969 research outputs found
On the measurement and impact of fiscal decentralization
The typical post-Bretton Woods era development approach that emphasized central government-led development efforts has changed dramatically, and local governments have clearly emerged as players in development policy. The thinking about what is important to achieve in development objectives is changing as fiscal decentralization reforms are being pursued by many countries around the world. In this context, a number of studies have attempted to quantify the impact of decentralization by relating some measure of it to economic outcomes of fiscal stability, economic growth, and public sector size. But decentralization is surprisingly difficult to measure. Nearly all cases examining the relationship between decentralization and macroeconomic performance have relied on the Government Finance Statistics (GFS) of the International Monetary Fund. However, despite its merits, GFS falls short in providing a full picture of fiscal decentralization. For some countries, however, there is data that more accurately captures fiscal responsibilities among different types of governments.Decentralization,Banks&Banking Reform,Municipal Financial Management,Public&Municipal Finance,Public Sector Economics&Finance,National Governance,Public Sector Economics&Finance,Banks&Banking Reform,Municipal Financial Management,Urban Economics
Adsorption and Diffusion of Pt and Au on the Stoichiometric and Reduced TiO2 Rutile (110) Surfaces
A comparative first principles pseudopotential study of the adsorption and
migration profiles of single Pt and Au atoms on the stoichiometric and reduced
TiO2 rutile (110) surfaces is presented. Pt and Au behave similarly with
respect to (i) most favorable adsorption sites, which are found to be the
hollow and substitutional sites on the stoichiometric and reduced surfaces,
respectively, (ii) the large increase in their binding energy (by ~1.7 eV) when
the surface is reduced, and (iii) their low migration barrier near 0.15 eV on
the stoichiometric surface. Pt, on the other hand, binds more strongly (by ~2
eV) to both surfaces. On the stoichiometric surface, Pt migration pattern is
expected to be one-dimensional, which is primarily influenced by interactions
with O atoms. Au migration is expected to be two-dimensional, with Au-Ti
interactions playing a more important role. On the reduced surface, the
migration barrier for Pt diffusion is significantly larger compared to Au.Comment: 3 figures, 1 table, submitted to PR
Density-relaxation part of the self energy
A comment is made on the large-cluster limit of the self-energy correction for the quasiparticle energy gap in silicon clusters presented by Serdar Ogut, James R. Chelikowsky and Steven G. Louie in Phys. Rev. Lett. 79, 1770 (1997)
The Electronic and Superconducting Properties of Oxygen-Ordered MgB2 compounds of the form Mg2B3Ox
Possible candidates for the Mg2B3Ox nanostructures observed in bulk of
polycrystalline MgB2 (Ref.1) have been studied using a combination of
Z-contrast imaging, electron energy loss spectroscopy (EELS) and
first-principles calculations. The electronic structures, phonon modes, and
electron phonon coupling parameters are calculated for two oxygen-ordered MgB2
compounds of composition Mg2B3O and Mg2B3O2, and compared with those of MgB2.
We find that the density of states for both Mg2B3Ox structures show very good
agreement with EELS, indicating that they are excellent candidates to explain
the observed coherent oxygen precipitates. Incorporation of oxygen reduces the
transition temperature and gives calculated TC values of 18.3 K and 1.6 K for
Mg2B3O and Mg2B3O2, respectively.Comment: Submitted to PR
Ab Initio Structural Energetics of Beta-Si3N4 Surfaces
Motivated by recent electron microscopy studies on the Si3N4/rare-earth oxide
interfaces, the atomic and electronic structures of bare beta-Si3N4 surfaces
are investigated from first principles. The equilibrium shape of a Si3N4
crystal is found to have a hexagonal cross section and a faceted dome-like base
in agreement with experimental observations. The large atomic relaxations on
the prismatic planes are driven by the tendency of Si to saturate its dangling
bonds, which gives rise to resonant-bond configurations or planar sp^2-type
bonding. We predict three bare surfaces with lower energies than the open-ring
(10-10) surface observed at the interface, which indicate that
non-stoichiometry and the presence of the rare-earth oxide play crucial roles
in determining the termination of the Si3N4 matrix grains.Comment: 4 Pages, 4 Figures, 1 tabl
Genome Resources for Climate‐Resilient Cowpea, an Essential Crop for Food Security
Cowpea (Vigna unguiculata L. Walp.) is a legume crop that is resilient to hot and drought‐prone climates, and a primary source of protein in sub‐Saharan Africa and other parts of the developing world. However, genome resources for cowpea have lagged behind most other major crops. Here we describe foundational genome resources and their application to the analysis of germplasm currently in use in West African breeding programs. Resources developed from the African cultivar IT97K‐499‐35 include a whole‐genome shotgun (WGS) assembly, a bacterial artificial chromosome (BAC) physical map, and assembled sequences from 4355 BACs. These resources and WGS sequences of an additional 36 diverse cowpea accessions supported the development of a genotyping assay for 51 128 SNPs, which was then applied to five bi‐parental RIL populations to produce a consensus genetic map containing 37 372 SNPs. This genetic map enabled the anchoring of 100 Mb of WGS and 420 Mb of BAC sequences, an exploration of genetic diversity along each linkage group, and clarification of macrosynteny between cowpea and common bean. The SNP assay enabled a diversity analysis of materials from West African breeding programs. Two major subpopulations exist within those materials, one of which has significant parentage from South and East Africa and more diversity. There are genomic regions of high differentiation between subpopulations, one of which coincides with a cluster of nodulin genes. The new resources and knowledge help to define goals and accelerate the breeding of improved varieties to address food security issues related to limited‐input small‐holder farming and climate stress
A Quasiperiodic Gibbons--Hawking Metric and Spacetime Foam
We present a quasiperiodic self-dual metric of the Gibbons--Hawking type with
one gravitational instanton per spacetime cell. The solution, based on an
adaptation of Weierstrassian and functions to three
dimensions, conforms to a definition of spacetime foam given by Hawking.Comment: 14 pages, Late
SPHERE FITTING INTO VOLUMETRIC REPRESENTATIONS OF BASKETBALL THROWS
This study aims to provide an evaluation, through some simplifications, for the most forgiving throw positions in the game of basketball throughout the playing field. For each position, throws are modelled as differential equations and then solved numerically. Given a position in the playing field, velocity vectors of successful throws constitute a solid and we fit a maximal sphere into these solids to evaluate the error tolerance for each position. A contour graph for the volumes of maximal spheres was plotted for this evaluation
Mapping and manipulating the Mycobacterium tuberculosis transcriptome using a transcription factor overexpression-derived regulatory network
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