cabin relative humidity; (2) design, fabricate, and assemble development hardware to continue the evolution of the electrochemical concentrating technique from the existing level to an advanced level able to efficiently meet the CO2 removal needs of a spacecraft air revitalization system (ARS); (3) develop and incorporate into the EDC the components and concepts that allow for the efficient integration of the electrochemical technique with other subsystems to form a spacecraft ARS; (4) combine ARS functions to enable the elimination of subsystem components and interfaces; and (5) demonstrate the integration concepts through actual operation of a functionally integrated ARS

Technology advancement of the electrochemical CO2 concentrating process

A five-cell, liquid-cooled advanced electrochemical depolarized carbon dioxide concentrator module was fabricated. The cells utilized the advanced, lightweight, plated anode current collector concept and internal liquid-cooling. The five cell module was designed to meet the carbon dioxide removal requirements of one man and was assembled using plexiglass endplates. This one-man module was tested as part of an integrated oxygen generation and recovery subsystem

Oxygen18 as Tracer in the Catalytic Decomposition of Potassium Chlorate

There is evidence that the catalytic action of manganese on the decomposition of potassium chlorate involves an alternate oxidation and reduction of the manganese. This evidence can be tested by enriching the oxygen of the catalyst with oxygen18 isotope. Oxygen liberated from chlorate decomposition with an enriched catalyst should contain oxygen18. Recently Forkushima et al (1) carried out a similar experiment. They enriched potassium chlorate with oxygen18 and decomposed it with Mn02.H20 containing ordinary oxygen. Water was formed from successive portions of the liberated oxygen. The density of this water was less than the density of water prepared from oxygen liberated from KC103 without a catalyst. They concluded that some unstable compound is formed between KC103 and Mn02, and that oxygen is liberated from this compound. They further concluded that only a limited portion of the catalyst is used in the reaction. In the present experiment the manganese dioxide was enriched with oxygen18, and the KC103 was normal. Isotopic ratios of liberated oxygen were determined directly by use of a mass spectrograph

Radiochlorine36 as a Tracer in the Decomposition of Potassium Chlorate

The thermal decomposition of potassium chlorate has been shown to be complex. Oxygen is evolved and, depending upon the conditions, various quantities of perchlorate are formed. At least two sets of equations have been proposed to explain the reaction. Otto and Fry (5) proposed that potassium chlorate decomposes by two simultaneous reactions