293 research outputs found
Memory and rejuvenation in a spin glass
The temperature dependence of the magnetisation of a Cu(Mn) spin glass (
57 K) has been investigated using weak probing magnetic fields ( =
0.5 or 0 Oe) and specific thermal protocols. The behaviour of the zero-field
cooled, thermoremanent and isothermal remanent magnetisation on (re-)cooling
the system from a temperature (40 K) where the system has been aged is
investigated. It is observed that the measured magnetisation is formed by two
parts: (i) a temperature- and observation time-dependent thermally activated
relaxational part governed by the age- and temperature-dependent response
function and the (latest) field change made at a lower temperature, superposed
on (ii) a weakly temperature-dependent frozen-in part. Interestingly we observe
that the spin configuration that is imprinted during an elongated halt in the
cooling, if it is accompanied by a field induced magnetisation, also includes a
unidirectional excess magnetisation that is recovered on returning to the
ageing temperature.Comment: EPL style; 7 pages, 5 figure
Synthesis of BaTiO3-CoFe2O4 nanocomposites using a one-pot technique
Abstract Low-cost and scalable sol–gel chemistry was employed to obtain ferroelectric-ferrimagnetic BaTiO3-CoFe2O4 nanocomposites. In a novel one-pot synthesis method, both the constituent phases of nanocomposites are formed during the same time and symbiotically participate to each other's growth. X-ray powder diffraction evidences the phase purity of the systems, with average crystallite sizes in the order of 20 nm for the BaTiO3 phase. The optimization of the synthesis conditions, precursors, and chemical agents for nanoscale BaTiO3 and BaTiO3-CoFe2O4 nanocomposites is presented, together with the magnetic and/or dielectric properties of the obtained materials. BaTiO3-CoFe2O4 nanocomposites with up to 20% CoFe2O4 volume fractions were found to display ferrimagnetic properties at room temperature akin to those of CoFe2O4, while preserving a dielectric behavior reminiscent of BaTiO3. Preliminary results describing the spin coating of BaTiO3 and BaTiO3-CoFe2O4 nanocomposites as thin films are also reported
Magnetic properties of cobalt ferrite-silica nanocomposites prepared by a sol-gel autocombustion technique
The magnetic properties of cobalt ferrite-silica nanocomposites with different concentrations (15, 30, and 50 wt %) and sizes (7, 16, and 28 nm) of ferrite particles have been studied by static magnetization measurements and Mossbauer spectroscopy. The results indicate a superparamagnetic behavior of the nanoparticles, with weak interactions slightly increasing with the cobalt ferrite content and with the particle size. From high-field Mossbauer spectra at low temperatures, the cationic distribution and the degree of spin canting have been estimated and both parameters are only slightly dependent on the particle size. The magnetic anisotropy constant increases with decreasing particle size, but in contrast to many other systems, the cobalt ferrite nanoparticles are found to have an anisotropy constant that is smaller than the bulk value. This can be explained by the distribution of the cations. The weak dependence of spin canting degree on particle size indicates that the spin canting is not simply a surface phenomenon but also occurs in the interiors of the particles. (c) 2006 American Institute of Physics
Effect of Nd doping on the crystallographic, magnetic and magnetocaloric properties of NdxGd3-xCoNi
The crystal structure, magnetic and magnetocaloric properties, and the critical behavior of representative compounds in the pseudo-ternary NdxGd3-xCoNi series have been investigated (x = 0.15, 0.5, 1.0, 1.5). All these phases are isotypic with the parent compound Gd3CoNi, crystallizing with the monoclinic Dy3Ni2-type (mS20, C2/m, No. 12). All samples present a paramagnetic to ferromagnetic (PM-FM) second order phase transition with decreasing Curie temperature as the Nd concentration is increased (TC = 171 K, 150 K, 120 K and 96 K, respectively) and, at lower temperatures, there is a spin reorientation which leads to a complex magnetic ground state. The critical exponents (beta, gamma, delta) have been retrieved for the PM-FM transitions. On the one hand, in x = 0.15, 0.5, 1.5 the value of γ ≈ 1 indicates that the magnetic interactions are long-range order while the values of β point to a certain deviation from the 3D-Heisenberg universality class; on the other hand, NdGd2CoNi has a particular critical behaviour, as β is close to the Mean Field model while γ is close to the uniaxial 3D-Ising one. Concerning the magnetocaloric properties, the magnetic entropy change and refrigerant capacity present competitive values, interesting for cryogenic applications. Finally, the thermal diffusivity values of these compounds are extremely good for practical magnetocaloric refrigeration systems, as they are in the range 1.5-3 mm2/s.This work has been supported by Departamento de Educación del Gobierno Vasco (Project No. IT1430-22)
Towards high-performance electrochemical thermal energy harvester based on ferrofluids
The ionic liquid-based thermo-electrochemical cells receive increasing attention as an inexpensive alternative to solid-state thermo-electrics for waste heat harvesting applications. Recently, it has been demonstrated that magnetic nanoparticles (MNPs) in liquid-based thermoelectric materials result in enhancement of the Seebeck effect opening new perspectives to the design of a thermoelectric device with relatively high efficiency and cost effectiveness. Here, the role of an interacting assembly of MNPs in the thermoelectric signal is studied for the first time. Based on a thermodynamic approach, an analytic expression has been derived for the Seebeck coefficient that includes the inter-particle magnetic interactions in the assembly and the nanoparticle's magnetic characteristics (saturation magnetization, magnetic anisotropy). Mesoscopic scale modelling with the implementation of the Monte Carlo Metropolis algorithm is performed to calculate their contribution to the Seebeck coefficient, for diluted assemblies of \u3b3-Fe2O3 and CoFe2O4 nanoparticles, materials commonly used in ferrofluids. The results demonstrate the increase of the size and temperature range of the Seebeck coefficient with the increase of nanoparticles\u2019 magnetic anisotropy paving the way for the detailed study of the magneto-thermal effects in high-performance thermoelectric materials based on ferrofluids
Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials - MagBioVin Project
Research advancements and opportunities by the FP7-ERA Chairs project MagBioVin are spotlighted.[1] Topic of the project is the design of different novel magnetic nanoarchitectures (e.g. bimagnetic and polymeric core-shell systems, nanoparticles embedded in mesoporous silica structures, and radiolabeled nanostructures)[2–4] for application in targeted treatment and diagnostics of cancer. These nanomaterials posses the ability for selective treatment of tumor tissues by the targeting with magnetic field.[5,6] Alternating magnetic field also provides the means for hyperthermia-induced cancer treatment.[7]Attachment of radionuclides to the synthesized nanoparticles is explored for the purpose of imaging and internal radiotherapy.[8,9] Magnetic characteristics of the prepared nanomaterials is done by SQUID magnetometry and Mössbauer spectroscopy. Structural characterization of the investigated nanomaterials is performed by XRD, TEM imaging, DRIFT spectroscopy, and nitrogen sorption analysis. Magnetic hyperthermia effects are monitored by using commercial setup (nB nanoScale Biomagnetics) which includes applicators for cell cultures and small animals. In vitro and in vivo (animal model) applicability of the synthesized nanomaterials regarding toxicity, biodistribution and anticancer efficacy is explored for targeted cancer treatment.1st International Symposium: program and the book of abstracts : March 29-31, 2016; University of Central Lancashire, Preston, U
One-step synthesis of magnetic zeolites from waste materials
Magnetic zeolites can be successfully used for removing contaminants from polluted water, as they
can be easily separated by the solution using an external magnetic field. In such a way, the
wastewater treatment becomes simpler than conventional processes, which imply time and energy
consuming centrifugation or filtration steps [1,2].
In this study, a low temperature environmentally friendly synthesis of magnetic zeolites by
hydrothermal activation is presented [3]. The major novelty of the process is the use of a mixture of
waste materials namely, fly ash (FA) and red mud (RM), as precursors to synthesize zeolites with
good magnetic properties in a one step process, i.e. without passing through the additional synthesis
of magnetic nanoparticles, which is commonly used for the preparation of the magnetic zeolites.
The structural properties were investigated by SEM, XRD and TEM and showed that different types
of zeolites (A, X and ZK-5) were obtained for different FA/RM percentages and incubation
temperature. All of them possess sufficiently high magnetic moment to allow their easy separation
by the solution using an external magnet (Fig. 1). The magnetic investigation was carried out by
SQUID and VSM magnetometry. The global magnetic properties of the newly formed minerals
were discussed on the basis of magnetic properties of precursors, where different magnetic behavior
was observed (Fig.1). Good adsorbance properties of the final synthetic products were confirmed
Adjusting the Neel relaxation time of Fe3O4/ZnxCo1-xFe2O4 core/shell nanoparticles for optimal heat generation in magnetic hyperthermia
In this work it is shown a precise way to optimize the heat generation in high viscosity magnetic colloids, by adjusting the Neel relaxation time in core/shell bimagnetic nanoparticles, for magnetic fluid hyperthermia (MFH) applications. To pursue this goal, Fe3O4/ZnxCo1-xFe2O4 core/shell nanoparticles were synthesized with 8.5 nm mean core diameter, encapsulated in a shell of similar to 1.1 nm of thickness, where the Zn atomic ratio (Zn/(Zn + Co) at%) changes from 33 to 68 at%. The magnetic measurements are consistent with a rigid interface coupling between the core and shell phases, where the effective magnetic anisotropy systematically decreases when the Zn concentration increases, without a significant change of the saturation magnetization. Experiments of MFH of 0.1 wt% of these particles dispersed in water, in Dulbecco modified Eagles minimal essential medium, and a high viscosity butter oil, result in a large specific loss power (SLP), up to 150 W g(-1), when the experiments are performed at 571 kHz and 200 Oe. The SLP was optimized adjusting the shell composition, showing a maximum for intermediate Zn concentration. This study shows a way to maximize the heat generation in viscous media like cytosol, for those biomedical applications that require smaller particle sizes
The interplay between single particle anisotropy and interparticle interactions in ensembles of magnetic nanoparticles
This paper aims to analyze the competition of single particle anisotropy and interparticle interactions in nanoparticle ensembles using a random anisotropy model. The model is first applied to ideal systems of non-interacting and strongly dipolar interacting ensembles of maghemite nanoparticles. The investigation is then extended to more complex systems of pure cobalt ferrite CoFe2O4 (CFO) and mixed cobalt-nickel ferrite (Co,Ni)Fe2O4 (CNFO) nanoparticles. Both samples were synthetized by the polyol process and exhibit the same particle size (DTEM 48 5 nm), but with different interparticle interaction strengths and single particle anisotropy. The implementation of the random anisotropy model allows investigation of the influence of single particle anisotropy and interparticle interactions, and sheds light on their complex interplay as well as on their individual contribution. This analysis is of fundamental importance in order to understand the physics of these systems and to develop technological applications based on concentrated magnetic nanoparticles, where single and collective behaviors coexist
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