Laser-controlled fluorescence in two-level systems

The ability to modify the character of fluorescent emission by a laser-controlled, optically nonlinear process has recently been shown theoretically feasible, and several possible applications have already been identified. In operation, a pulse of off-resonant probe laser beam, of sufficient intensity, is applied to a system exhibiting fluorescence, during the interval of excited- state decay following the initial excitation. The result is a rate of decay that can be controllably modified, the associated changes in fluorescence behavior affording new, chemically specific information. In this paper, a two-level emission model is employed in the further analysis of this all-optical process; the results should prove especially relevant to the analysis and imaging of physical systems employing fluorescent markers, these ranging from quantum dots to green fluorescence protein. Expressions are presented for the laser-controlled fluorescence anisotropy exhibited by samples in which the fluorophores are randomly oriented. It is also shown that, in systems with suitably configured electronic levels and symmetry properties, fluorescence emission can be produced from energy levels that would normally decay nonradiatively. © 2010 American Chemical Society

Interparticle interactions:Energy potentials, energy transfer, and nanoscale mechanical motion in response to optical radiation

In the interactions between particles of material with slightly different electronic levels, unusually large shifts in the pair potential can result from photoexcitation, and on subsequent electronic excitation transfer. To elicit these phenomena, it is necessary to understand the fundamental differences between a variety of optical properties deriving from dispersion interactions, and processes such as resonance energy transfer that occur under laser irradiance. This helps dispel some confusion in the recent literature. By developing and interpreting the theory at a deeper level, one can anticipate that in suitable systems, light absorption and energy transfer will be accompanied by significant displacements in interparticle separation, leading to nanoscale mechanical motion

Drinking water and pregnancy outcome in central North Carolina: source, amount, and trihalomethane levels.

In spite of the recognition of potentially toxic chemicals in chlorinated drinking water, few studies have evaluated reproductive health consequences of such exposure. Using data from a case-control study of miscarriage, preterm delivery, and low birth weight in central North Carolina, we evaluated risk associated with water source, amount, and trihalomethane (THM) concentration. Water source was not related to any of those pregnancy outcomes, but an increasing amount of ingested water was associated with decreased risks of all three outcomes (odds ratios around 1.5 for 0 glasses per day relative to 1-3 glasses per day, falling to 0.8 for 4+ glasses per day). THM concentration and dose (concentration x amount) were not related to pregnancy outcome, with the possible exception of an increased risk of miscarriage in the highest sextile of THM concentration (adjusted odds ratio = 2.8, 95% confidence interval = 1.1-2.7), which was not part of an overall dose-response gradient. These data do not indicate a strong association between chlorination by-products and adverse pregnancy outcome, but given the limited quality of our exposure assessment and the increased miscarriage risk in the highest exposure group, more refined evaluation is warranted

Excitation spectrum in a cylindrical Bose-Einstein gas

Whole excitation spectrum is calculated within the Popov approximation of the Bogoliubov theory for a cylindrical symmetric Bose-Einstein gas trapped radially by a harmonic potential. The full dispersion relation and its temperature dependence of the zero sound mode propagating along the axial direction are evaluated in a self-consistent manner. The sound velocity is shown to depend not only on the peak density, but also on the axial area density. Recent sound velocity experiment on Na atom gas is discussed in light of the present theory.Comment: 4 pages, 5 eps figure

Quantum Kinetic Theory VI: The Growth of a Bose-Einstein Condensate

A detailed analysis of the growth of a BEC is given, based on quantum kinetic theory, in which we take account of the evolution of the occupations of lower trap levels, and of the full Bose-Einstein formula for the occupations of higher trap levels, as well as the Bose stimulated direct transfer of atoms to the condensate level introduced by Gardiner et al. We find good agreement with experiment at higher temperatures, but at lower temperatures the experimentally observed growth rate is somewhat more rapid. We also confirm the picture of the ``kinetic'' region of evolution, introduced by Kagan et al., for the time up to the initiation of the condensate. The behavior after initiation essentially follows our original growth equation, but with a substantially increased rate coefficient. Our modelling of growth implicitly gives a model of the spatial shape of the condensate vapor system as the condensate grows, and thus provides an alternative to the present phenomenological fitting procedure, based on the sum of a zero-chemical potential vapor and a Thomas-Fermi shaped condensate. Our method may give substantially different results for condensate numbers and temperatures obtained from phenomentological fits, and indicates the need for more systematic investigation of the growth dynamics of the condensate from a supersaturated vapor.Comment: TeX source; 29 Pages including 26 PostScript figure

An ALMA 3mm continuum census of Westerlund 1

Context. Massive stars play an important role in both cluster and galactic evolution and the rate at which they lose mass is a key driver of both their own evolution and their interaction with the environment up to and including their terminal SNe explosions. Young massive clusters provide an ideal opportunity to study a co-eval population of massive stars, where both their individual properties and the interaction with their environment can be studied in detail. Aims. We aim to study the constituent stars of the Galactic cluster Westerlund 1 in order to determine mass-loss rates for the diverse post-main sequence population of massive stars. Methods. To accomplish this we made 3mm continuum observations with the Atacama Large Millimetre/submillimetre Array. Results. We detected emission from 50 stars in Westerlund 1, comprising all 21 Wolf-Rayets within the field of view, plus eight cool and 21 OB super-/hypergiants. Emission nebulae were associated with a number of the cool hypergiants while, unexpectedly, a number of hot stars also appear spatially resolved. Conclusions. We were able to measure the mass-loss rates for a unique population of massive post-main sequence stars at every stage of evolution, confirming a significant increase as stars transitioned from OB supergiant to WR states via LBV and/or cool hypergiant phases. Fortuitously, the range of spectral types exhibited by the OB supergiants provides a critical test of radiatively-driven wind theory and in particular the reality of the bi-stability jump. The extreme mass-loss rate inferred for the interacting binary Wd1-9 in comparison to other cluster members confirmed the key role binarity plays in massive stellar evolution. The presence of compact nebulae around a number of OB and WR stars is unexpected; by analogy to the cool super-/hypergiants we attribute this to confinement and sculpting of the stellar wind via interaction with the intra-cluster medium/wind. Given the morphology of core collapse SNe depend on the nature of the pre-explosion circumstellar environment, if this hypothesis is correct then the properties of the explosion depend not just on the progenitor, but also the environment in which it is located

Restoration and Monitoring of the River Otter Population in Iowa

Northern river otters (Lontra canadensis) were widespread in North America at the time of European settlement. However, river otters were extirpated from most of Iowa in the early 1900s due to habitat degradation and unregulated harvest. In 1985, the Iowa Department of Natural Resources began an effort to restore the river otter population throughout the state, including a pilot study of survival to determine if establishment was feasible. Annual survival was estimated to be 86% during the pilot study. River otters dispersed an average of about 11 km from the point of release and exhibited habitat use typical for the species. Based on the successful pilot study, 261 river otters were released in the state of Iowa from 1986-2001. More recently we examined the age structure and reproductive effort of 81 river otters (43 females and 38 males) collected in Iowa from 1999-2001 to document the characteristics of the reestablished population. We found that 41% of the otters sampled were juveniles, 38% were yearlings and 21% were adults. Fifty-five percent of all female otters were pregnant, and 80% of adult females were pregnant. We observed a mean of 2.9 corpora lutea/female and calculated that female’s ≥ 1 year old could potentially produce an average 5.7 female offspring during an average life span. Based on the widespread distribution, healthy reproductive characteristics, and high survival rates it is feasible that a limited harvest of river otter could be implemented in Iowa