550 research outputs found
"Wet-to-Dry" Conformational Transition of Polymer Layers Grafted to Nanoparticles in Nanocomposite
The present communication reports the first direct measurement of the
conformation of a polymer corona grafted around silica nano-particles dispersed
inside a nanocomposite, a matrix of the same polymer. This measurement
constitutes an experimental breakthrough based on a refined combination of
chemical synthesis, which permits to match the contribution of the neutron
silica signal inside the composite, and the use of complementary scattering
methods SANS and SAXS to extract the grafted polymer layer form factor from the
inter-particles silica structure factor. The modelization of the signal of the
grafted polymer on nanoparticles inside the matrix and the direct comparison
with the form factor of the same particles in solution show a clear-cut change
of the polymer conformation from bulk to the nanocomposite: a transition from a
stretched and swollen form in solution to a Gaussian conformation in the matrix
followed with a compression of a factor two of the grafted corona. In the
probed range, increasing the interactions between the grafted particles (by
increasing the particle volume fraction) or between the grafted and the free
matrix chains (decreasing the grafted-free chain length ratio) does not
influence the amplitude of the grafted brush compression. This is the first
direct observation of the wet-to-dry conformational transition theoretically
expected to minimize the free energy of swelling of grafted chains in
interaction with free matrix chains, illustrating the competition between the
mixing entropy of grafted and free chains, and the elastic deformation of the
grafted chains. In addition to the experimental validation of the theoretical
prediction, this result constitutes a new insight for the nderstanding of the
general problem of dispersion of nanoparticles inside a polymer matrix for the
design of new nanocomposites materials
Morphology of axisymmetric vesicles with encapsulated filaments and impurities
The shape deformation of a three-dimensional axisymmetric vesicle with
encapsulated filaments or impurities is analyzed by integrating a dissipation
dynamics. This method can incorporate systematically the constraint of a fixed
surface area and/or a fixed volume. The filament encapsulated in a vesicle is
assumed to take a form of a rod or a ring so as to imitate cytoskeletons. In
both cases, results of the shape transition of the vesicle are summarized in
phase diagrams in the phase space of the vesicular volume and a rod length or a
ring radius.
We also study the dynamics of a vesicle with impurities coupled to the
membrane curvature. The phase separation and the associated shape deformation
in the early stage of the dynamical evolution can well be explained by the
linear stability analysis. Long runs of simulation demonstrate the nonlinear
coarsening of the wavy deformation of the vesicle in the late stage.Comment: 9 pages, 9 figure
Zooming In on the Progenitors of Superluminous Supernovae With the HST
We present Hubble Space Telescope (HST) rest-frame ultraviolet imaging of the
host galaxies of 16 hydrogen-poor superluminous supernovae (SLSNe), including
11 events from the Pan-STARRS Medium Deep Survey. Taking advantage of the
superb angular resolution of HST, we characterize the galaxies' morphological
properties, sizes and star formation rate (SFR) densities. We determine the
supernova (SN) locations within the host galaxies through precise astrometric
matching, and measure physical and host-normalized offsets, as well as the SN
positions within the cumulative distribution of UV light pixel brightness. We
find that the host galaxies of H-poor SLSNe are irregular, compact dwarf
galaxies, with a median half-light radius of just 0.9 kpc. The UV-derived SFR
densities are high ( ~ 0.1 M_sun/yr/kpc^2), suggesting that SLSNe
form in overdense environments. Their locations trace the UV light of their
host galaxies, with a distribution intermediate between that of long-duration
gamma-ray bursts (LGRBs) (which are strongly clustered on the brightest regions
of their hosts) and a uniform distribution (characteristic of normal
core-collapse SNe), though cannot be statistically distinguished from either
with the current sample size. Taken together, this strengthens the picture that
SLSN progenitors require different conditions than those of ordinary
core-collapse SNe to form, and that they explode in broadly similar galaxies as
do LGRBs. If the tendency for SLSNe to be less clustered on the brightest
regions than are LGRBs is confirmed by a larger sample, this would indicate a
different, potentially lower-mass progenitor for SLSNe than LRGBs.Comment: ApJ in press; matches published version. Minor changes following
referee's comments; conclusions unchange
Orientational phase transitions in the hexagonal phase of a diblock copolymer melt under shear flow
We generalize the earlier theory by Fredrickson [J. Rheol. v.38, 1045 (1994)]
to study the orientational behaviour of the hexagonal phase of diblock
copolymer melt subjected to steady shear flow. We use symmetry arguments to
show that the orientational ordering in the hexagonal phase is a much weaker
effect than in the lamellae. We predict the parallel orientation to be stable
at low and the perpendicular orientation at high shear rates. Our analysis
reproduces the experimental results by Tepe et al. [Macromolecules v.28, 3008
(1995)] and explains the difficulties in experimental observation of the
different orientations in the hexagonal phase.Comment: 21 pages, 6 eps figures, submitted to Physical Review
Superconducting Fluxon Pumps and Lenses
We study stochastic transport of fluxons in superconductors by alternating
current (AC) rectification. Our simulated system provides a fluxon pump,
"lens", or fluxon "rectifier" because the applied electrical AC is transformed
into a net DC motion of fluxons. Thermal fluctuations and the asymmetry of the
ratchet channel walls induce this "diode" effect, which can have important
applications in devices, like SQUID magnetometers, and for fluxon optics,
including convex and concave fluxon lenses. Certain features are unique to this
novel two-dimensional (2D) geometric pump, and different from the previously
studied 1D ratchets.Comment: Phys. Rev. Lett. 83, in press (1999); 4 pages, 5 .gif figures;
figures also available at http://www-personal.engin.umich.edu/~nori/ratche
Three and four current reversals versus temperature in correlation ratchets with a simple sawtooh potential
Transport of Brownian particles on a simple sawtooth potential subjected to
both unbiased thermal and nonequilibrium symmetric three-level Markovian noise
is considered. The new effects of three and four current reversals as a
function of temperature are established in such correlation ratchets. The
parameter space coordinates of the fixed points associated with these current
reversals and the necessary and sufficient conditions for the existence of the
novel current reversals are found.Comment: 4 pages, 5 figures; some changes introduced; accepted for publication
in Physical Review
Interactions between proteins bound to biomembranes
We study a physical model for the interaction between general inclusions
bound to fluid membranes that possess finite tension, as well as the usual
bending rigidity. We are motivated by an interest in proteins bound to cell
membranes that apply forces to these membranes, due to either entropic or
direct chemical interactions. We find an exact analytic solution for the
repulsive interaction between two similar circularly symmetric inclusions. This
repulsion extends over length scales of order tens of nanometers, and contrasts
with the membrane-mediated contact attraction for similar inclusions on
tensionless membranes. For non circularly symmetric inclusions we study the
small, algebraically long-ranged, attractive contribution to the force that
arises. We discuss the relevance of our results to biological phenomena, such
as the budding of caveolae from cell membranes and the striations that are
observed on their coats.Comment: 22 pages, 2 figure
Spontaneous Oscillations of Collective Molecular Motors
We analyze a simple stochastic model to describe motor molecules which
cooperate in large groups and present a physical mechanism which can lead to
oscillatory motion if the motors are elastically coupled to their environment.
Beyond a critical fuel concentration, the non-moving state of the system
becomes unstable with respect to a mode with angular frequency omega. We
present a perturbative description of the system near the instability and
demonstrate that oscillation frequencies are determined by the typical
timescales of the motors.Comment: 11 pages, Revtex, 4 pages Figure
Force Dependence of the Michaelis Constant in a Two-State Ratchet Model for Molecular Motors
We present a quantitative analysis of recent data on the kinetics of ATP
hydrolysis, which has presented a puzzle regarding the load dependence of the
Michaelis constant. Within the framework of coarse grained two-state ratchet
models, our analysis not only explains the puzzling data, but provides a
modified Michaelis law, which could be useful as a guide for future
experiments.Comment: 4 pages, 3 eps figures, accepted for publication on Physical Review
Letter
Euler buckling in red blood cells: An optically driven biological micromotor
We investigate the physics of an optically-driven micromotor of biological
origin. A single, live red blood cell, when placed in an optical trap folds
into a rod-like shape. If the trapping laser beam is circularly polarized, the
folded RBC rotates. A model based on the concept of buckling instabilities
captures the folding phenomenon; the rotation of the cell is simply understood
using the Poincar\`e sphere. Our model predicts that (i) at a critical
intensity of the trapping beam the RBC shape undergoes large fluctuations and
(ii) the torque is proportional to the intensity of the laser beam. These
predictions have been tested experimentally. We suggest a possible mechanism
for emergence of birefringent properties in the RBC in the folded state
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