Connection between slow and fast dynamics of molecular liquids around the glass transition

The mean-square displacement (MSD) was measured by neutron scattering at various temperatures and pressures for a number of molecular glass-forming liquids. The MSD is invariant along the glass-transition line at the pressure studied, thus establishing an ``intrinsic'' Lindemann criterion for any given liquid. A one-to-one connection between the MSD's temperature dependence and the liquid's fragility is found when the MSD is evaluated on a time scale of approximately 4 nanoseconds, but does not hold when the MSD is evaluated at shorter times. The findings are discussed in terms of the elastic model and the role of relaxations, and the correlations between slow and fast dynamics are addressed.Comment: accepted by Phys Rev E (2010

Cysteinylation and homocysteinylation of plasma protein thiols during ageing of healthy human beings

The purpose of the present study was to determine the relative amount of S-thiolated proteins (i.e. S-homocysteinylated, S-cysteinylglycinylated, S-glutathionylated and S-cysteinylated proteins) to the total protein thiols (i.e. the sum of reduced protein sulphydryl groups (PSHs) and protein mixed disulphides with homocysteine [HcySH], cysteinylglycine, cysteine [CysSH] and glutathione) in the plasma of healthy individuals aged 20 to 93. After plasma separation, total protein thiols, S-thiolated proteins, as well as CysSH, cystine, HcySH and homocystine were measured by high-performance liquid chromatography (HPLC) with fluorescence determination of the thiol-monobromobimane conjugate. Determination of plasma levels of protein thiols was performed by spectrophotometry with 5,5′-dithiobis(2-nitrobenzoic acid) as a titrating agent. The present study demonstrates an age-dependent reduction in the amount of PSHs, and an age-dependent increase in cysteinylated and homocysteinylated plasma proteins in healthy human beings. This indicates that the efficiency of the reduced protein thiol pool as an antioxidant defence system decreases with age, possibly causing an increased risk of irreversible oxidation (i.e. further oxidation to sulphinic and sulphonic acids, which are usually not reducible by thiol reducing agents) of sulphydryl groups of plasma proteins. The drop in the plasma level of protein sulphydryl groups suggests depletion and/or impairment of the antioxidant capacity of plasma, likely related to an alteration of the delicate balance between the different redox forms of thiols

A comparison of extreme value theory approaches for determining value at risk

This paper compares a number of different extreme value models for determining the value at risk (VaR) of three LIFFE futures contracts. A semi-nonparametric approach is also proposed, where the tail events are modeled using the generalised Pareto distribution, and normal market conditions are captured by the empirical distribution function. The value at risk estimates from this approach are compared with those of standard nonparametric extreme value tail estimation approaches, with a small sample bias-corrected extreme value approach, and with those calculated from bootstrapping the unconditional density and bootstrapping from a GARCH(1,1) model. The results indicate that, for a holdout sample, the proposed semi-nonparametric extreme value approach yields superior results to other methods, but the small sample tail index technique is also accurate

Surface Composition of Pluto's Kiladze Area and Relationship to Cryovolcanism

A link between exposures of water (H${}_{2}$O) ice with traces of an ammoniated compound (e.g., a salt) and the probable effusion of a water-rich cryolava onto the surface of Pluto has been established in previous investigations (Dalle Ore et al. 2019). Here we present the results from the application of a machine learning technique and a radiative transfer model to a water-ice-rich exposure in Kiladze area and surroundings on Pluto. We demonstrate the presence of an ammoniated material suggestive of an undetermined but relatively recent emplacement event. Kiladze lies in a region of Pluto's surface that is structurally distinct from that of the areas where similar evidence points to cryovolcanic activity at some undetermined time in the planet's history. Although the Kiladze depression superficially resembles an impact crater, a close inspection of higher-resolution images indicates that the feature lacks the typical morphology of a crater. Here we suggest that a cryolava water carrying an ammoniated component may have come onto the surface at the Kiladze area via one or more volcanic collapses, as in a resurgent volcanic caldera complex. Large regions east of Kiladze also exhibit the presence of H${}_{2}$O ice and have graben-like structures suggestive of cryovolcanic activity, but with existing data are not amenable to the detailed search that might reveal an ammoniated component.Comment: 28 pages, 11 figures, submitted to Icaru

Colloids in light fields: particle dynamics in random and periodic energy landscapes

The dynamics of colloidal particles in potential energy landscapes have mainly been investigated theoretically. In contrast, here we discuss the experimental realization of potential energy landscapes with the help of light fields and the observation of the particle dynamics by video microscopy. The experimentally observed dynamics in periodic and random potentials are compared to simulation and theoretical results in terms of, e.g. the mean-squared displacement, the time-dependent diffusion coefficient or the non-Gaussian parameter. The dynamics are initially diffusive followed by intermediate subdiffusive behaviour which again becomes diffusive at long times. How pronounced and extended the different regimes are, depends on the specific conditions, in particular the shape of the potential as well as its roughness or amplitude but also the particle concentration. Here we focus on dilute systems, but the dynamics of interacting systems in external potentials, and thus the interplay between particle-particle and particle-potential interactions, is also mentioned briefly. Furthermore, the observed dynamics of dilute systems resemble the dynamics of concentrated systems close to their glass transition, with which it is compared. The effect of certain potential energy landscapes on the dynamics of individual particles appears similar to the effect of interparticle interactions in the absence of an external potential

On the correlation between fragility and stretching in glassforming liquids

We study the pressure and temperature dependences of the dielectric relaxation of two molecular glassforming liquids, dibutyl phtalate and m-toluidine. We focus on two characteristics of the slowing down of relaxation, the fragility associated with the temperature dependence and the stretching characterizing the relaxation function. We combine our data with data from the literature to revisit the proposed correlation between these two quantities. We do this in light of constraints that we suggest to put on the search for empirical correlations among properties of glassformers. In particular, argue that a meaningful correlation is to be looked for between stretching and isochoric fragility, as both seem to be constant under isochronic conditions and thereby reflect the intrinsic effect of temperature

Quaoar: New, Longitudinaly Resolved, Spectroscopic Characterization of Its Surface

(50000) Quaoar, one of the largest Trans-neptunian objects, is comparable in size to Pluto's moon Charon. However, while Charon's surface is rich almost exclusively in H2O ice, Quaoar's surface characterized by ices of CH4, N2, as well as C2H6, a product of irradiation of CH4 (Dalle Ore et al. 2009). Because of its distance from the Sun, Quaoar is expected to have preserved, to a degree, its original composition, however, its relatively small size did not make it a prime candidate for presence of volatile ices in the study by Schaller and Brown (2007). Furthermore, based on the Brown et al. (2011) study (Brown, Schaller, & Fraser, 2011. A Hypothesis for the Color Diversity of the Kuiper Belt. ApJL, 739, L60) its red coloration points to CH3OH as the ice which, when irradiated, might have produced the red material. We present new visible to near-infrared (0.3-2.48 micrometers) spectro-photometric data obtained with the XSHOOTER (Vernet et al. 2011, A&A, 536A, 105 ) instrument at the VLT-ESO facility at four different longitudes on the surface of Quaoar. The data are complemented by previously published photometric observations obtained in the near-infrared (3.6, 4.5 micrometers) with the Spitzer Space Telescope, which provide an extra set of constraints in the model calculation process in spite of the different observing times that preclude establishing the spatial consistency between the two sets. For each of the four spectra we perform spectral modeling of the entire wavelength range -from 0.3 to 4.5 micrometers- by means of a code based on the Shkuratov radiative transfer formulation of the slab model. We obtain spatially resolved compositional information for the surface of Quaoar supporting the presence of CH4 and C2H6, as previously reported, along with evidence for N2 and NH3OH. The albedo at the two Spitzer bands indicates the likely presence of CO and CO2. CH3OH, predicted on the basis of Quaoar's coloration (Brown et al. 2011), is not found at any of the four longitudes, implying that the presence of this ice is a sufficient, but not necessary condition for reddening of TNO surfaces. Other ices, in particular CH4 (Brunetto et al. 2006), have been shown to be plausible precursors for reddening of TNO surfaces

Dataset of measured and commented pantograph electric arcs in DC railways

DC railways are characterized by particularly intense arcing caused by pantograph detachment, due to the large current intensity and the general implementation of onboard resonant filters, whose transient response is triggered by electric transients including electric arcs. Electric arc depends on the train speed (the relative speed between the sliding contact over the pantograph and the hot spot on the catenary system), the intensity of the collected pantograph current and the line voltage level. Electric arcs are broadband in nature and can trigger the system transient response dominated by the resonant filter, besides interfering with the operation of onboard equipment (such as for energy conversion and metering)

Composition of KBO (50000) Quaoar

Aims. The objective of this work is to investigate the physical properties of objects beyond Neptune-the new frontiers of the Solar System-and in particular to study the surface composition of (50 000) Quaoar, a classical Transneptunian (or Kuiper Belt) object. Because of its distance from the Sun, Quaoar is expected to have preserved, to a degree, its original composition. Our goals are to determine to what degree this is true and to shed light on the chemical evolution of this icy body. Methods. We present new near-infrared (3.6 and 4.5 mu m) photometric data obtained with the Spitzer Space Telescope. These data complement high resolution, low signal-to-noise spectroscopic and photometric data obtained in the visible and near-infrared (0.4-2.3 mu m) at VLT-ESO and provide an excellent set of constraints in the model calculation process. We perform spectral modeling of the entire wavelength range-from 0.3 to 4.5 mu m by means of a code based on the Shkuratov radiative transfer formulation of the slab model. We also attempt to determine the temperature of H(2)O ice making use of the crystalline feature at 1.65 mu m. Results. We present a model confirming previous results regarding the presence of crystalline H(2)O and CH(4) ice, as well as C(2)H(6) and organic materials, on the surface of this distant icy body. We attempt a measurement of the temperature and find that stronger constraints on the composition are needed to obtain a precise determination. Conclusions. Model fits indicate that N(2) may be a significant component, along with a component that is bright at lambda > 3.3 mu m, which we suggest at this time could be amorphous H(2)O ice in tiny grains or thin grain coatings. Irradiated crystalline H(2)O could be the source of small-grained amorphous H(2)O ice. The albedo and composition of Quaoar, in particular the presence of N(2), if confirmed, make this TNO quite similar to Triton and Pluto

Peer-to-Peer and Mass Communication Effect on Revolution Dynamics

Revolution dynamics is studied through a minimal Ising model with three main influences (fields): personal conservatism (power-law distributed), inter-personal and group pressure, and a global field incorporating peer-to-peer and mass communications, which is generated bottom-up from the revolutionary faction. A rich phase diagram appears separating possible terminal stages of the revolution, characterizing failure phases by the features of the individuals who had joined the revolution. An exhaustive solution of the model is produced, allowing predictions to be made on the revolution's outcome