Charge density study with the Maximum Entropy Method on model data of silicon. A search for non-nuclear attractors

1990 Sakata and Sato applied the maximum entropy method (MEM) to a set of structure factors measured earlier by Saka and Kato with the Pendellösung method. They found the presence of non-nuclear attractors, i.e., maxima in the density between two bonded atoms. We applied the MEM to a limited set of Fourier data calculated from a known electron density distribution (EDD) of silicon. The EDD of silicon was calculated with the program ADF-BAND. This program performs electronic structure calculations, including periodicity, based on the density functional theory of Hohenberg and Kohn. No non-nuclear attractor between two bonded silicon atoms was observed in this density. Structure factors were calculated from this density and the same set of structure factors that was measured by Saka and Kato was used in the MEM analysis. The EDD obtained with the MEM shows the same non-nuclear attractors that were later obtained by Sakata and Sato. This means that the non-nuclear attractors in silicon are really an artefact of the MEM

The properties of kaonic nuclei in relativistic mean-field theory

The static properties of some possible light and moderate kaonic nuclei, from C to Ti, are studied in the relativistic mean-field theory. The 1s and 1p state binding energies of $K^-$ are in the range of $73\sim 96$ MeV and $22\sim 63$ MeV, respectively. The binding energies of 1p states increase monotonically with the nucleon number A. The upper limit of the widths are about $42\pm 14$ MeV for the 1s states, and about $71\pm 10$ MeV for the 1p states. The lower limit of the widths are about $12\pm 4$ MeV for the 1s states, and $21\pm 3$ MeV for the 1p states. If $V_{0}\leq 30$ MeV, the discrete $K^-$ bound states should be identified in experiment. The shrinkage effect is found in the possible kaonic nuclei. The interior nuclear density increases obviously, the densest center density is about $2.1\rho_{0}$.Comment: 9 pages, 2 tables and 1 figure, widths are considered, changes a lo

Intercalation-enhanced electric polarization and chain formation of nano-layered particles

Microscopy observations show that suspensions of synthetic and natural nano-layered smectite clay particles submitted to a strong external electric field undergo a fast and extended structuring. This structuring results from the interaction between induced electric dipoles, and is only possible for particles with suitable polarization properties. Smectite clay colloids are observed to be particularly suitable, in contrast to similar suspensions of a non-swelling clay. Synchrotron X-ray scattering experiments provide the orientation distributions for the particles. These distributions are understood in terms of competing (i) homogenizing entropy and (ii) interaction between the particles and the local electric field; they show that clay particles polarize along their silica sheet. Furthermore, a change in the platelet separation inside nano-layered particles occurs under application of the electric field, indicating that intercalated ions and water molecules play a role in their electric polarization. The resulting induced dipole is structurally attached to the particle, and this causes particles to reorient and interact, resulting in the observed macroscopic structuring. The macroscopic properties of these electro-rheological smectite suspensions may be tuned by controlling the nature and quantity of the intercalated species, at the nanoscale.Comment: 7 pages, 5 figure

Who learns from whom? Supporting users and developers of a major biodiversity e-infrastructure

Abstract. Support systems play an important role for the communication between users and developers of software. We studied two support systems, an issues tracker and an email service available for Scratchpads, a Web 2.0 social networking tool that enables communities to build, share, manage and publish biodiversity information on the Web. Our aim was to identify co-learning opportunities between users and developers of the Scratchpad system by asking which support system was used by whom and for what type of questions. Our results show that issues tracker and emails cater to different user mentalities as well as different kind of questions and suggest ways to improve the support system as part of the development under the EU funded ViBRANT programme